电池液冷管路用尼龙:这里最不能用的恰是 PA66 和 PA6

塑料知识科普 发布时间: 2026-09-13 1053 阅读

Regarding the selection of materials for liquid cooling pipelines, there is a counterintuitive conclusion that needs to be mentioned first:

The ones that should not be used here the most are exactly the most common PA6 and PA66.

There is only one word for the reason: hydrolysis.

This article explains hydrolysis thoroughly—it’s not that the material is 'bad,' it’s that the molecular chains are being broken down under the combined action of water and heat. Once you understand the mechanism, choosing materials no longer requires guessing.

Let's start with a live scene

Last fall, a few photos were posted in an after-sales group of an energy storage integrator: the liquid-cooled piping, which had been in operation for a year and a half, was leaking at the base of the quick connector, and a small puddle of white coolant had accumulated at the bottom of the cabinet. The supplier initially suspected it was an assembly torque issue and replaced the on-site spare parts with a new batch, but the problem recurred in the same way three months later.

Later, when the leaking joint was cut open for inspection, fine cracks appeared on the inner wall — this was not an assembly problem, but hydrolysis of the material after long-term service in ethylene glycol-based coolant.

There is another intriguing detail about the same case: the material used for the main body of the pipeline was fine, and the problem only occurred at the quick connector. This is because the coolant temperature at the connector is higher, the flow rate is faster, and the residual stress from injection molding is concentrated there, causing hydrolysis at this point to be accelerated several times.

Let's start this article from the root cause: hydrolysis. First, explain the chemical process of 'how ethylene glycol at high temperatures cuts nylon apart' in plain language, and then talk about why long carbon chain nylon can withstand this—when the carbon chain is long, the density of amide groups becomes sparse, so water molecules can't get in. Then split the discussion on selection into two parts: one for the main body of the piping, and one for the quick connectors, the latter being much more difficult than the former.

Finally, there are five pitfalls and boundaries. For readers involved in energy storage and liquid-thermal management, pay special attention to Section 4 on quick connectors, as that is the most demanding area in this field.

1. Hydrolysis: The process of 'cutting' nylon

First clarify the mechanism, then all subsequent conclusions will be derived from it.

There is a chemical bond called an amide bond (—CO—NH—) in the molecular chain of nylon. It is stable by itself, but it will react when it encounters two things:

① Water molecules. At high temperatures, water will attack amide bonds, breaking the chain. ② Temperature. Each increase in temperature level does not cause a linear increase in the hydrolysis rate, but a significant acceleration.

So the real killers are the simultaneous presence of 'high temperature and moisture'.

And the operating condition of the liquid cooling pipeline is precisely this combination:

Coolant (commonly ethylene glycol-based) - long-term temperature 90-120°C - both inside and outside of the pipes are wet

In this environment, the molecular chains of PA6 and PA66 will continue to break. The manifestations are first a decrease in strength, yellowing and brittleness on the surface, and later cracking and leakage.

The most troublesome part is: it has already occurred when there is no visible problem with the exterior of the item.

Why is ethylene glycol more troublesome?

Pure water is already tough enough, and ethylene glycol-based coolant adds another layer:

Ethylene glycol itself can generate acidic substances at high temperatures - the additives in the coolant (anti-rust, anti-scale) will further affect the materials - the coolant also carries pressure pulsations during circulation

These three combined are the reason why the selection of materials for liquid cooling pipelines must 'take a conservative approach'.

There is another type of medium that is easily overlooked: deionized water.

Deionized water has no ions, but it can 'pull' ions and additives from materials, and long-term soaking will also affect the material's condition. This type of medium is used in cold-plate liquid cooling in data centers.

So the judgment that 'crossing water is safe' is not valid—it depends on what kind of water it is, the temperature, and how long it flows.

In one sentence: As long as the medium is 'high-temperature water or high-temperature coolant,' the first step in material selection is to rule out PA6 / PA66.

2. Long-chain nylon: Why it can withstand

In the nylon family, the longer the chain, the lower the 'density' of amide bonds.

Low amide bond density = fewer sites that can be hydrolyzed = better hydrolysis resistance.

At the same time, it also brings a second benefit: low water absorption.

