再生PI/PSU/PEI:半导体工装边角料,特种料回收的小众生意

塑料知识科普 发布时间: 2026-09-14 713 阅读

PI, PSU, PEI—saying their names sounds like a tongue twister. Anyone who works with high-temperature components knows that these three are tough cookies. Each one withstands higher temperatures than the last, each one is more expensive than the last, and each one is more precious than the last—but when it comes to cutting costs, nine out of ten factories dare not touch their recycled materials, fearing that performance will collapse once reused. In today’s article, we’ll break down the recycling accounts of these three 'high-temperature nobles': how much can be saved, where the savings come from, and which areas you absolutely shouldn’t overdo.

Spend two minutes first to fully recognize these three. PI is polyimide, the 'big brother' among high-temperature resistant materials. It can withstand over 300°C for long periods and over 400°C briefly without flinching. The golden-yellow PI film (commonly known in the industry as Kapton) is the go-to material for flexible circuit boards and semiconductor packaging insulation. PSU is polysulfone, transparent, chemically resistant, and can be used long-term between -100°C to 175°C. It is well-known for medical devices, water treatment membranes, and transparent chemical-resistant parts. PEI is polyetherimide, with the most well-known brand name being ULTEM. Amber-colored and semi-transparent, it has a glass transition temperature of about 217°C, can be used at 178°C long-term and over 200°C short-term, has a tensile strength over 100 MPa, and comes with V-0 flame retardancy. It is favorite for semiconductor test fixtures and electronic connectors. Ningbo Kelon New Materials Co., Ltd. supplies plastic raw materials, combining industry and trade, stocking common recycled plastics year-round. Special materials like PI/PSU/PEI are lower in volume but the most demanding in quality.

The difference between these three and the common PP or ABS is that their quantities are too small and their sources too specialized. Recycled PI/PSU/PEI available on the market are almost never collected from post-consumer waste, but rather are clean gate runners, scrap, or shavings from semiconductor factories, injection molding plants, or CNC workshops—same grade, single source, and free of oil contamination, so they already know what they are before recycling. Especially for PEI, since the raw material is expensive to begin with, colorless shavings or gate runners shaved in the workshop are collected by specialized buyers, and clean, natural-colored material is valued even higher. Once mixed with other plastics or oil, its value immediately drops by half. When Ningbo Kolon New Materials Co., Ltd. collects this kind of material, they focus on the clean scraps from the factory and don’t use miscellaneous colored materials of unclear origin.

Specialty material recycling is a small business, and what it earns is the word 'clean'.

Don't underestimate this pile of scrap material. The price of one ton of new PEI is enough to buy dozens of tons of ordinary PP; PI films, PI sheets, and rods are even priced by the gram. In a year, semiconductor factories and precision machining shops can accumulate quite a bit of money just from the natural shavings milled in the workshop or the film scraps cut off. But there's a strange phenomenon in this business: specialty recycled materials in circulation outside look pitifully scarce. Why? Because good materials are recycled within the factory’s own closed loop—adding a bit back to the production at one's own workstation, the quantity isn’t large but it’s enough to use, so there’s no need to release it publicly. Material that does appear on the open market is either surplus that can’t be reused internally or scrap of questionable origin. So when you’re looking for recycled PI/PSU/PEI on the market, don’t expect it to be as abundant as PP; you have to rely on specialized channels and dedicated connections to source it.

Another key point of this small business is the term 'original color.' Why is specialty material expensive? Because it is used to make semiconductor test carriers, medical parts, and high-temperature insulation, which are very demanding regarding impurities, ion leaching, and appearance. Even with the same PEI sprue, if it is in its original color, translucent amber, and free of oil stains, its recycling price can be higher; once mixed with black impurities, contaminated with cutting fluid and oil, or if it's unclear whether it is PEI or PSU mixed together, its value is immediately halved and it can only be downgraded for low-demand parts. Therefore, when collecting specialty materials, the first thing is not to ask the price but to check whether the materials are clean and separated. Ningbo Kolong has been involved in this field for many years; when collecting materials, they first look at the original color, then sort by grade, and only after that discuss the price. The principle is simple—the profit of specialty materials lies entirely in the sorting process.

