除味剂吸湿剂:回收料的“清新剂”,气味吸附分子筛干燥,让回料不再“有味”

塑料知识科普 发布时间: 2026-09-14 4232 阅读

A batch of recycled PP pellets was sent to downstream customers. As soon as the truck was unpacked, the sour odor was pungent, and the customer's receiving staff refused to sign for it. The driver stopped the truck at the factory gate and refused to unload. The boss of the modification plant was extremely anxious——the recycled material itself had small molecular volatiles from degradation, and no deodorizing agents were added in the formulation, which was equivalent to sending the smell of the recycling workshop directly to the customer.

The 'smell' and 'moisture' of recycled material: one is dealt with by adsorbents, the other by molecular sieves; don't expect one method to handle everything.

This article is compiled by Ningbo Kolong New Materials Co., Ltd., which has long been engaged in the business of plastic raw materials and additives. The grade and batch information are subject to the actual supply channels.

Quick Reference Table for Deodorizing and Moisture Absorption: Each one for pipe water and pipe odor

The names of deodorants and desiccants are close to each other, but what they do is actually very different: deodorants deal with 'gaseous' odor molecules, while desiccants handle 'liquid' free water. The table below lists the mainstream varieties clearly.

CharacterRepresentative varietyMechanism of actionTypical usesAdd ratio
Odor adsorbentZeolite, activated carbon, porous silicatePorous structures physically adsorb odors/small moleculesRecycled PP/PE, regenerated modified materials0.2%-1.0%
Moisture Absorbent / DesiccantMolecular Sieve 3A/4A/5A TypeScreening adsorbed moisture by apertureMoisture-absorbing resin, recycled material drying0.1%-0.5%
Compound DeodorizerPlant extract adsorbent compoundAdsorption, shielding, and synergyAutomotive interior-grade recycled material0.3%-2.0%

Note: The above adsorption capacity and pore size are general parameters. The actual deodorization effect is affected by the quality of the recycled material and should be based on the measured VOC.

Figure 1 Deodorants and Desiccants — Odor and Moisture Purification of Recycled Materials

One absorbs the flavor, the other sucks out the water

This main character is the refresher for recycled materials. Ningbo Kolon New Materials Co., Ltd. has been long engaged in various plastic additives and modified raw materials, covering sources for multiple domestic and international brands. It has stable supply channels for porous adsorption deodorizers, molecular sieve desiccants, and deodorizing masterbatches specifically for recycled materials. Essentially, this group of additives—deodorizers and desiccants—serves as the 'purification workshop' for recycled plastics. Recycled materials come from mixed sources and have undergone use and aging; they contain residual degraded small molecules, oils, and moisture, which smell and become damp, making them wholly unacceptable to product manufacturers if used directly.

Deodorizing desiccants are like the 'air fresheners' for recycled materials, taking away both sour odors and moisture.

The method of odor removers is 'adsorption and masking.' Materials like zeolite, activated carbon, and porous silicates are full of dense micropores, with a huge specific surface area. The small odor molecules (aldehydes, acids, hydrocarbons) coming from recycled materials get physically 'trapped' once they enter these pores. Plant extract blends add another layer of 'pleasant masking,' and together they suppress the odor to the point where it is undetectable to the nose.

The molecular sieve is like a sieve, specifically picking small water molecules to put inside; the deodorant is like a sponge wall, pressing small odor molecules onto the wall—each does its own job, and no one crosses the line.

The type of desiccant (molecular sieve) is determined by 'choosing water according to pore size.' Models 3A, 4A, and 5A actually refer to micropore diameters of approximately 0.3, 0.4, and 0.5 nanometers — water molecules are small and can enter to be firmly adsorbed; resin and oil molecules are larger and cannot enter. Therefore, it specifically absorbs moisture without absorbing the material, removing free water from recycled materials and moisture-prone resins, thereby preventing hydrolysis and foaming at the source.

Oh, you call this 'eco-friendly recycled material'? The moment the customer unpacks it, they smell a sour odor. This directly delivers the smell of the recycling workshop to the end user.

Quick reference by type: zeolite activated carbon adsorption, molecular sieve water in pipes

Materials for deodorizing and moisture absorption all look like 'gray powder,' but the selection completely depends on pore size and intended use. Let's go through them one by one.

Whether the money spent on deodorizer is worth it can be seen the moment the customer opens the package — the nose is more honest than any instrument, and also stricter than an instrument.