MaterialBalanced water absorptionHydrolysis-resistantRelative cost
PA68-10%poorLow
PA668-9%poorLow
PA610About 1.5%Bettermiddle
PA612About 1.2%GoodMedium-high
PA1010 / PA1012Less than 1.5%GoodMedium-high
PA11About 0.8%GoodTall
PA12About 0.7%BestTall

(Typical magnitude, subject to the TDS of the specific grade)

Low water absorption rate provides a double benefit in liquid cooling pipelines:

① Size is stable. The piping has joints, clamps, and assembly positions. Water absorption and expansion/contraction can cause the sealing fit to fail. ② Slow hydrolysis. The material contains little water internally, so there is little 'water' involved in hydrolysis.

PA12 and PA11 are the most stable in this family. Their water absorption is below 1%, hydrolysis resistance is the best, and they can be used long-term in water and oil pipelines.

The cost is the price—PA12 is roughly several times the magnitude of PA6. In liquid cooling pipelines, it's not 'better to use,' it's 'you have to use it.'

Can hydrolysis stabilizers save PA66?

The answer is: it can improve, but it cannot solve the problem.

Adding hydrolysis stabilizers can indeed extend the lifespan of PA66 under humid and hot conditions, which is a relatively mature practice in the industry. But what it changes is 'how long before chain breakage occurs,' not 'whether chain breakage will occur.'

Under the operating conditions of long-term immersion in coolant at 90-120°C, even with a hydrolysis-stabilized system, the long-term performance of PA66 is still inferior to that of long-chain nylon. This is because the water absorption rate is what it is—once water enters, the raw materials for hydrolysis are present.

So the order of selecting materials should be: first eliminate unsuitable resins based on the medium and temperature, and then discuss which additives to use for optimization. Doing it the other way around means using additives to compensate for the shortcomings of the resin, which is costly and has limited effectiveness.

3. How to choose the main pipeline body

Body partMaterial directionReason
coolant hosePA12 / PA11 / PA612Hydrolysis-resistant Soft Low-temperature resistant
corrugated tube sheathPA612 / PA12Bending fatigue Hydrolysis resistance
Multi-layer barrier pipePA/EVOH compositeBarrier penetration (more common in fuel systems)
Rigid pipeline sectionPA12-GF / PA612-GFPressure-resistant Hydrolysis-resistant
Quick coupler bodyPA12 / PA612 (including reinforced)Hydrolysis resistant Dimensionally stable
Sealing / O-ring seatPA12 / ElastomerFit precision Rebound

A few selection details:

① For bellows, what matters is 'bending fatigue,' not strength. For pipelines that need to be bent repeatedly and subjected to vibration, fatigue resistance is much more important than tensile strength.

② Low-temperature performance should be considered together. Long-chain nylon generally has better low-temperature toughness than PA66, but there are also differences between different chain lengths. Vehicles for cold regions must look at the -40℃ data.

③ The processing method determines the state of the material. Extruded pipes and injection-molded parts have completely different requirements for material flowability, and injection molding grades cannot be used for extrusion.

④ The transition position between the hose and the hard pipe should be calculated for stress separately. The rigidity of the hose (PA12, PA612) and the hard pipe section (PA12-GF) differs significantly, and the stress concentration at the connection is much greater than in the pipe body. Many pipe cracks do not occur in the pipe body but at the soft-hard transition. In terms of design, either make a gradient or add a fixed constraint at the transition to disperse the stress.

A judgment: On the liquid cooling pipeline, 'hydrolysis resistance' is the entry ticket, while 'dimensional stability brought by low water absorption' is the real threshold.

4. Quick Connectors: A More Difficult Area Than Pipelines

If the main pipeline has a problem, it’s slow; if the quick connector has a problem, it’s fast.

The coupler has three more requirements than the pipeline itself:

① Dimensional accuracy. The sealing surface depends on the fitting dimensions. If it absorbs moisture and expands by 0.1mm, it may change from 'no leakage' to 'seepage'.

② Long-term stress. The buckle and locking structure are in a stress state for a long time, observing creep.

③ Repeated plugging and unplugging. During maintenance, it will be disassembled and reassembled, and the plugging and unplugging lifespan is a hard specification.

Among these three, dimensional accuracy is the most prone to failure.

There is another common misconception about quick connectors: thinking 'as long as it can be plugged in, it's fine.'

