再生TPU热塑性聚氨酯:鞋材车衣软管,弹性体降本靠什么

塑料知识科普 发布时间: 2026-09-13 1279 阅读

For those in the business of shoe materials, car protective films, or hoses, who hasn’t sighed over a stack of price increase notices? New TPU gets more expensive year by year, but rebound doesn’t care about logic or your price list. Once a customer steps on it or squeezes it with their hand, they immediately know if it’s soft, springy, or collapses. Today’s article will clearly explain how to choose recycled TPU, how much rebound can be retained, which type to use for which part, and which pitfalls to avoid.

Let's spend two minutes getting to know the main character. TPU, formally known as thermoplastic polyurethane, is an elastomer composed of 'hard segments and soft segments': the hard segments provide strength, while the soft segments provide elasticity. By adjusting the ratio of hard to soft segments, its hardness can range from Shore 45A all the way to 85D, soft like a rubber band, hard like a plastic shell. It is wear-resistant, has good rebound, and is oil-resistant. The things made from it are things you see every day—sports shoe midsoles and outsoles, automotive paint protection films, pneumatic hoses, soft phone cases, cable sheaths, and sealing rings are all its territory. Ningbo Cologne New Materials Co., Ltd. supplies plastic raw materials, integrating industry and trade, stocks common recycled plastic types year-round, and TPU is one that relies on its tactile feel and resilience.

The sources of recycled TPU mainly come from clean sprues and scraps from shoe material factories, film factories, and hose factories, along with some post-consumer elastic products recycling. Unlike PP or ABS, TPU is divided into two major types: polyester-based and polyether-based. These two have different origins and completely different properties; mixing them together in recycling is like stirring springs and sponges into a mess, ruining performance. Therefore, the first step in recycled TPU processing is not pelletizing, but sorting—polyester with polyester, polyether with polyether, and aliphatic types separately. When Ningbo Kolon New Materials Co., Ltd. prepares recycled TPU, they first ask the customer where it will be used and whether it will be in contact with water, then determine the type accordingly, rather than relying on a single material for everything.

For elastomer regeneration, first separate polyester and polyether; otherwise, rebound is all talk.

Whenever recycled TPU is mentioned, many purchasers feel a bit skeptical: it's an elastomer, so can't it just be remelted and reused? This statement is only half correct. Whether TPU can be recycled first depends on the type of soft segment it has—polyester and polyether have fundamentally different weak points.

Polyester-based TPU has polyester segments. Its strengths are wear resistance, oil resistance, and high tensile strength. It's cost-effective for indoor use at room temperature. The downside is that it is sensitive to water and moisture—polyester chains will hydrolyze over time when exposed to hot water or organic acids, causing surface chalking and cracking. If you use recycled polyester TPU for hoses that are constantly submerged in water, they won't last long. Polyether-based TPU has polyether segments. Its strengths are hydrolysis resistance, mildew resistance, and remaining soft at low temperatures—down to several tens of degrees below zero without becoming brittle. The downside is that its wear and oil resistance are slightly inferior to polyester, and it is more expensive. In the industry, there is a selection rhyme: for dry and wear-resistant use, choose polyester; for water exposure and weather resistance, choose polyether.

This classification becomes even more important during recycling. New polyester is sensitive to water, and recycled polyester, having gone through another cycle and a more complex thermal history, only has an increased risk of hydrolysis; polyether is naturally water-resistant, and if reused properly, its advantages can be preserved. If polyester and polyether are crushed and mixed together for recycling, the two types of soft segments won’t be compatible, and elasticity, wear resistance, and water resistance will all be compromised. The resulting products will be neither soft nor hard, revealing their flaws as soon as the customer squeezes them. Therefore, there is a simple consensus in the recycled TPU industry: recycling within the same type is safest—polyester feedstock should make polyester parts, polyether feedstock should make polyether parts, and different types should not be mixed indiscriminately.