Zeolite (molecular sieve type adsorbent): One of the main agents for deodorization, with well-developed micropores and good thermal stability, capable of withstanding extrusion temperatures and commonly used for recycling modified PP/PE materials. Signals for choosing it: scenarios requiring simultaneous deodorization and heat resistance during extrusion. Note: Zeolite itself is a light-colored powder; it doesn't matter with dark-colored materials, but for light-colored transparent materials, pay attention to its effect on color. Zeolites with different pore sizes adsorb different targets: small pores absorb aldehydes, large pores absorb hydrocarbons. Using a combination of two pore sizes provides broader coverage than using just one, which is especially noticeable when the material is very mixed.

Supply Notice: Porous adsorption deodorants and molecular sieve desiccants can be supplied in coordination by Kelon New Materials, with pore size and adsorption capacity data attached for each batch. Kilogram-scale samples are available for preliminary VOC comparison.

Activated carbon: It has broad-spectrum adsorption and works well for odors from organic substances, but its blackness is too high, so it can only be used in dark-colored materials; sprinkling it on light-colored products will make them dirty immediately. Signals for choosing it: black or dark recycled modified materials. Note: Carbon powder is prone to flying and requires good dispersion, otherwise black spots may appear on the surface of the products.

Molecular Sieve Desiccant (Types 3A/4A/5A): Specifically absorbs moisture. Useful for recovering hygroscopic materials like PET, PA, PC, or pellets that have absorbed moisture in warehouses during the plum rain season. Add a little molecular sieve before extrusion to absorb free water, preventing bubbling and hydrolysis during discharge. Indicators for choosing it: hygroscopic substrates and moisture prevention during the rainy season. Note: Once the molecular sieve is saturated, it needs to be reactivated or replaced, and it only absorbs water, it cannot remove odors.

Compound recycled material odor-removing masterbatch: Make the masterbatch with adsorbents and plant extracts, well dispersed, convenient to add, commonly used for automotive interior-grade recycled materials. Signals for choosing it: low VOC, interior parts with odor level requirements. Note: Plant extracts have limited temperature resistance, and excessive processing temperature will cause decomposition and failure.

Plant extract deodorizer: relies on natural plant essential oils or extracts to achieve a dual effect of 'masking and adsorption.' It requires a low addition amount, has a fresh scent, and provides good masking of aldehydes and acidic odors. It is targeted as an environmentally friendly, low-addition deodorizing solution. Signals to choose it: daily necessities, household products, and children's products that are sensitive to odors, as well as light-colored materials where mineral powders are not desired. Note: the heat resistance of plant extracts is generally limited; processing temperatures exceeding 300°C can easily cause decomposition and loss of effectiveness. They are better suited for PP/PE recycled materials in the 200-260°C range; the cost is higher than ordinary zeolites, and they are usually used in combination with porous adsorbents, where adsorption addresses the root cause and plant extracts tackle surface odors, covering both aspects.

That new car plastic smell partly comes from recycled materials that weren't properly removed, so don't just blame the car's interior decoration.

Alternative Comparison: Can imported odor-removing masterbatch be replaced? First, look at this table

Common questions in purchasing recycled materials for automotive interiors: Imported odor-removing masterbatches and imported molecular sieves are expensive—can domestic products suffice? Frankly, for odor removal in general packaging and daily recycled materials, domestic adsorbents are sufficient; however, for automotive interiors with strict low-VOC and odor rating evaluations, comparison still needs to be based on actual odor ratings and VOC measurements. The table below outlines possible alternatives and the prerequisites for verification.

Original imported directionTypical ApplicationsBenchmark solutionSwitch premise
Imported odor-removing masterbatchAutomotive interior recycled PP/PEDomestic composite odor-removing masterbatchCompared in parallel by odor level and actual VOC measurement
Imported zeolite adsorbentGeneral recycled material deodorizationDomestic zeolite/porous silicateCompare deodorization efficiency and residual odor after extrusion
Imported activated carbonDeodorization of dark recycled materialDomestic activated carbonComparison of adsorption amount, dispersion, and black spot control
Imported molecular sieve 3A/4ARecycling PET/PA DryingDomestic molecular sieveCompare water absorption, activation regeneration, and hydrolysis inhibition

The directions listed in the table are for reference in substitution; the actual deodorization effect should be based on measured VOC and odor. The old substitution process: small-scale test → parallel odor/VOC testing → written customer confirmation → small batch → full-scale production.

The choice of deodorant replacement depends on VOC and odor rating. When Kolon New Materials sends kilogram-scale samples of porous adsorbents/molecular sieves, they include pore size and adsorption capacity data, allowing customers to directly compare odor ratings and conduct VOC testing. Decisions can be made based on the data before scaling up.