Figure 1 High-temperature resistant special engineering plastics: PI film, PSU fittings, PEI rods and plates

The three can withstand high temperatures, but that doesn't mean they can be arbitrarily remelted.

As soon as special material recycling is mentioned, many people think: anyway, it’s heat-resistant, just melt it down and reuse it. This might barely apply to PEI and PSU, but it’s completely wrong for PI. Although these three all have the label 'high heat resistance,' their behavior is very different, and the recycling approach cannot be generalized.

Let's start with PEI, which is the 'easiest to deal with' among the three. PEI is an amorphous thermoplastic; if the sprue is clean inside the factory, breaking it down, washing, and regranulating it can maintain performance quite well. Industry data has shown that for normally controlled processes, a single recycling of PEI only reduces the glass transition temperature by 2 to 8°C compared to new material—new material is around 217°C, and after one recycling it’s around 213 to 218°C, almost unnoticeable. But repeated recycling is less forgiving: research shows that processing it five times in a row results in the Tg gradually dropping each time, with mechanical properties and appearance deteriorating accordingly. Then there’s PSU, also an amorphous thermoplastic, with a Tg of about 185°C. Clean sprue regranulation can retain most of its performance, and glass fiber reinforcement makes it even more wear-resistant.

To go back to where these materials are used, you'll understand why they are selective. PEI is used for semiconductor test carriers because it can repeatedly maintain its shape in environments at 170-180 degrees during testing, keeping the chip perfectly in place; if the dimensions shift even slightly, an entire batch of tests could fail. PSU is used for medical devices and water treatment membranes because it can withstand repeated high-temperature sterilization, resist acid and alkali corrosion, and is transparent so liquid levels can be seen. PI is used for flexible circuit boards and high-temperature insulation because it remains stable across a wide temperature range from over minus 200 to 400 degrees Celsius, whereas other materials would have melted or become brittle. Precisely because these materials are used in such "can't-make-mistakes" applications, their attitude toward recycled materials is especially cautious—not that they can't be used, but they must be used with complete clarity.

When it comes to PI, the approach changes. Most PIs are thermosetting or have a semi-crystalline structure and simply don't melt. The idea of cleaning them like PP and directly pelletizing is out of the question—they don't melt when heated; they only slowly decompose. Therefore, PI recycling doesn't follow the route of melting and re-pelletizing; it mostly involves physical grinding: turning panels, rods, and film scraps into fine powder, which can then be used as filler in other materials, or decomposed for recovery at high temperatures. In other words, PEI and PSU are "recycled pellets," while PI is more "recycled powder." Don’t try to apply the pelletizing approach to PI. If you don’t understand this and try to pelletize a bunch of PI scraps, the machine will jam immediately.

There's another common point that has to be mentioned: all three are expensive, so the economics of recycling them is very sensitive. People don't care if recycling PP into granules saves a few cents per pound, but a pound of PEI scrap could be worth several pounds of regular material. Therefore, their recycling isn't based on large volume; it's based on 'cleanliness'—natural color, single type, no oily gate areas, which everyone wants to grab; blackened, mixed-color, oily pieces are hard to even give away. The grade table below categorizes them according to the source and form of each of these three types.

LevelMain sourceKey indicatorsTypical uses
Recycling of PI Film ScrapFPC cutting corners with PI filmHigh temperature resistant insulation, with a wide temperature range of -269 to 400°CHigh-temperature insulation film, flexible circuit reinforcement
PI molded plastic/powder recyclingPI board rod CNC planing edgesLong-term resistance above 300°C, suitable for grinding and recyclingHigh-temperature structural components, seals, wear-resistant parts
PSU injection molding grade recycledPSU injection molding clean gateTg about 185℃, long-term -100~175℃Medical devices, water treatment membranes, transparent chemical-resistant components
PSU Extrusion/Transparent Grade RecyclePSU extrusion edgesTransparent and weather-resistant, resistant to inorganic acids, alkalis, and saltsTransparent fittings, insulating parts, food contact parts
PEI (ULTEM) natural-colored sprue recyclingPEI Injection Molding Gate / CNC ChipboardTg about 217°C maintained, UL94 V-0Electronic connectors, semiconductor test fixtures
PEI glass fiber reinforced recycledIn-plant gate of glass fiber reinforced PEIHigh strength and rigidity, dimensionally stableHigh-strength heat-resistant structural components

