光伏连接器接线盒用尼龙:户外 25 年,是场老化考试

塑料知识科普 发布时间: 2026-09-15 1413 阅读

When selecting materials for photovoltaic components, many people first look at strength and flame retardancy.

But the greatest uniqueness of photovoltaic components is written in the five words 'outdoor 25 years'.

Not one year, not three years, it's a design life of 25 years, and it also has to endure exposure to the sun, rain, humidity, temperature differences, salt spray, and ammonia.

This is an aging test, not a strength test.

This article explains the two types of components, photovoltaic connectors and junction boxes, and where the threshold for materials actually lies.

Let's start with a scene.

The summer before last, I went with a power plant maintenance team to a centralized power station in the northwest. On the Gobi Desert, the surface temperature was close to sixty degrees. A maintenance worker opened a junction box to show us: the nylon terminal blocks inside had already turned powdery on the surface, and a scratch from a fingernail left a white mark, with the plastic layer flaking off like puff pastry. In the same box, another brand's component installed five years earlier had only darkened in color, with its structure intact.

Where is the difference? In the formulas of the two parts, the grade of the weather-resistant system differs by one level. Photovoltaics are the harshest scenario for all nylon applications, with the most intense sun, the longest periods of humidity and heat, and the largest day-night temperature differences. Material aging is accelerated to the extreme here — which is why the failure of photovoltaic parts is mostly not due to strength, but due to aging.

This article follows the main thread of 'aging' to discuss material selection for photovoltaics. First, it looks at the evaluation points for connectors and junction boxes separately, then explains the double 85 wet-heat aging watershed thoroughly, and finally addresses the issue of CTI dropping under humidity and heat—this point echoes the one in the high-voltage connector article, but the aging conditions in photovoltaics are harsher.

The inverter casing has separate requirements for weather resistance and flame retardancy. The last five pitfalls are supplemented with boundaries. For readers working on photovoltaic module support, after reading, remember to compare the aging verification checklist in the text with your own suppliers.

1. The failure of photovoltaic components is mostly due to aging.

First, distinguish between the two aging pathways:

Path One · Ultraviolet Aging (Surface)

Ultraviolet rays in sunlight can break polymer chains, which manifests as:

Surface chalking, discoloration, loss of gloss - surface cracking, forming microcracks - mechanical properties begin to decline from the surface

Pathway Two · Damp-Heat Aging (Internal)

The combination of high temperature and high humidity will do two things at the same time:

Causing the material to absorb moisture, resulting in dimensional changes and decreased insulation - Accelerated hydrolysis and chain scission at high temperatures

For nylon, the second path is more deadly. Because nylon naturally absorbs water, while the operating environment of photovoltaic components is damp and hot all year round.

The two pathways accelerate each other: after surface UV cracking, moisture enters more easily, while internal humidity and heat age faster.

A judgment: When selecting photovoltaic components, first consider 'weather resistance' and 'humidity-heat resistance' separately. They are not the same thing, and the remedies are different.

2. Connectors and Junction Boxes: What to Look at Separately

pieceMaterial directionKey indicators
Photovoltaic connector housingPA66-GF Weather-Resistant System / PPAUL94 V0, CTI, UV resistant, humidity resistant
Connector adhesive corePA66-GF / PA6TCTI, dimensional stability, temperature resistance
Junction box bodyPA66-GF Weather Resistant Flame RetardantV0, UV-resistant, hydrolysis-resistant, dimensionally stable
Junction box coverPA66 / PA6TWeather resistance, light transmittance (partially needs to be transparent)
Potting basePA66-GF / PBTCompatible with potting compounds, temperature-resistant
Inverter casingFlame-retardant PA66-GF / PPAV0, weather resistance, rigidity
Bracket / Mounting PartsPA66-GF30Rigid, creep-resistant, weather-resistant

The most picky thing here is the connector housing.

Because it needs to simultaneously meet: flame retardant V0, high CTI, UV resistance, moisture and heat resistance, mechanical strength, and 25 years outdoors. When these six requirements are combined, PA66 with a weather-resistant system can cover most cases, but for higher-demand scenarios, one has to turn to PPA or PA6T.