If too little deodorizer is added, customers complain; if too much is added, the cost becomes unbearable and it may cause a residual smell. The amount should follow the level of contamination of the material.

Quick Industry Scene Check: Who Is Battling with 'Flavor' to the Death

Even when it comes to deodorization, the tolerance for odors is vastly different between ordinary household products and car interiors. The table below breaks it down by industry.

IndustryTypical productsThe parameters the customer asked about firstRecommended planCertification requirements
CarRecycled PP interior panels, pillar trimsOdor level, VOC emissionsCompound deodorizing masterbatch 1%-2%Automobile Industry Odor/VOC Standards
Home appliancesRecycled material casing, drawerUnboxing Odor, VOCZeolite adsorbent 0.5%-1%RoHS, REACH
Daily useRecycling basins and trash cansPungent sour taste masking the flavorAdsorption and masking compoundCorporate internal control
PackagingRecycled PE/PP Film ContainerOdor transfer to contentsFood-grade adsorption solutionGB 4806 Series
Pipes and sheetsRecycling PP/PE rollsDischarge flue gas, hydrolysisMolecular sieve moisture absorption and deodorizationGB/T Related Standards

A real-life scenario: when making automotive recycled PP interior panels, pillar trims, or door panels, customers require that the products pass the OEM's odor level evaluation and VOC limits. The interior space of a car is small and sealed for long periods; in summer, after being exposed to the sun, the dashboard temperature can exceed 80°C. Aldehyde- and acid-based volatiles remaining in the recycled material are released once heated. The OEM uses the standard bottle method for fumigation tests and has dedicated personnel rate the odor. If the odor level does not meet the standard, the product is returned. In such scenarios, relying solely on zeolite adsorption is often insufficient; a composite odor-removing masterbatch is needed—porous adsorbents lock in aldehydes and acids, plant extracts add a layer of pleasant fragrance to mask odors, and 4A molecular sieves absorb free water. The addition rate is generally 0.5%-1.5%, and the processing temperature is often reduced by 5-10°C to minimize degradation. If the parts fail the OEM's odor test, no matter how neatly they are made, they can only be considered scrap.

Dosage and Key Points of Combination: Three Targeted Remedies

The amount needed for deodorizing and moisture absorption should follow the level of 'dirtiness' and 'moisture' of the material, rather than applying a one-size-fits-all approach. The following three points are industry experience.

Recycled material with odor should be handled in two ways: remove the odor if it smells, and absorb moisture if it is wet. Don't expect one package to solve everything.

◆ General odor removal for recycling: Zeolite or porous silicate 0.3%-1.0% can suppress acidic and fishy odors to an acceptable level, sufficient for daily-use packaging grade.

◆ Low-VOC automotive interior: 1%-2% composite deodorizing masterbatch, adsorption with plant extract blend, combined with low-VOC substrates and processing cooling.

◆ Easy hydrolysis / Moisture protection during rainy season: Molecular sieve 0.1%-0.5%, dry free water before extruding recycled PET/PA/PC to suppress hydrolysis bubbling.

There are three more key points for matching: First, deodorization and drying need to be coordinated — if the material is both damp and odorous, dry it first before deodorizing, otherwise moisture will occupy the adsorption channels and reduce deodorization efficiency; second, adsorbents can only hold so much, so don't expect unlimited deodorization. When the material is too dirty, cleaning and sorting at the source is more cost-effective than just adding deodorant; third, be cautious when using dark charcoal powder with light-colored transparent materials, as it can stain the color. For automotive interiors, choose plant extracts that withstand high temperatures for blending, and avoid losing the active components during high-temperature processing; fourth, the carrier of the deodorizing masterbatch must be compatible with the base material. Using a PE carrier for PP material is generally fine, but for PA/PET, a compatible carrier must be selected, otherwise the masterbatch itself can become a new source of contamination.

Recycled material: deodorizing and drying.

Flavor is not hidden; it is fragrant only when tasted again.

Processing and Compliance Red Lines: Avoid These Pitfalls

If deodorizing and moisture absorption are done poorly, you'll either waste money or contaminate the material. The table below lists processing parameters and the corresponding consequences of operations.

link; segment; partReference valueThe consequences of doing wrong
Dry first, then deodorizeMoisture-absorbent materials should be dried first at 80-120°CMoist air occupying the hole → Decreased deodorization efficiency
Adsorbent DispersionUse masterbatch or mix thoroughlyUneven dispersion → localized odor, localized streaking
Processing temperaturePlant extract type temperature control does not get too highExcessive temperature → active ingredients decompose, off-flavor
Molecular sieve regenerationActivate or replace after saturationContinue using after failure → discharge bubbling hydrolysis
Selection of light-colored materialsLight-colored materials choose light-colored adsorbentsCarbon powder pollution → Products turn black and mottled

Compliance Red Lines: Deodorizing and moisture-absorbing agents used in recycled products that come into contact with food must comply with the GB 4806 series; automotive interiors must meet the OEM odor/VOC standards; exports must comply with REACH. Batch COAs and odor or VOC test reports should be filed with the shipment.