Explanation: PI/PSU/PEI are all special engineering plastics. Currently, recycling mainly refers to GB/T 40006.1 'Plastics — Recycled Plastics — Part 1: General Rules' and the corporate standards of various manufacturers. Most PI materials are thermosetting/semi-crystalline structures and cannot be re-melted into pellets, primarily being reused as powder, while amorphous thermoplastic PEI/PSU can be crushed and pelletized. The Tg, heat resistance, and other indicators in the table are summarized from publicly available industry information and manufacturers' technical data. For more grades and physical property parameters, refer to the manufacturers' official TDS.

Recycling special materials saves on price differences; what you can't gamble with are the key components.

Are specialty recycled materials cheap? They are cheap, but their cheapness is not the same as the cheapness of PP. PP is a direct cut in the price per ton, while specialty materials are more like 'new material is too expensive, so use some clean recycled material to bring down the cost'—you save on the price difference, but you can't risk it on critical components. That's how the accounting should be done.

Cost itemNew materialRegenerationDifference Explanation
Price per ton of materialVery tallA bit lowerThe price difference for special materials is large, and using clean, natural-colored materials really saves.
Temperature Resistance / Tg RetentionBenchmarkRecycle several degrees at a timeRepeatedly reheating and cumulatively lowering again, don't be greedy for the number of times
Strength and rigidityTallKeep the natural color of the sprueImpurities and mixed oil then decrease significantly
Source stabilityStableNear the factory water inlet/CNC wood chipSmall quantity and limited batches, materials need to be secured in advance
Medical/Semiconductor CertificationSufficient endorsement for new materialsRegeneration needs to be evaluated item by itemFor implant-grade and ultra-clean levels, use ordinary recycled material
Comprehensive costBenchmarkChoosing the right part saves moneyBeing greedy and mixing carelessly will instead cause problems

Taking this account into consideration, the boundary list below helps you determine whether the high-temperature parts you have can use recycled materials.

Suitable for recycling: clean natural PEI sprues for semiconductor test fixtures, electronic connectors, and heat-resistant structural parts; PSU recycled material for transparent chemical-resistant parts; PI powder/molded material for recycling high-temperature insulation and wear-resistant parts.

For long-term high-load key stress-bearing parts, medical implants, and parts with extremely strict requirements for ion leaching and cleanliness: don't gamble with ordinary recycled material; use new material when new material is required.

Don't think about melting and re-pelletizing PI: it doesn't melt, it can only be ground into powder for use as filler or re-pressed; trying to start the machine with a pelleting approach will definitely jam it.

Don't be greedy with the amount: use a small proportion of special recycled material, mix it according to its purpose; if you mix too much, both strength and appearance will collapse.

Stick to clean, natural materials: blackened, mixed-colored, or oily scraps, no matter how cheap, should never be used in high-temperature parts.

Changing materials on semiconductor carriers saves money on scrap and maintains the precision of the carriers.

Let's give a typical scenario example. Ningbo Cologne New Materials Co., Ltd. has handled quite a few cases in the specialty materials field. Below, we will reconstruct according to common situations in the industry.

There is a semiconductor test fixture factory in East China that mainly processes PEI (ULTEM) material. This material is expensive when new, and the shavings from CNC milling and the injection molding sprues in the workshop used to be piled up in a corner, previously treated as waste for convenience. Later, when they calculated the costs, they found that the clean natural-color PEI shavings thrown away each month were worth quite a bit of money, but recycling them themselves was risky as the performance could be unstable. After all, the fixtures need to be repeatedly used in test environments of 170 to 180 degrees Celsius, and if the dimensions are off, the chips cannot be placed correctly.