Another type to mention here is aliphatic TPU. The previously mentioned polyester and polyether refer to the soft segment; whether it's aromatic or aliphatic refers to the type of hard segment. Aromatic TPU is cheap and has good mechanical properties, but it tends to yellow over time or when exposed to sunlight; aliphatic TPU contains no benzene ring groups, is UV-resistant, does not yellow, and has good transparency, making it ideal for automotive paint protection films and transparent covers, though it is more expensive. The same principle applies during recycling: the transparent scraps from making paint protection films are only valuable if yellowing is well controlled; using ordinary aromatic recycled material to pass off as yellow-resistant material will reveal itself after a summer in the sun. When it comes to TPU, dealing with types is an unavoidable issue.

Figure 1 TPU film, hose, and soft parts

The soft and hard segments of TPU are like steel bars inserted into a spring

Why does TPU get soft when squeezed and spring back when released? It relies on its structure of 'soft segments acting as springs, hard segments acting as steel reinforcement.' Once you understand this, you'll know which part fails during recycling.

On the molecular chain of TPU, the soft segments are like springs, providing elongation and rebound; the hard segments are like physical crosslinking points, like steel bars holding the springs, maintaining strength and shape. New TPU can achieve a rebound recovery rate of around 90%, with a rebound rate of over 50%, so when pressed down, it quickly springs back. During recycling, the molecular chains are subjected to heat and shear, causing a certain degree of breakage in both hard and soft segments—the spring breaks, slowing and slightly reducing the rebound; the steel bars loosen, and strength and abrasion resistance decrease accordingly. This is why the question of 'how much rebound can remain after recycling' cannot be answered with a single number: clean sprues, fast low-temperature processing, and added additives maintain good rebound; mixed sources and repeatedly reprocessed material result in fluctuating rebound and hardness.

Specifically regarding 'rebound,' there are a few figures in the industry that can be referenced: for running shoe midsoles made of high-performance TPU, the elastic recovery rate can exceed 90%, and the rebound rate can be around 50%; abrasion resistance is several times higher than regular rubber, with very low wear values. These are the levels for new materials. How much reclaimed TPU can maintain depends on its thermal history—if it comes from the same factory sprue, reused once, or processed quickly at low temperatures, the loss in rebound and abrasion is not significant; for repeatedly processed material, the hard segment physical crosslink points are destroyed, and the material gradually becomes 'dead,' compressing with little rebound and stretching decreasing. So when asking 'what percentage of rebound remains after recycling,' the correct answer is not a fixed percentage, but rather: it depends on how many times it has gone through the furnace, whether the type is correct, and whether additives have been replenished.

The proper process for regenerating TPU is: first, sort it by type, then crush, wash, and dry it—TPU has a relatively high water absorption, and granulating it with moisture will cause hydrolysis and degradation, so the drying step cannot be skipped; next, extrude and granulate at low temperature, minimizing heat exposure; finally, depending on the intended use, add some lubricant, anti-hydrolysis agent, and antioxidant to restore the balance between soft and hard segments. For shoe soles and cushioning components, the focus is on rebound and permanent compression deformation; for hoses and sheaths, the focus is on hydrolysis resistance and low-temperature performance. The table below classifies the grades according to type and source.

LevelMain sourceKey indicatorsTypical uses
Polyester-based recycled TPU (clean sprue)Shoe materials/film factory polyester sprueShao's approximately 70A-95A, wear-resistant and oil-resistant, retains good reboundSoles, casters, seals, oil-resistant parts
Polyether-based Recycled TPUPolyether Factory Water GateHydrolysis-resistant, low-temperature flexible, stable reboundWater-resistant hoses, cable sheaths, outdoor components
Aliphatic Recycled TPUCar cover film/transparent film scrapsUV-resistant and does not yellow, with good transparencyCar cover film, transparent protective sleeve, outdoor parts
Shoe Material Foamed Recycled TPUETPU midsole/insole wasteHigh rebound rate, moisture content needs to be strictly controlledInsoles, cushioning components, modified blends
General Blended Recycled TPUMulti-source hybrid granulationHardness drift, performance fluctuation is relatively largeNon-essential buffers, low-end daily necessities
Modified Recycled TPURecycled material with flame retardant or fillerSpecific functions require combined verificationCables, sheaths, functional components

Note: TPU recycling currently mainly refers to GB/T 40006.1 "Plastics – Recycled Plastics – Part 1: General Principles" and the enterprise standards of various manufacturers; the performance differences between polyester, polyether, and aliphatic types are significant. The indicators in the table are summarized from publicly available industry data and manufacturer technical data. For more grades and property parameters, the manufacturer's official TDS shall prevail.

