再生PVDF:锂电涂覆废膜和光伏背板边角料,正在被抢着收

塑料知识科普 发布时间: 2026-09-14 2361 阅读

Anyone working with lithium batteries knows that coated waste films used to be thrown away as garbage, but now there are people who come specifically to collect them. We're talking about PVDF—polyvinylidene fluoride, a fluorine-containing specialty plastic that is indispensable in lithium battery binders, photovoltaic back sheets, and water treatment membranes. New PVDF is very expensive per ton, and the waste film and photovoltaic backsheet scraps from coating processes offer increasing potential for recycling and reuse. This article will break down the accounting of recycled PVDF clearly.

Let's spend two minutes getting to know the main character. Ningbo Kolon New Materials Co., Ltd. has long been dealing with PVDF raw materials, and recycled PVDF is one part of this. PVDF is a fluoropolymer that is resistant to acids and alkalis, weathering, and UV, has good film-forming properties, and is used as a binder for positive and negative electrodes in lithium batteries, as a backsheet protective film in photovoltaics, as a filtration membrane in water treatment, and for corrosion resistance in chemicals. It has a particular feature: like PTFE, it contains fluorine, but PVDF is soluble in solvents like NMP, allowing for solvent recovery, and its recycling process is different from ordinary plastics. The main sources of recycled PVDF are twofold: waste films and scrap from the lithium battery coating process, and edge scraps from photovoltaic backsheet production.

Waste coating films used to be thrown away as garbage, but now there are people who come specifically to collect them.

Factories that do lithium battery coating all have experience with this: the waste films and scraps from cathode coating used to be treated as hazardous waste and required paying someone to remove them. In recent years, things have changed—PVDF is expensive, and the waste films from coating contain a significant amount of PVDF, so there are people who specifically come to collect them. A 2025 industry report gave a figure: among the sources of recycled PVDF, about 41% comes from lithium battery coating waste films, and about 33% comes from photovoltaic backsheet scraps. Together, these two sources are the main supply of recycled PVDF.

Why are the supply sources increasing? Because lithium batteries and photovoltaics have expanded production rapidly in the past two years, leading to more scrap from coated films and backsheet edges. New PVDF material is expensive, so if you recycle PVDF from this waste and use it in scenarios where the requirements aren't extreme, the numbers add up. Recycling fluorinated materials has a threshold, but behind that threshold lies real cost-saving potential.

Why is new PVDF so expensive? Because it contains fluorine, has a complex synthesis process, excels in acid and alkali resistance as well as weather resistance, and emerging industries like lithium batteries and photovoltaics are competing to use it. Lithium battery binders require PVDF to dissolve in NMP solvent, bond firmly, and be consistent across batches; photovoltaic back sheets require it to withstand decades of UV exposure and extreme temperatures. Precisely because other plastics cannot replace it with these properties, the price of new PVDF has remained high. The more expensive the new material, the more cost-effective recycled material appears.

It's not just new materials driving the boom in lithium batteries and photovoltaics; the good times for recycled materials are only just beginning.

Figure 1  Recycled PVDF granules and film rolls (schematic diagram)

PVDF contains fluorine, and its recycling follows the solvent recovery route.

When breaking down recycled PVDF by source and form, it roughly corresponds to the table below (the indicators are a general summary of industry norms, and the specifics should follow the manufacturer's TDS). For PVDF, source and purity are hard indicators: materials recovered from lithium battery coating waste films have relatively high purity, offcuts from photovoltaic back sheets are next, and those from chemical pipelines are a tier cheaper.

