高压连接器用尼龙:UL94 只是入场券,CTI 才是分水岭

塑料知识科普 发布时间: 2026-09-16 4776 阅读

For high-voltage connector material selection, we have seen too many openings like this:

We want a flame-retardant nylon with UL94 V0 rating.

The demand is not wrong, but it only covers one-third.

UL94 tests for self-extinguishing properties, GWIT tests for glow wire ignition, and CTI tests for tracking resistance. For high-voltage components, what truly causes safety standards failures are often the latter two, especially CTI.

This article explains the division of the three indicators clearly, so you will know which direction to choose materials for high-voltage connectors.

Let's start with a live scene

There is a client who makes charging pile accessories. They once came to us with two test reports and asked: For flame-retardant reinforced PA66 of the same brand, one institution measured a CTI of 600 volts, while another measured just over 400 volts. Is it possible that one of them made a mistake?

We compared the test conditions of the two reports line by line and found no testing errors—the difference lies in the sample condition: the 600-volt test used dry samples, while the 400-volt test simulated testing after damp-heat treatment. And the actual service environment of the charging pile is obviously more like the latter.

This case puts the core conflict of high-voltage connector selection on the table: the beautiful numbers on the physical property sheets are numbers from dry laboratory tests; your product has to operate for ten years in humid, dirty, and temperature-changing environments, and a whole set of evaluation methods separates these two worlds.

This article specifically discusses this gap. First, clarify what the three indicators CTI, GWIT, and tracking resistance each cover—many tender documents mix them together, and suppliers report mixed values accordingly. Then it explains how CTI is gradually 'brought down' through formulations and working conditions, why high-voltage components often have to move toward semi-aromatic types, and how different parts of the same connector are selected differently.

Add the last five pits and boundaries. For readers making high-voltage connectors, charging guns, and energy storage connections: the criteria in this article are recommended to be directly copied into your incoming material inspection standards.

1. First, distinguish what each of the three indicators measures

These three indicators are often mixed up when discussed, but in fact, they measure three different things.

IndicatorFull name meaningWhat examTypical requirements
UL94Horizontal/Vertical BurningCan the material extinguish itself after being removed from the fire source?V0 (Highest Common Level)
GWITIncandescent wire ignition temperatureWill it ignite when in contact with a heat source?750℃ / 850℃ / 960℃
CTIComparative Tracking IndexWill voltage, dirt, and moisture form a conductive path?The 600V range is commonly used for high-voltage components.

Division in one sentence: UL94 handles 'flammability', GWIT handles 'heat', CTI handles 'electricity'.

The test conditions for the three indicators are also different and cannot be converted into each other. UL94 is a combustion test conducted on standard specimens; GWIT is done on a hot wire at a specific temperature; CTI needs to be measured under specific solution contamination conditions.

So the phrase 'we have V0' cannot answer CTI's question. The three indicators each require separate data and separate verification.

High-voltage connectors involve electricity, so CTI is their main field.

Many projects require safety rework, not because V0 wasn't achieved, but because the CTI is one grade lower.

2. How CTI was 'brought down'

The mechanism of CTI failure is worth discussing separately.

The conditions are three: voltage, moisture, surface contamination.

The process is roughly as follows:

1. The surface of the part absorbs moisture or gets contaminated with conductive dirt

2. Under the action of voltage, a small leakage current occurs on the surface

3. Leakage current generates local high temperatures, causing the surface to carbonize.

4. The carbonized layer is conductive, and the current is further concentrated

5. Form a permanent conductive path

After the final step, the insulation will fail permanently and irreversibly.

So there are two approaches to increasing CTI:

① Make the material moisture-resistant — this is at the resin level ② Make the material less prone to charring — this is at the flame-retardant system level

These two happen to counteract each other. Many flame-retardant additives (especially halogen-based ones) can cause the CTI to drop. This is why 'high CTI V0' is a formulation challenge, not something that can be solved by simply buying an off-the-shelf grade.