The connector has a special requirement: it cannot 'leak more as it gets older'

A photovoltaic system is a high-voltage direct current (commonly 1000V / 1500V system).

Leakage tracking under DC is more severe than under AC, because DC arcs are not easily extinguished.

Therefore, the CTI of photovoltaic connectors is required to be higher than that of general AC components. Moreover, this CTI must still meet the standard after aging, not just the data at the time of manufacture.

3. Double 85: The Watershed of Humid Heat Aging

In the photovoltaic industry, there is an unavoidable test: the Double 85.

85℃ 85% relative humidity, maintained for a certain period of time (commonly 1000 hours).

Its meaning is: to compress the humid and hot outdoor environment into the laboratory, to see the state of the materials after several years.

Why specifically mention this?

Because much of the promotion of 'weather-resistant nylon' refers to UV resistance, while the DuPont 85 test is about moisture-heat resistance. These are two different things, but many suppliers only address one.

When selecting materials, you need to ask three questions clearly:

1. How many hours did Double 85 work?

2. What is the mechanical retention rate after aging? (Not 'no change in appearance')

3. What is the CTI after aging?

If you can't answer any of the three sentences, it means this material wasn't intended for use in photovoltaics.

What else should be looked at after Double 85?

In addition to the three items mentioned earlier, there is another often overlooked correlation: appearance changes are actually an electrical performance issue.

Once the surface starts to chalk or develop microcracks, stains adhere more easily, and stains are one of the conditions for CTI failure. Therefore, 'appearance changes' on photovoltaic components are not an aesthetic issue.

In the acceptance criteria, it is best to consider the surface chalking level and CTI retention rate together, rather than evaluating them separately—looking at them separately can easily result in a combination of 'appearance qualified, electrical performance downgraded'.

Aging conditionsWhat examTypical duration
Ultraviolet accelerated agingSurface weather resistanceAccording to standards, it is often converted based on the equivalent outdoor annual life.
Dual 85 (85°C/85% RH)Damp-heat HydrolysisCommon 1000 hours
Temperature cyclingThermal expansion and contraction fatigueaccording to the standard
Salt sprayCoastal environmentaccording to the standard
Ammonia-resistantAgricultural Photovoltaics (Ammonia Corrosion)Depends on the situation

Pay attention to the last line: ammonia resistance. This is a special requirement for agricultural photovoltaics (especially the rooftops of livestock farms), which ordinary weather-resistant systems may not cover. If the project is in an agri-PV complementary scenario, this point must be mentioned separately.

There is another part in the junction box that is prone to leaking: the insulation near the bypass diode.

This position has a higher temperature than other parts of the enclosure and is subjected to long-term thermal cycling. The insulating components need to be considered for both temperature resistance and electrical performance after long-term thermal aging.

If materials are selected based solely on the temperature requirements of the box body itself, this position is often the first place to encounter problems.

4. CTI will lose performance under hot and humid conditions

This is the one that is easiest to be overlooked and has the most serious consequences.

CTI is not a factory value; it will decrease with moisture absorption and aging.

The reason is clear in terms of the mechanism: CTI failure requires 'voltage, moisture, and contamination,' and moisture absorption itself creates conditions for the failure.

So:

For components tested with a CTI of 600V at the factory, after damp-heat aging, the value may drop to 500V or even lower. Outdoor dust, bird droppings, and salt deposits can further reduce surface resistance. After surface ultraviolet chalking, it is easier for dirt to accumulate.

Stacked together, these three points represent the typical path of 'passing factory inspection but developing problems a few years after installation'.

The correct approach is: require suppliers to provide aged CTI data and maintain a safety margin based on the aged data.

One more thing: CTI validation should be done according to the structure and thickness of the actual part. There will be differences between the data of standard samples and the actual parts—thin walls, inserts, and locations with holes behave differently from standard samples. For critical parts, it is best to perform part-level validation and not directly refer to material data.

In one sentence: When selecting photovoltaic components, 'factory data' can only be used as a reference, while 'post-aging data' is the basis for design.