Sealing is achieved through a combination of size and force. If the plug-in force is too small, the seal will not be tight; if it is too large, it can damage the clip during assembly. Therefore, the acceptance of quick connectors must consider two numbers simultaneously: the results of the seal test and the plug-in force curve.

Only testing the sealing and not the insertion and extraction force will result in problems only being exposed at the mass production stage.

So quick connectors in long-chain nylon tend more towards PA12 or PA612 with reinforcement—the low water absorption ensures dimensional stability, while the reinforcement supports the strength of the clips.

Here is a very practical self-check question:

Is this part of yours 'soaked in coolant for a long time,' or 'occasionally in contact with coolant'?

Long-term immersion: must use long-chain carbon, no exceptions - Occasional contact (for example, splashing): can relax to PA66 hydrolysis-resistant system, but testing is required

Many liquid cooling projects choose the wrong materials because they mistake 'long-term immersion' for 'occasional contact'.

How to choose a long carbon chain family

After deciding to go with longer carbon chains, choosing within the family becomes another issue. Here’s a concise hierarchy. PA11, PA12: they are bio-based or monomer-derived, have the lowest water absorption, the most stable hydrolysis resistance, and good flexibility. They are the traditional mainstays for pipelines and fittings, and also the most expensive. The copolymer-modified grades of PA12 are specially enhanced for fuel permeability resistance, making them the go-to for fuel pipelines.

Long carbon chain copolyamide: performance balances between PA12 and PA66, with a lower price, used in pipeline sections with moderate temperature and medium requirements. Selection logic in one sentence: for areas contacting ethylene glycol and fuel, choose according to the highest requirements; for transition sections and static sections, the balanced cost-reducing type can be used.

The scariest thing is the reverse—using the best material for the static section, but the contact point uses cheap material. The money is spent, yet the leakage points remain. Draw a contact map for the medium and allocate material grades according to the map, so that the money for long carbon chains is spent where it really matters.

5. Five Pitfalls of Liquid Cooling Pipelines

Pitfall 1: Using PA66 for coolant pipes. It can hold up in the short term, but over time it undergoes hydrolysis and chain scission. This type of failure usually only becomes apparent after two or three years, by which time the warranty period has passed.

Pitfall 2: Only looking at the original strength. For liquid-cooled components, you must consider the strength retention after hydrolytic aging (for example, data after 1000 hours at different temperatures), not the initial tensile strength.

Pitfall 3: Ignoring the specific formulation of the coolant. Different formulations have significantly different corrosion effects on materials. When selecting materials, you should perform soaking tests with the actual coolant to be used, and not substitute it with a 'universal coolant'.

Pitfall 4: Using the same grade for both pipelines and quick connectors. Pipelines require flexibility and hydrolysis resistance, while quick connectors need precision and rigidity; their requirements are different.

Pitfall 5: Forgetting about low temperature. Long-chain nylon has good low-temperature resistance, but after adding glass fiber, its low-temperature toughness decreases. Components for cold regions must be verified.

6. Borders

SceneConclusionExplanation
Long-term 90-120℃ coolantlong-chain nylonPA12 / PA11 / PA612
Long-term >120℃ high-temperature water circuitNeed to be cautiousReplace PA1010 or switch to a metal/composite solution
Strong acid and alkaline mediumNot suitableRequires special resistance to chemical systems
High-pressure fuel systemPA11 / PA12Oil-resistant Barrier (multilayer structure)
Extremely low temperature below -40℃Need to be cautiousToughening system or elastomer

A real feeling in the industry

There is a type of inquiry that makes us ask a few more questions every time we see it:

The customer brought over a cracked corrugated tube and said, 'This is nylon, it's cracked. Do you have a stronger nylon one?'

If you ask, nine times out of ten it is a coolant pipe made of PA66 or PA6.

At this time, our usual response is: it's not about using stronger materials, it's about using 'waterproof' materials.

Because the customer asked about 'sturdiness,' but the problem has nothing to do with strength—it is hydrolyzed, with cracks caused by chain breakage, which has nothing to do with strength. If you switch to a higher-strength PA66, it will still crack; it will just crack a little later.

Our follow-up questions are generally three: Is it water or ethylene glycol running through the pipe? What is the long-term temperature? How long did it take to crack?