LevelTypical sourceKey indicatorsTypical applications
Lithium battery grade regenerated PVDFRecycling of waste films from lithium battery coatingHigh purity, stable viscosityAdhesive for non-critical parts of lithium batteries
Photovoltaic-grade recycled PVDFPhotovoltaic backsheet scrapsWeather-resistant and UV-resistantPhotovoltaic backsheet, junction box bracket
Chemical-grade recycled PVDFChemical piping, lining cornersAcid and alkali resistantAnti-corrosion lining, pipe fittings
Powdered Recycled PVDFMembrane material, coating wastePowder formCoatings, modified additives
Granulated Recycled PVDFVarious edge granulationsGranularInjection molded extruded parts
Low-purity recycled PVDFMixed recycled materialsLow priceGeneral anticorrosion, packing

Market reference: PVDF virgin material prices are high, while recycled material has a prominent cost-performance advantage in non-extreme scenarios. When Ningbo Kelon New Materials Co., Ltd. reports PVDF material prices, they usually first ask whether the downstream application is for photovoltaic backplanes or chemical corrosion protection, and whether lithium battery-grade purity is needed, then they classify the grade based on the source and purity — because in the PVDF industry, if you ask for the wrong purity, you can't use cheap material in critical parts.

A bit more about the process of recycling PVDF. PVDF can dissolve in solvents like NMP, so waste lithium battery coating films can be recovered using solvents—dissolving, purifying, and then precipitating the PVDF from waste films to make PVDF resin close to new material. This method is cleaner than physical crushing, offers higher purity, and is suitable for high-demand applications like lithium batteries. Waste edges of photovoltaic back sheets are a bit harder to recycle because they carry coatings and adhesives, and are often used in non-extreme applications such as back sheet supports and corrosion protection.

The downstream use also has a scope. In 2025, in the downstream consumption of recycled PVDF, lithium battery binders and coating materials account for about 63%, photovoltaic backsheet resins about 22%, water treatment membranes about 10%, and electronic encapsulation adhesives about 5%. In other words, most recycled PVDF still goes back to lithium batteries and photovoltaics, but it is used in non-critical parts—the binders in critical parts of batteries still use newly certified materials or high-purity recycled materials.

The threshold for lithium batteries is particularly high. The battery binder uses PVDF, which must meet the technical specifications of both automakers and battery manufacturers, with batch viscosity and swelling rate strictly controlled. Public information mentions that a leading battery company's own corporate technical specifications impose strict limits on the deviation of the swelling rate of recycled PVDF, and there are not many production grades that can reach this level. In other words, for recycled PVDF to be directly used in the most critical binder part of lithium batteries, the threshold is very high; but for use in non-critical parts of lithium batteries, photovoltaic supports, or chemical corrosion protection, the standards are much more relaxed.

Weather resistance is a rigid requirement in the photovoltaic field. Junction box brackets are exposed to the sun year-round, with 90-degree high temperatures and ultraviolet rays, causing materials to easily yellow and become brittle. According to some supplier test data, photovoltaic-grade recycled PVDF has a very low yellowing index under these conditions, much better than ordinary modified ABS. Therefore, photovoltaic brackets are a very suitable application for recycled PVDF—they are weather-resistant and cheaper than virgin PVDF, making it cost-effective for manufacturers.

Then distinguish PVDF from the other nearby fluorinated materials. PTFE does not melt and can only be ground into powder and sintered; PVDF can dissolve in solvents and be recovered through solvent processing. Don’t confuse these two—PTFE recycling is based on mesh size, while PVDF recycling depends on source and purity. When collecting materials, separate PTFE turning scraps from PVDF coating waste film; if they get mixed, the process cannot be applied, and the material is wasted. Although both types of fluorinated materials are valuable, their recycling methods are different.

The account of recycled PVDF: new material is expensive, recycled material has a lot of potential.

The accounts for recycled PVDF cannot be compared solely based on the price per kilogram. Consider the price, purity, certifications, and operating conditions together:

Cost itemBrand new PVDFRecycled PVDFDifference Explanation
Raw material purchase priceTallA bit lowerThe price difference varies greatly with different purity levels
PurityconsistentHigh solvent recoveryMixed recycling has low purity
Key components of lithium batteriesMust useCertification requiredNon-critical parts can be mixed with recycled material
Photovoltaic Weather ResistanceGoodSufficient at the motherboard levelLong-term outdoor pre-validation
Acid and alkali resistantStableChemical grade is sufficientExtreme conditions are based on new material
Full-year comprehensivesuperficially expensiveNon-critical parts cost-savingDo not use for high-purity lithium batteries or food contact

If you thoroughly study this table, you'll find that the real cost-effectiveness of recycled PVDF isn't in the critical binder for lithium batteries, but in fully understanding applications like photovoltaic brackets, chemical anti-corrosion, and water treatment membranes—scenarios that require high weather and corrosion resistance but where purity hasn't been pushed to the limit. In these scenarios, using recycled PVDF provides sufficient weather and chemical resistance, and the price is lower than virgin material. On the other hand, for critical lithium battery binders or high-purity semiconductor components, any failure can lead to battery safety incidents—don't gamble to save on materials.