5. Inverter housing: Flame retardant and weather resistance must be addressed simultaneously

The inverter casing is another major component in the photovoltaic system and requires a more comprehensive approach:

Flame retardant: UL94 V0, halogen-free trend, GWIT- Weather resistance: long-term outdoor, ultraviolet, humidity and heat- Rigidity: large-size parts, installation and fixation- Temperature resistance: internal power devices, high ambient temperature

The most common mistake here is 'satisfy fire resistance first, then add weather resistance'.

Because flame retardant systems (especially halogen-free ones with high loading) can affect the weather resistance and toughness of materials, conversely, weathering additives can also affect flame retardant efficiency. For such composite requirements, it is best to find formulations that can handle both flame retardancy and weather resistance, rather than trying to piece together the requirements yourself.

There is another type of location that needs to be evaluated separately: near the fans and air inlets and outlets.

These locations, in addition to being weather-resistant, also need to withstand alternating dust and moisture. The aging pace of materials here is completely different from sealed areas—alternating dry and wet conditions damage the materials more than prolonged dampness.

If the project is in an area with heavy dust, the materials in such locations need to be considered separately and cannot follow the conclusions for the main body of the enclosure.

Behind the number 85 twice

In the photovoltaic industry, people always mention 'Double 85', but many tender documents only specify temperature and humidity, without specifying time and criteria. This makes the value of 'Double 85' vary greatly. One thousand hours and two thousand hours are two different things; measuring appearance after damp heat and measuring insulation or CTI after damp heat are two different things.

We recommend that photovoltaic supporting companies write the 'double 85' acceptance clauses in detail themselves: duration should be set according to product positioning, with indoor supporting parts tested for a baseline of 1,000 hours and outdoor exposed parts for 2,000 directly; after testing, add three more tests—insulation resistance, CTI, and appearance chalking, and failing any one of them counts as not passing.

Another advantage of writing detailed specifications is screening suppliers: those who can provide reports according to the detailed rules indicate they have actually done the work; those who can only give a general certificate of conformity are mostly copied. 'Double 85' is not just a slogan; it is a set of verifiable numbers. Turn it into an attachment to your procurement documents, and you will avoid half of the pitfalls caused by aging.

6. Five Pits

Pitfall 1: Treating 'UV resistance' as 'humidity and heat resistance.' Two aging paths, two sets of additives. If it can't pass Double 85, it can't be used in photovoltaics.

Pitfall 2: Only look at the factory CTI. CTI declines with aging, so the design should reserve margin according to the aged value.

Pitfall 3: Ignoring the particularities of high-voltage DC. DC leakage tracking is more severe, and the CTI requirements are higher than those for AC components.

Pitfall 4: Forgetting the local environment. Coastal areas require salt mist resistance, agricultural areas need ammonia resistance, and high altitudes require stronger UV protection. Photovoltaic projects are 'material selection based on location.'

Pitfall 5: Ignoring the compatibility of potting compound with the junction box. When potting parts are in long-term contact with the potting compound, the compatibility of the material with the compound must be tested together, otherwise interface cracking may occur.

7. Borders

SceneConclusionExplanation
Ordinary roof photovoltaicPA66 Weather-Resistant SystemMainstream solution
Coastal / High Salt FogNeeds improved weather resistanceSalt spray test must be done
Agrivoltaics (Ammonia Environment)Requires special verificationThe ordinary weather-resistant system is not enough
Long-term >120℃ partsPA6T / PPAChange the system according to temperature
High CTI, thin-walled, outdoorThe most difficultIt is recommended to start with a compound formula early.

A real feeling in the industry

In photovoltaic inquiries, the question we are most frequently asked is: 'Is your material weather-resistant?'

The term 'weather-resistant' sounds very clear, but it is actually quite vague — it contains at least three meanings: UV resistance, resistance to damp heat, and resistance to salt spray/ammonia.

We usually break it down into four questions:

1. In which region is the project located? (Coastal, inland, agricultural/solar?)

2. Have you ever done double 85? How many hours does it require?

3. Is the item a connector, a junction box, or is it inside the inverter?

4. Is there a CTI requirement, and if so, how much?

After asking four questions, many clients realize on their own: what they want is not 'weather resistance,' but 'resistance in certain environments and specific indicators after aging.'