FAQ: Five Common Questions from Recycled Material Factories

Q1: Can domestically produced odor-removing desiccants replace imported materials?

For daily use and packaging-grade recycled materials, domestic brands can already serve as replacements; in scenarios such as automotive interiors with low VOC and odor level evaluations, it is recommended to compare based on actual VOC measurements and parallel odor levels. For parallel tests, Cologne New Materials provides reference samples by the kilogram, along with VOC and pore size data for comparison.

Q2: Why is there still a smell even after adding a deodorizer?

Three common reasons: First, the material is too dirty, the adsorption pores are full, so no matter how much you add, it cannot be absorbed, and it needs to be cleaned and sorted first; second, only deodorization is done without drying, so moisture carries the volatiles out together; third, the processing temperature is too high, causing the plant extract to decompose and release odors. Check these three issues accordingly.

Q3: Are molecular sieves the same as ordinary desiccants?

The principle is similar but the uses are different. Ordinary desiccants are packaged in bags to absorb moisture from the environment, while molecular sieves for plastics are added directly into the material to absorb free water inside the resin during the extrusion process. They are heat-resistant and can withstand extrusion temperatures; ordinary desiccants cannot be used as a substitute.

Q4: Will the deodorizer affect the material performance?

Adding a small amount usually has little impact, but adsorbents are powders, and adding too much will affect the chemical and surface effects; Carbon powder can also contaminate light pigments. So keeping it in the range of 0.1%-2% and choosing light-colored adsorbents for light pigments is a prudent approach.

Q5: Can deodorizers control the odor of all recycled materials?

No. The sources of odor in recycled plastic materials are complex—oil residue, degradable small molecules, and cross-contamination. Deodorizers can suppress some of them, but fundamentally, they still rely on source sorting and cleaning. Deodorizers are the "finishing touch," not the "root cure."

Three-step selection checklist: Prepare the chemicals according to the order without redoing

◆ Step 1 · Identify symptoms: First, determine whether it is "smelly" or "watery"—apply odor remover for sour, oily, or fishy smell; apply molecular sieves for soaking and hydrolysis before discharge; mix both if present.

◆ Step 2 · Determine usage: For daily packaging, choose general-purpose zeolite products; for automotive interiors, choose low-VOC compound deodorizing masterbatches; for light colors, avoid charcoal powder; Set the dosage at 0.1%-2% based on dirt and moisture level.

◆ Step 3 · Dry first, then test for odor/VOC and discharge stability in parallel at the kilogram level. After written confirmation by the customer, increase volume.

Does recycled material have odor? Customers are more sensitive than instruments .

Deodorizer relies on its porous structure to adsorb odor molecules, while desiccants use molecular sieve to adsorb moisture and small molecules. Both are often used together for modified recycled materials. Kelong New Materials supplies zeolite, porous silicate deodorizers, and 3A/4A molecular sieves, providing reference data for pore size distribution and adsorption capacity. Different recycled materials (PP/PE/PA/ABS) can be recommended for corresponding systems; kilogram-level samples support VOC and odor grade comparisons first.

Last year, a factory specializing in recycled PP modification had a customer complain of strong odor upon unpacking, and three batches were rejected for three consecutive batches. Kolon New Materials recommended a porous adsorption deodorizer (about 0.5%) and a 4A molecular sieve (about 0.3%) blend, sending kilogram-level samples. After the customer's trial production, VOC detection dropped by about 40%, and the odor level dropped from level 4 to level 2. During the fourth batch shipment, the customer's consignee finally stopped covering their noses, and orders returned to normal. The factory manager said, "You can't cut corners on deodorizer; if you save it, you're losing the customer."

Recycled material smells as soon as you open the package—do you remove odors or just cover the smell?

Statement: The brands, trademarks, and product names mentioned in this article belong to their respective original manufacturers. This article is a third-party material selection knowledge sharing. The grades, parameters, prices, certifications, and application cases mentioned are for reference only. Please refer to the latest official information and batch inspection reports from each manufacturer. This article does not constitute any procurement or investment advice. Readers are responsible for any actions based on it

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