If the rebound is a bit less, the shoes will have a bit less power.

Recycled TPU is cheap, but when it comes to elastomers, you shouldn’t just focus on the price per ton; you need to compare rebound and feel. Think about it: if you save a few bucks per kilogram of material, and it’s made into insoles that collapse after three months of use, that little discount will be lost, and you’ll also risk damaging your reputation.

Why has recycled TPU been so popular in the past two years? Because its application market is huge. For shoe materials, especially foamed midsoles and insoles, the amount of waste is not small; the car film market is expanding rapidly, and scraps from the edges of the film are also increasing; plus, there are hoses, cable sheaths, and phone cases, all providing a stable source of scraps. The problem is that TPU has a high value density and its applications are scattered, so whether recycled material can be used depends heavily on molding and formulation—it’s not something that can be solved just by washing and granulating. Whoever can properly collect similar sprue, control rebound and moisture content will have a solid position in this niche. This is also why, although recycled TPU seems popular, there are very few companies that can truly provide a stable supply.

Cost itemNew TPU materialRecycled TPUDifference Explanation
Price per ton of materialHigherThe same type of sprue is slightly lowerThe price difference for clean water of the same origin is real, and miscellaneous materials are even cheaper.
Rebound retentionHigh resilience, quick recoveryThe clean water outlet is maintained fairly well, and debris rebounds and drops off.Rebound is the lifeline of elastomers; you can tell as soon as you step on it.
Stable hardnessStable batchThermal history different hardness driftIf the hardness is off by a few degrees, the feel is wrong
Hydrolysis-resistantBy typeRecycled polyester is more afraid of waterDo not use recycled polyester for water-related parts
Batch ConsistencyTallThe same factory's nozzle is stable, while mixed materials fluctuate greatlyTime spent on adjusting the machine due to miscellaneous materials
Comprehensive costBenchmarkUsing the same source water inlet is cost-effective, but mixing different types carries high risksYou only save money if the type is right; mixing types saves money in vain.

Combining this account, the following boundary list helps you determine whether the part in your hand can be put on recycled TPU.

Suitable for using recycled TPU: direct reuse of clean water outlets of the same type; indoor dry, non-water-involved wear-resistant cushioning parts; shoe soles, casters, phone cases, ordinary packaging parts.

For items exposed to water, outdoor moisture, or soaking all year round: do not use recycled polyester, use recycled polyether instead.

Car cover film, transparent weather-resistant parts that require no yellowing: make sure to choose aliphatic resin; avoid ordinary aromatic resin.

For high-end insoles that require high resilience and resistance to permanent compression: don’t use miscellaneous materials, check the rebound report.

Food contact and medical-grade parts: must comply accordingly, ordinary recycled materials should not be used.

Finally, a reminder about processing. TPU naturally absorbs moisture, and recycled material even more so. Before molding, be sure to dry it according to the requirements until the moisture content meets the standard; otherwise, when heated, the moisture will break the molecular chains, resulting in parts that are brittle and have surface blisters. Don't just aim for high material temperature either—overheating TPU will cause yellowing and degradation, so just follow the manufacturer's recommended processing window. Also, the hardness of recycled TPU may differ by a few degrees from new material, so mold temperature and injection speed need slight adjustments. Don't rigidly apply the parameters for new material; otherwise, the feel and dimensions won't be correct. These careful steps in processing often affect the final product's feel more than choosing the right material does.

Whether the soles flatten after three months of wear depends on the hardness and softness of the material.

Talk about an experience commonly seen in the insole industry—the work done by Ningbo Cologne New Materials Co., Ltd. is exactly in this field, and the scenario is a typical situation, not referring to any specific company.