A parameter that is easily overlooked: hygroscopicity

After absorbing moisture, the volume resistivity of PA6 / PA66 will significantly decrease.

In other words, the same grade may meet the CTI standard under dry conditions, but it might fail during the plum rain season in the south.

This is especially important for products exported to high-humidity areas. When selecting materials, suppliers should provide electrical data in the 'conditioned' state, not just in the dry state.

Creepage distance cannot replace CTI

There is a common 'remedial' practice: when the CTI is insufficient, the creepage distance in the structure is lengthened.

This is useful in design, but it cannot replace materials, for the following reasons:

Creepage distance addresses whether the 'surface path is long enough' - CTI addresses whether the 'surface will be carbonized'

If the material itself is prone to carbonization, increasing the distance only shifts the failure point elsewhere. Once a certain area is carbonized, the conductive path will expand outward from the carbonized region, rather than following the designed path.

So the correct order is: first choose the CTI rating of the right material, then use the creepage distance to design the safety margin. If reversed, it means using the structure to compensate for the material's shortcomings.

3. Why high-pressure components often tend to move toward semi-aromatic

Look at the two requirements from the previous section together:

High CTI: requires low moisture absorption and resistance to carbonization - High flame retardancy: requires V0, and sometimes also halogen-free - High temperature resistance: SMT components must withstand reflow soldering, automotive components must withstand long-term 120-150°C

With three combined factors, PA66 becomes very difficult to handle.

The advantages of semi-aromatic nylons (PA6T, PA9T, PA10T, PPA family) are here:

FeaturePA66PA6T / PA9T
Balanced water absorption8-9%Significantly lower (PA9T extremely low)
Melting point265℃320℃ / 306℃
Reflow solder resistantgeneralGood
CTI BaselineMediumHigh (PA9T is often mentioned in the 600V range)
Dimensional stabilitygeneralGood
CostBenchmarkTall

The item with the best cost-performance ratio here is usually PA6T, while PA9T has the best CTI and dimensional stability.

The drawback is the high processing temperature—PA6T has a melting point above 320°C, so both the injection molding machine’s material temperature and the mold need to be adjusted accordingly; you cannot directly apply the process parameters of PA66.

In one sentence: The expensive material of high-voltage components is not bought for its strength, but for the simultaneous compliance of 'electrical performance, dimensions, and temperature resistance'.

4. For the same connector, different components should be selected separately

A high-voltage connector is not a single part, it is an assembly. Their stress, temperature resistance, and electrical requirements are all different.

ComponentMaterial directionKey indicators
ShellFlame-retardant PA66 / PA6TV0, CTI, Mechanical Strength
Rubber core / InsulatorPA6T / PA9T / PPACTI, temperature resistance, dimensional stability
Terminal block / FastenerPA66-GF / PA6T-GFStrength, temperature resistance
Sealing ring / Dust-proof partElastomer / TPERebound, weather resistance
Shield / Structural BracketPA66-GF or materials with shielding capabilitiesStrength, assembly

The rubber core is the most particular piece of material.

Because it needs to simultaneously meet: high CTI, thin-wall molding, high dimensional accuracy, and temperature resistance. This is why high-voltage connector resin cores often directly use PA9T or PPA—other areas can economize, but here it cannot be spared.

A vicarious liability in craftsmanship

CTI is not just a matter of the formulation; it is also affected by the injection molding process.

Melt temperature too high → Local material degradation → Surface more prone to carbonization - Mold temperature too low → Rough surface, high internal stress → More prone to moisture absorption and contamination - Long residence time in the barrel → Also leads to degradation

So for the same grade, parts with an unadjusted process and parts with an adjusted process may have different measured CTI values. It is worth doing a test sample measurement yourself before sending it for safety certification testing.

There is one more spot that is often overlooked: the fit between metal inserts and plastic.

High-voltage connectors usually need to embed metal terminals or nuts. The thermal expansion coefficients of metal and plastic differ significantly.

Under temperature cycling, stress occurs at the interface. When performing temperature cycling tests, if a part cracks at the insert location, it is mostly due to this reason, not because of insufficient material strength.