Leaks, low temperature, cracks appear after several years → The material selection is on the conservative side and can be adjusted. Leaks with ethylene glycol, temperature above 90℃, cracks appear in a year or two → Must switch to long-chain materials, there is no intermediate solution.

The same character '裂' has two different answers. If you get one question wrong, changing the material ten times won't help.

Two Reader Inquiries

Follow-up question one: Can existing PA66 systems survive by adding antihydrolytic agents? It can alleviate this, but there is a limit. Antihydrolytic agents can significantly extend the lifespan of PA66 in ethylene glycol, extending the standard operating cycle from two to three years to over five years. This is a mature route used by many cooling systems.

But be clear: antihydrolytic agents cannot change the density of amide groups. In fast-contact joints with high temperature, high flow rate, and high stress, they only delay the failure time, not cancel it. So the criterion is based on position: the body and static section, PA66 is sufficient for hydrolysis resistance; For contact ports and moving sealing areas, directly apply long carbon chains—don't skimp.

Follow-up question 2: How do you determine the criteria for liquid leakage? It is recommended to divide the data into three levels: Level 1 is surface moisture marks, which should be wiped off without recurrence and recorded for observation; Level 2 is drip seepage, which forms drops within 24 hours and is in the rectification process; Level 3 is continuous leakage, which requires immediate shutdown and replacement. After the criteria are written into the operation and maintenance manual, the most important action is to keep samples for each stage for inspection. The anatomical conclusions of the seepage parts are the most valuable input for next-generation product selection, more accurate than any experimental data.

Casually explained the acceptance procedures for liquid cooling pipelines: besides the standard dimensions and appearance, it is recommended to add two targeted inspections upon arrival—first, sampling swelling rate to measure the sample in coolant for 72 hours; if it exceeds the standard, it is immediately returned; Second, check the sealing surface condition, using a magnifying glass to check for flow marks and material shortages on the sealing belt, which cannot be detected with a caliper. Each of these two actions takes ten minutes, which can block the vast majority of batch issues. The stricter the acceptance inspection, the fewer calls after-sales there are.

Liquid Leakage Level 3 Response Card

Operation and Maintenance On-site Equip a Level 3 Liquid Leakage Response Card. Level 1, Moisture Mark: Surface is moist and does not drip; actions include marking the location, taking photos, wiping and observing for 48 hours, entering into the ledger for tracking, no need to shut down. Level 2, Drip Level: Dripping within 24 hours; actions include taking photos and sampling, arranging spare parts replacement windows, sealing and sending failed parts back for analysis. The system can operate with defects but is required to rectify within a specified period.

Level 3, Continuous Leakage Level: Positive pressure seepage or increased dripping speed; actions include immediately isolating the cabinet, cutting off power to drain liquid, and activating emergency plans. This level has no room for discussion. At the end of each level of response, it's the same action: send the failed parts back for dissection analysis, and the seepage parts are the most honest teachers of liquid cooling systems. Their fractures and cracks will tell you where to go for the next selection process. Stick the response card in the maintenance duty room, clearly write the responsible person, and it's more effective than any WeChat group notification.

By the way, to answer a frequently asked question: Should the liquid cooling piping also be fitted with a long carbon chain to get it done in one step? Our suggestion is to look at them separately. The pipeline itself operates under milder conditions than joints, with low flow rate, no assembly stress, uniform temperature, and mature performance records in this area. The cost of fully long carbon chains increases significantly, so saving money is more cost-effective for the necessary location.

's standard for judgment isn't that expensive material is always safer, but that every location should be matched with the right material, and every location is validated equally. Waste and saving the wrong places are major taboos in material selection.

Conclusion

Liquid cooling pipeline material selection—the logic is actually very clean:

The medium is water or coolant→ cross out PA6/PA66→ go for the long carbon chain→ and specify the exact grade based on temperature and precision.

After four steps, the only thing left is price and verification.

The only thing to watch out for is "just make do with PA66 first, replace it when it breaks." For liquid cooling parts, the cost of this process isn't rework, but batch leakage within the warranty period.

One last reminder: When selecting liquid cooling parts, you can be convinced by "price," not by "experience." Just because others don't have problems with PA66 doesn't mean your medium and temperature won't have issues

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