Let me say a bit more about the market here. The price of recycled PVDF follows that of new PVDF and the overall trend of the lithium battery and photovoltaic industries. When the expansion of new energy is fast, there is a lot of supply from coated waste films and leftover corners of backplanes, making recycled material prices favorable. For manufacturers in the photovoltaic and corrosion protection sectors, it's important to keep an eye on supply sources and stock up a bit during periods when waste is abundant, which can help further reduce costs. The key is to distinguish the sources—materials recycled from lithium battery films and those recovered from chemical pipelines differ significantly in their applications.

Here's a practical tip. When sourcing recycled PVDF externally, don't just look at the price; first ask whether the material comes from lithium battery film or from photovoltaic backsheet, and whether it has gone through solvent purification. Material from lithium battery film with recovered solvent has high purity and can be used in parts with high requirements; material from chemical pipelines is cheaper but has more impurities and can only be used for ordinary corrosion protection. Using material from the matching source for your working conditions is a more reliable combination. First make small samples of externally sourced material to test weather resistance, and only scale up if it passes.

Opening up boundaries—Which working conditions to be mindful of, and which ones not to force:

Use with confidence: photovoltaic backsheet, junction box bracket, chemical corrosion-resistant liner, water treatment membrane, paint additives.

Use with caution: For non-critical parts of lithium batteries, make sure to use standardized high-purity recycled materials.

First verify: long-term outdoor weather-resistant parts, checking for yellowing and UV aging.

Do not touch: high-purity lithium battery key binders, food contact materials, aviation certified parts.

Procurement actions: You need the source, you need the purity, you need the viscosity data; don't just ask how much per kilogram.

The journey of a roll of coated waste film: from scrap material to junction box bracket

Let's talk about a typical experience in a photovoltaic factory (this is a pieced-together scenario, don't take it as news). There is a factory in Ningbo that makes photovoltaic junction box brackets. They used to use brand-new PVDF to make brackets, and the leftover film from the coating process and the leftover corners of the backsheet were treated as waste. The new material was expensive, and the boss always felt that the cost of photovoltaic components couldn't be reduced.

Later, they matched the two ends: recycling the photovoltaic backsheet scraps and coating waste films, sorting them by source, purifying them with solvents, and granulating them to produce photovoltaic-grade recycled PVDF pellets, used for junction box brackets under long-term conditions of 90-degree heat plus UV radiation. Ningbo Kolon New Materials Co., Ltd. helped streamline this step—first conducting yellowing tests; the recycled material showed very little yellowing under these conditions, far better than ordinary modified ABS, and once batch consistency was confirmed, they proceeded to mass production. After streamlining, the amount of externally purchased new PVDF decreased significantly, the source of the waste was clarified, and the weather resistance of the brackets remained stable.

They also fell into pitfalls. The first time they used a batch of recycled PVDF with an unclear source, the brackets they made yellowed and became brittle after being exposed for six months. Later, they strictly controlled the source—only PVDF-grade material recovered from the edges of photovoltaic back sheets and from leftover coating films of lithium batteries, with each batch tested for yellowing before use—and the problem disappeared. This case shows: recycling PVDF saves on material costs, but the premise is not to be vague about the source and purity.

Running the numbers: using photovoltaic-grade recycled PVDF for brackets, the material cost is lower than brand-new material, and samples from outdoor aging tests still pass, so downstream users can rely on it. What this case shows is not complicated: the profit from recycled PVDF comes from using the leftover edges of lithium battery and photovoltaic films in non-critical photovoltaic conditions. Ningbo Kolon New Materials Co., Ltd. is engaged in PVDF recycling supply, and what they do is not just selling a bag of pellets—they help downstream users with sorting sources, ensuring purity, and matching to operating conditions.