There are usually two ways to deal with it: design the insert with sufficient interlocking structures, or choose a resin system with a coefficient of linear expansion that is closer. This kind of problem must be solved early in the design stage—you can't fix it by changing the material.

By the way, a small detail: the groove for the sealing ring in the connector.

The compression rate of the sealing ring is determined by the groove size. After absorbing moisture, the plastic part will expand, the groove size will change accordingly, and the compression rate will change accordingly.

Therefore, the key dimensions of the sealing groove must be determined using data after humidity adjustment. Otherwise, it may fit well during assembly, but leakage will start after a period of use.

Semi-aromatic is not a universal upgrade

If the CTI standard is not met, we go for semi-aromatic; this upgrade path has almost become a standard formula in the industry, but formulas have applicable limits. The electrical performance of semi-aromatics is indeed good, CTI of 600 is common, and the temperature resistance is also half a level higher; the costs are threefold: higher unit price, narrower processing window, and lower toughness compared to aliphatics, so caution is needed for brittle failure in low-temperature assembly.

So before upgrading, do three things: confirm that the wet CTI really does not meet the standard, as many projects scare themselves with dry data; confirm that the creepage distance on the structural side has been optimized, as adding one millimeter might mean no need to change the material; confirm that the temperature rise and assembly temperature are within the comfortable range for semi-aromatic.

Finish these three things before upgrading, and you'll spend money with peace of mind. Upgrading materials cannot solve the problem of cutting corners in the structure, and this principle is especially evident in high-stress components.

Five, five pits

Pitfall 1: Only ask about V0, not CTI. The whole text is talking about this. For high-voltage components, all three indicators need to be mentioned together.

Pitfall 2: Designing using dry-state electrical data. Moisture absorption will lower the volume resistivity. It is necessary to use conditioned (moisture-adjusted) data.

Pitfall 3: Sacrificing processability for flame retardancy. Halogen-free flame retardant systems require high loading, resulting in poor flow and difficulty in molding thin walls. For thin-walled parts with a plastic core, it is necessary to confirm flowability and molding window in advance.

Pitfall 4: Ignoring the timeliness of CTI. CTI declines with moisture absorption and aging. Passing certification does not mean long-term stability.

Pitfall 5: Using the process for PA66 to process PA6T. The material temperature, mold temperature, and drying requirements of high-temperature nylon are all different, so not changing the process is equivalent to choosing the material in vain.

A commonly overlooked verification item: the mechanical strength after aging

CTI decreases with aging, and mechanical properties will also decline. High-voltage connectors are subjected to temperature cycling and vibration throughout the vehicle’s life, so the strength of the latch cannot be judged solely by its initial value.

It is much more useful to ask suppliers to provide the strength retention after thermal aging than to provide the tensile strength at room temperature. Especially for locations above 130°C over the long term, this parameter explains the issue better than the initial strength.

6. Borders

SceneConclusionExplanation
800V platform high-voltage componentssemi-aromatic directionPA6T / PA9T / PPA
400V platform standard partsPA66 flame-retardant system can coverCTI verification required
Electrical components >150℃ long-termPA6T / PA46 / PPAAccording to temperature
High CTI, Thin Wall, Halogen-FreeThe most difficultIt is recommended to conduct formula verification early
High-power arc situationsRequires a specialized planMay require thermosetting or ceramic materials

A real feeling in the industry

In high-voltage connector inquiries, the sentence we hear most often is:

I want V0 materials, how many types do you have?

If this question is asked, it can basically be judged that the customer is dealing with high-pressure components for the first time.

Because the customer has worked with high-voltage components, the question was asked like this: 'V0, CTI 600V, long-term 150℃, is there any direction?' — all three indicators are mentioned together.

We usually ask three follow-up questions: Which tier of the high-voltage platform is this component, 400V or 800V? What is the long-term operating temperature? Are there any thin-walled areas?