Later, this factory discussed this matter with Kolon New Materials. Kolon New Materials didn’t quote a price first; instead, they asked about the intended use: whether the carriers would undergo long-term high-temperature testing or intermittent use, how strict the requirements were for dimensional accuracy and strength retention, and whether a small proportion of recycled material would be acceptable. After clarifying these points, their suggestion was: separately collect, crush, and wash the natural-colored, oil-free PEI sprues and shavings from the workshop; separate them by grade; for single-use recycling, ensure proper drying and processing, and blend a small proportion back into non-critical locating carrier parts. For parts with critical locating surfaces or long-term high-load applications, continue using new material and don’t take risks. They also required measuring Tg and tensile strength for each batch, limiting the number of recycling cycles, and strictly forbidding repeated processing of the same batch.

The factory later turned recycling into workshop rules: natural PEI sprues are stored separately, ground separately, and recorded separately; CNC chips are cleaned on the same day and never mixed with other materials. After a year, more than half of the chips that used to be sold by weight as scrap plastic returned to the production line, making the cost chart look much better and the corners of the workshop cleaner. The boss said that if he had known the scraps of special materials were this valuable, he wouldn’t have thrown them away wastefully in the past few years.

By doing this, scrap material is no longer thrown away as waste, effectively reducing costs, while the precision and yield of the components do not drop — because critical parts are always backed up with new material, and recycled material only covers the parts it is meant to. After working with specialty materials for a long time, one comes to realize: this field is not about who dares to use entirely recycled material, but about who can distinguish which parts can use recycled material and which must use new material. This is also why Ningbo Cologne New Materials Co., Ltd., when recycling PI/PSU/PEI, would rather use a small proportion to maintain original color and profitability than fill in with mixed-color material — the cost of specialty materials is saved at the edge where it matters, not in invisible areas.

When choosing recycled materials for high-temperature parts, first ask how much heat resistance is left.

Before selecting materials, first save the following application comparison to your phone and find the level according to the scenario. These three high-temperature nobles are indeed expensive in small quantities, but it's not a problem if used in the right place.

Application scenarioRecommendation LevelPrecautionsWhen not to use
Semiconductor Test Fixtures/ConnectorsPEI natural color sprue recyclingObserve Tg and maintain intensityNew material for critical high-precision positioning parts
High-temperature insulation/wear-resistant structurePI Powder/Molding Plastic RecyclingGrinding and recyclingDo not use if you want to remelt and regranulate
Transparent chemical-resistant/medical equipmentPSU RecyclingResistance to chemicals and complianceAromatic hydrocarbon-resistant, halogenated hydrocarbon
Glass fiber reinforced heat-resistant partPEI Fiber-Reinforced RecycledCheck the fiberglass contentNo authentication identification
High-temperature film/insulationPI film regenerationCheck the thickness and insulationDo not use leftover membranes after consumption
Price-sensitive non-critical partsBlended recyclingsmall proportion mixingDo not use for high-load critical components

High-temperature resistant materials are expensive, and the sense of proportion in recycling them is even more precious—using the right amount saves a lot of money, while greedily using too much ruins your reputation.

Recycled PI/PSU/PEI can save money, but don't overuse it.

Ningbo Kolon New Materials Co., Ltd. has long supplied recycled special engineering plastics such as PI, PSU, and PEI, covering sources like natural-colored PEI sprues, PSU injection molding grade, and PI powder, used in scenarios such as semiconductor test carriers, electronic connectors, high-temperature resistant structural parts, and transparent chemical-resistant parts. How much recycling performance remains for high-temperature resistant transparent materials? Why can't PI be melt regranulated?

Disclaimer: The brands and trademarks mentioned in this article belong to their respective original manufacturers (ULTEM is a registered trademark of SABIC). This article is a third-party material selection knowledge sharing, and the specific grades, parameters, prices, certifications, and other information mentioned are subject to the latest official information from each manufacturer. This article does not constitute any procurement or investment advice.

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