There is a factory in the south that makes insoles and cushioning pads. They wanted to reduce costs, so they bought a batch of cheap recycled TPU to make the insoles. The new insoles felt okay when first stepped on—moderately soft and bouncy—but after customers wore them for two or three months, feedback came in: the insoles were flattened, non-returning, and got harder over time. Upon inspection, it turned out that this batch of recycled material had unstable proportions of soft and hard segments and a relatively high moisture content, so its resilience was depleted after repeated bending. A batch of insoles had to be replaced, and the remaining inventory ended up sitting in the warehouse.

Through peer introduction, the owner of this factory made a special visit to Kolon New Materials. Kolon New Materials did not discuss price first; they first asked whether the insoles were for indoor use or frequently exposed to sweat and water, and how high the requirements for rebound durability were. After understanding, the advice given was to stop using that type of mixed material across categories: for indoor, dry insoles, use polyester-type clean water-gate recycled TPU, properly add anti-hydrolysis and lubricants, so rebound can be maintained, and the price is more reasonable than new material; if the insoles are prone to moisture and sweat, do not insist on polyester, switch to polyether-type recycled TPU, which is slightly more expensive but doesn’t hydrolyze and doesn’t easily collapse. At the same time, it is required to measure Shore hardness, rebound, and compressive permanent deformation for each batch, ensure the material is fully dried before running the machine, and never run if the moisture content does not meet the standard.

Kolon New Materials also taught this factory a simple trick: press one test piece each from the new material and the recycled material, then repeatedly bend and knead them by hand dozens of times. The new material shows lines quickly when bent and rebounds immediately; recycled material turns white after just two bends and rebounds more slowly, so you can get a clear idea of the batch. Also, don’t skimp on testing: measure the Shore hardness, rebound rate, and compression set—compare these numbers for each batch to see at a glance whether the batch is stable. The feel of TPU can’t fool the craftsmen who handle it daily, nor can it fool feet that have worn it for three months.

After changing the material, complaints about the insole's rebound significantly decreased, and inventory turnover returned to normal. TPU is something you can't fool feet with—whether the material is good or not will become clear after three months of use. This is also the reason why Ningbo Kolong New Materials Co., Ltd., when compounding recycled TPU, insists on selecting the type based on category and usage instead of just quoting a low price and shipping—when it comes to feel, there's nothing you should cut corners on.

Replace the elastomer with recycled material, first check if it bubbles in water

At this point, make a table of the key points and match them accordingly — reducing the cost of recycled TPU is not a lie, but the premise is not to mix dry components with water-exposed ones, or polyester with polyether. Remember this mnemonic: for dry and wear-resistant, choose polyester; for water-exposed and weather-resistant, choose polyether; for transparent and weather-resistant, go for aliphatic — match these three lines correctly, and recycled TPU will regain its elasticity and avoid defects, and customers will be satisfied with both their feet and hands.

Application scenarioRecommendation LevelPrecautionsWhen to stop using
Sole/Caster Wear-ResistantPolyester-based recycled TPUFor indoor dryingDo not use when wet or damp
Waterproof hoses/cablesPolyether-based Recycled TPUControl water contentDon't touch recycled polyester
Car cover film / transparent protective sleeveAliphatic Recycled TPUYellowing and TransparencyDo not use common aromatic compounds
Insole/Cushioning FoamShoe Material Foamed Recycled TPUObserve rebound and compression deformationDo not use miscellaneous materials
Phone cases / Daily necessitiesGeneral-purpose recycled TPULow costDon't use if high rebound is required
Flame-retardant componentsModified Recycled TPUCheck the flame retardant ratingDo not use without certification

You can tell if an elastomer is elastic just by squeezing it—whether recycled material works or not, stepping on it a couple of times and pinching it a few times is more accurate than reading the report.

Recycled TPU, cost reduction for elastomers depends on grade, not luck

Disclaimer: The brands and trademarks mentioned in this article belong to their respective original manufacturers. This article is a third-party material selection knowledge sharing. The specific grades, parameters, prices, certifications, and other information involved in the text are subject to the latest official data from each manufacturer. This article does not constitute any procurement or investment advice.

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