After asking three questions, the direction is basically determined. If the client can only answer 'want to V0,' it indicates that the project is still at the very beginning of material selection — at this point, choosing any grade is just a matter of luck.

We'd rather ask a few more questions at this time than wait for the customer to finish safety testing before coming to us for a replacement. The cost of replacements is a minor issue; the cost of delaying the certification cycle is a big issue.

Reader Follow-up Questions Two Questions

Follow-up Question One: How to verify CTI data during procurement without being misled? Three actions: Check the thickness corresponding to the yellow card; CTI values are only valid below the indicated thickness, and lower the notch if the wall thickness is thinner; Check the test status, specify whether it's dry or damp heat, and the tender documents uniformly judge it as damp heat;

Check batch consistency and have suppliers provide third-party retest records from the past two years. If there is only one historical yellow card with no tracking data, leave a question mark. After completing these three steps, the moisture on the CTI is basically squeezed out.

Follow-up question two: What is the most easily overlooked verification item when upgrading to semi-aromatic? Low-temperature assembly impact. The toughness of semi-aromatic is one level lower than that of aliphatic types, so room temperature assembly is fine, but in northern production lines or low-temperature logistics scenarios in winter, snap assembly brittle breakage rates can appear.

Before finalizing the upgrade plan, add the plug-in and unplug test at the lowest assembly temperature to the validation list. This can block the most common after-sales type after the upgrade. In short: upgrading is about changing character, not changing parameters. First, understand the temperament of the new character, then put it into work.

also has a reminder for the proposal review meeting: don't just have material engineers sign the material plan for high-voltage connectors. Structure, process, and quality all need to be reviewed—the structure depends on whether the creepage distance is sufficient, the process depends on whether injection molding can stably achieve thin walls, and on quality, the material inspection has corresponding testing methods.

The material plan has never been a decision made by the material alone; only when all four parties sign together can the plan be established and implemented without dead ends. This process may seem slow, but in reality, it is the most time-saving part of the three-electric project.

The CTI template in the tender terms

Include the CTI requirements in the bidding documents, recommending a segment as follows: High-voltage electrical parts use engineering plastics, compared to the marking index tested according to IEC 60112, determined to be after wet heat treatment, PTI not less than 400V (800V platform parts not less than 600V), test thickness not exceeding the minimum product wall thickness, with yellow card screenshots corresponding to the grade attached with the report;

Suppliers must provide third-party retest records from the past two years; those without tracking data must be sent for inspection synchronously with the samples. Copying this section locks three things: lock the judgment state to block dry data confusion; Thickness binding to prevent mismatches between high levels and low thickness; Track data and block one-time reports.

Write these five lines more in the bidding documents, and CTI disputes in the incoming material stage basically disappear. The clause is managed upstream, much cheaper than downstream disputes.

Here's a common scenario in bidding negotiations: a supplier has submitted a new grade with a very high CTI, and the price is attractive. Should you cut it? Before cutting, you need three things: a complete third-party report, not just the numbers on the flyer, the last six months' worth of mass production and supply records, and usage cases under similar conditions in the same industry.

With all three items together, do small-batch trial production, sending all trial parts for inspection and retesting. The performance trap of new grades is often not the average, but fluctuations between batches—the advertised numbers are the best batch, but your production line gets random batches. Every supplier in the supply chain needs to pay for the fluctuation lesson—the earlier you supplement, the safer you are. The later the lesson, the more you pay for it.

Conclusion

High-voltage connector material selection, remember the order of the three words:

First CTI, then GWIT, and finally UL94.

Because high-voltage components are 'electrical work,' UL94 is just a ticket. If the order is reversed, problems will only be discovered when it's sent for inspection.

Add one more thing: all electrical data must be asked about humidity regulation.

One last note: When selecting high-voltage connector materials, essentially, it's about finding a position that can stand on the three corners of 'electrical performance, temperature resistance, and cost' at the same time. If you want all three parts, it's expensive material; Save one to have room to spare. This saying is useful for your next R&D meeting—it's more useful than ten pages of documentation

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