The thing photovoltaic components fear most is the phrase 'close enough is fine.' Because the verification cycle in this industry is too long—problems with the components don’t show up during the prototyping stage, but three to five years after installation. At that time, the cost of rework can affect an entire solar power plant.

So for this type of project, we would rather ask a few more questions in the early stages, making the requirements even more detailed than the client themselves have imagined.

Some people have materials to sell, but it’s not certain you can get a judgment. In photovoltaic parts, this sentence is especially valuable.

Three Reader Inquiries

Follow-up Question 1: What are the material selection differences between rooftop distributed systems and ground power stations? The core difference is temperature and ventilation. Rooftop distributed systems are installed close to the roof, with poor backsheet ventilation. The junction box of the modules has a consistently higher temperature than that of ground power stations, which accelerates the rate of moisture-heat aging. Therefore, it is recommended to upgrade the material grade by half a level overall, focusing on long-term temperature resistance and hydrolysis stability.

The advantage of ground-mounted power plants is good ventilation, but the wind, sand, and ultraviolet are harsher, which in turn requires a more durable weather-resistant system. First, look at the installation form, then decide on the material grade; this is the first step in photovoltaic material selection.

Follow-up Question 2: The component warranty is 25 years. How do plastic parts stand on this? A practical approach is to separate the assessment by part: structural components like junction box bodies and connectors are justified with accelerated aging models using double 85 heating cycles; elastomers like sealing rings and potting adhesives are evaluated using compression set curves.

No one can realistically test 25 years, and the bidders are aware of this. What they are looking for is whether your accelerated verification logic is complete and the evidence chain is honest. Suppliers who dare to write out their models and assumptions are actually more likely to earn trust.

Finally, a small factory audit tip for photovoltaic accessory companies outside of trade shows: focus on three corners in the supplier's workshop—whether the sample room has physical samples archived by batch, whether the aging chamber runs samples from your industry peers' orders, and whether the pigment storage is managed with zone labeling. Spending ten minutes in these three corners is more revealing than looking at any certificate wall.

Empty sample rooms mean that if problems arise, there are no comparison samples available; underfilled aging chambers mean you have to calculate the reliability of the double 85 report yourself.

Double 85 Acceptance Clause Checklist

Provide photovoltaic accessory procurement with a directly usable double 85 specification: test conditions should specify 85 degrees Celsius, 85% relative humidity, and staged durations, with indoor components at no less than 1,000 hours and outdoor exposed components at no less than 2,000 hours; after the test, measure three additional items: insulation resistance decay must not exceed one order of magnitude, CTI should remain at its original level or drop only one level, and there should be no powdering or cracking on the surface;

Sample quantities should be drawn per batch and meet minimum specified amounts, with reports issued by third-party agencies; attach retained samples beyond the report, kept until the warranty period ends. Combining these four detailed rules turns 'double 85' from an industry buzzword into a verifiable, accountable technical clause. The first time this is implemented, a batch of suppliers will be eliminated, which is normal. Most eliminated suppliers are not incapable, just never truly qualified. After screening, the market will be much cleaner, and your after-sales data will prove the value of each selection.

Final reminder regarding contract clause alignment: double 85 reports must be linked to batch validity in contracts; a single report does not cover everything. Any changes, such as formula adjustments, switching fiberglass suppliers, or changing pigments, should prompt re-evaluation of the original report's effectiveness. The contract should clearly state obligations and cost responsibility for retesting triggered by changes.

Many photovoltaic after-sales disputes stem from suppliers switching fiberglass providers three years ago, causing performance to quietly decline while the customer still relies on outdated reports. The clearer the terms, the longer the cooperation, which is a consensus gained at the cost of experience in the photovoltaic supply chain.

Conclusion

When selecting materials for photovoltaic connectors and junction boxes, three sentences are enough:

First distinguish between UV resistance and heat-moisture resistance; then use double 85 to screen materials; finally, leave a CTI margin after aging.

For outdoor 25-year service, what matters is not how strong it can endure, but how long it remains unchanged.

For modified nylon: PA6, PA66, PA46, PA11, PA12, PA6T, PA9T, nylon alloys. For modified PPO, PPS, thermoplastic elastomers. Work with major chemical giants' nylon resins, secondary-brand materials, and bulk materials.

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