When selecting recycled PVDF, first ask about the source, then ask about the purity.

Put the common working conditions and their corresponding levels together, so you can easily refer to them when making a plan:

Application scenarioRecommendation LevelPrecautionsWhen not to use
Photovoltaic backsheet, bracketPhotovoltaic-grade recycled PVDFCheck weather resistance and yellowingHigh-purity outdoor parts to be verified first
Non-critical parts of lithium batteryLithium battery grade regenerated PVDFCheck the purity and certificationNew material for key adhesive
Chemical anti-corrosion liningChemical-grade recycled PVDFCheck acid and alkali resistant batchHigh-purity medium, handle with care
Water treatment membranePowdered Recycled PVDFCheck the purity and particle sizeDrinkable grade must first pass compliance
Paint modification additiveLow-purity recycled PVDFPrice PriorityDo not use high-end coating

Let me mention another common misconception. Some people shake their heads when they hear 'recycled PVDF,' thinking that fluorinated specialty material definitely won't work after being recycled. In fact, material from well-done solvent recovery is nearly as pure as virgin material and is perfectly adequate for use in photovoltaic brackets and chemical corrosion protection. The real problem isn't 'recycling'; it's when the source is unclear, the purity doesn't meet standards, and it is used in critical parts of lithium batteries. If the source and purity are strictly controlled, recycled PVDF is an underrated material.

How much recycled material is appropriate to mix into new PVDF? For photovoltaic brackets and ordinary anti-corrosion parts, photovoltaic-grade recycled material can be used with confidence. For non-critical parts of lithium batteries, start with a small proportion and increase it only after each batch passes viscosity and purity tests. Don’t just start with a large proportion forcefully—mixing material of unknown origin into critical parts can cause major problems. In the PVDF industry, the proportion of mixing must be handled more cautiously than with other plastics.

Let's be clear: recycled PVDF is not some well-established, old business; it has only started to heat up in the past couple of years alongside lithium batteries and photovoltaics. No matter how expensive new material is, coated waste films and backsheet edges are real PVDF; if you sort and purify it according to its source and use it in the right parts of photovoltaics and corrosion protection, the cost can be reduced by a significant amount. The sooner you act, the more proactive you can be. Don’t wait until waste piles up, costs can’t be lowered, and customers are pressing for cost reductions before you remember this — by then, it will really be too late. Don't wait until that step to take action; remember this. The boom brought by lithium batteries and photovoltaics isn’t just for new material; the good days for recycled material are just beginning.

Let me talk about something related to orders. Nowadays, many lithium battery and photovoltaic manufacturers are advocating for a circular economy and carbon reduction, using recycled PVDF in their own products. This not only reduces costs but also serves as an environmental story for external communication. Getting the supply chain for the compatible recycled PVDF sorted out in advance is equivalent to having an extra card to play when responding to such requirements. If you wait until the customer makes a request to source materials, it's usually too late; normally, managing your sources well allows you to provide stable batches whenever needed.

When purchasing recycled PVDF, here’s a practical step for you: for the first cooperation, start with a small sample. Ask clearly about the source of the material, its purity, and whether its viscosity is stable. Run a few of your typical parts on the machine, and only after testing for weather resistance or acid resistance should you discuss bulk orders. The trick with recycled PVDF isn’t in a single batch, but whether the purity and viscosity fluctuate between batches — make the acceptance criteria clear, and include data with each shipment, which is more reliable than verbal assurances.

The new PVDF can withstand the most critical step of lithium batteries, and recycled PVDF can meet the essentials of photovoltaics and corrosion protection—choosing the right part makes waste also a treasure.

Using recycled PVDF in the right parts is the only way to save costs.

Disclaimer: The brands and trademarks mentioned in this article belong to their respective original manufacturers. This article is a third-party material selection knowledge sharing. The specific grades, parameters, prices, certifications, and other information involved in the text are subject to the latest official data from each manufacturer. This article does not constitute any procurement or investment advice.

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