耐候抗 UV 尼龙怎么选?失效不是断,是慢慢不行了

塑料知识科普 发布时间: 2026-09-14 918 阅读

Nylon parts used outdoors usually don't fail by 'breaking,' but rather by 'gradually wearing out.'

Specifically, it manifests as: darkening and yellowing of the color, powdery surface, crumbling when pinched, and a gradual decrease in strength year by year.

This process is called aging, and the main factor that accelerates it is ultraviolet light.

Weather-resistant modification seems to be just 'adding UV-resistant additives,' but the real solution requires the coordination of three types of systems. Adding just one often doesn't last more than a few years.

1. Why Nylon is afraid of UV

Nylon's molecular chain contains amide groups. Under the combined action of ultraviolet light (especially in the UV-B and UV-A bands) and oxygen, photo-oxidation reactions occur.

The consequence of the reaction is:

① Molecular chain breakage. When the chain breaks, the molecular weight decreases, and the mechanical properties decrease accordingly — manifested as brittleness and reduced strength.

② Formation of hair color groups. The new structures generated during the breaking process absorb visible light, appearing as yellowing.

③ Surface degradation. The reaction initially occurs on the surface, manifested as powdering, loss of gloss, and roughness.

The three consequences are different aspects of the same process. Therefore, weathering plans should address all three points simultaneously.

Be aware: heat and light can accelerate each other. Outdoor components are often exposed to both heat and sunlight, and their aging speed is faster than what is estimated by testing under a single condition in the laboratory.

The outdoor fitness equipment in the residential community is the most honest testing ground for weather resistance. An old purchaser from an equipment factory once said something: the same batch of self-locking nut covers, after being installed on the north side of the building for five years, remained dark gray, but on the rooftop platform, they turned white and brittle by the second year. Different locations result in a lifespan difference of twice as much.

He later developed the habit in inquiries of first clarifying the installation orientation and region. East China, South China, and the plateau—three levels of UV intensity, three sets of formulation answers.

In the plan we provided for him, the dark-colored parts were enhanced with a composite system of carbon black and hindered amines, while the light-colored parts used only titanium dioxide with a high-stability formula. The price differs by 20%, and the expected lifespan differs by three times.

He once made a summary: The money spent on outdoor activities is not spent on the materials, but on the sun.

2. The three components of the weathering system

ComponentFunctionExplanation
Ultraviolet Absorbent (UVA)Absorb UV and convert it into heat to dissipateProtects the material itself, with limited protection for the surface layer
Hindered Amine Light Stabilizer (HALS)Capture free radicals, block chain reactionsAnti-aging core, synergizes with UVA
Pigment / Carbon BlackPhysically block ultraviolet raysCarbon black works best, and it is also the reason why darker parts are more weather-resistant.

The division of labor among the three is very clear:

UVA tube 'less come in'

Even if the 'HALS pipe' comes in, don't spread it

"Carbon black pipe" absolutely do not come in

Only adding UVA: the surface layer will still be damaged, and the surface will first start to powder.

Only add HALS: The substrate protection is good, but light-colored parts will still yellow.

The combination of the two is what constitutes a complete weather-resistant system. This is also the biggest difference between "cheap weather-resistant materials" and "qualified weather-resistant materials."

3. Dark colors and light colors have a huge difference

Carbon black is known as one of the most effective ultraviolet shields, and it is inexpensive.

This brings a very realistic conclusion:

Black outdoor parts, the lowest difficulty in weather resistance.

Light-colored (white, gray, beige) outdoor pieces are the most difficult to weatherproof.

ColorWeather resistance difficultyExplanation
Black (containing a sufficient amount of carbon black)LowCarbon black has good shielding effect
Dark colors (dark gray, dark blue)Medium-lowThe pigment itself has a certain shielding effect
Light colors (white, light gray)TallNeeds support from UVA HALS, and yellowing is highly visible
Natural / TransparentThe bestNo shielding, yellowing is extremely obvious

So when encountering light-colored outdoor parts, you need to clarify your expectations in advance:

A stabilizer system requiring a higher dosage

Higher cost

Long-term slight color changes are often difficult to completely avoid — it is necessary to agree on an acceptable color difference range (ΔE)

The requirement that 'white parts should not yellow outdoors for five years' needs to be seriously discussed at the early stage of the project.

4. How to evaluate weather resistance

Three main methods:

① Artificial accelerated aging (Xenon lamp / QUV).

Simulate light, temperature, and humidity cycles for hundreds to thousands of hours, measuring color difference and performance retention rate. It is fast, but the correlation with real exposure needs to be calibrated.

② Exposure to outdoor sunlight.

Exposure in real environments is usually measured on an annual basis. It is the most realistic, but the cycle is long, and the radiation levels vary greatly in different regions (completely different between the south and the northwest).

③ Combination method (recommended).

First perform accelerated aging screening, then calibrate with outdoor data. This approach balances speed and reliability.

Evaluation metrics should consider two types at the same time:

Appearance: Color difference ΔE, gloss loss rate, chalking grade

Performance: tensile strength retention rate, impact strength retention rate

Special attention: The decline in impact performance usually occurs earlier and is more pronounced than tensile strength. Only looking at tensile retention can easily lead to the misleading conclusion of 'still healthy'.

5. Key Points for Selection

① First, clarify the usage environment.

Outdoors or indoors? Is there direct sunlight? What is the regional irradiation level? Items indoors near windows will also age, which is often overlooked.

② Clarify the lifespan requirements.

"Outdoor use" and "outdoor five years" are two separate requirements. Lifespan is the direct basis for selecting material strength.

③ Specify the color and color difference tolerance.

The ΔE range for light-colored items should be agreed upon in advance.

④ Request aging data, not the word 'weather-resistant'.

We need to have the supplier provide specific testing conditions and retention rate data.

⑤ Consider the superimposition of other factors.

Outdoor components often face: UV, heat, rainwater, media, and loads at the same time. When multiple factors act together, aging is significantly accelerated.

6. Processing and Storage

① The dispersal of additives should be uniform. If weather-resistant additives are not well dispersed, local premature aging may occur. This is a common reason why some items in the same batch turn yellow while others do not.

② The processing temperature must not be too high. Some additives may decompose or volatilize at high temperatures, and if the processing temperature exceeds the additive's tolerance limit, it is equivalent to adding it for nothing.

③ Avoid excessive shearing. High shear can accelerate the degradation of additives.

④ Storage should avoid light. Unused raw materials and parts that have been formed but not yet installed should be stored away from light.

⑤ Post-processing and coating need to be considered. If painting or printing will be done later, the type of additives may conflict with the coating system, and this should be confirmed in advance.

Seven, Five Common Pitfalls

Pitfall 1: Thinking that 'weather resistance' just means adding a kind of additive.

The complete system is a combination of UVA and HALS (pigments). Missing one type will definitely result in poor long-term performance.

Pitfall 2: Directly converting accelerated aging data to years outdoors.

The correspondence between the two needs to be calibrated; simple linear conversion often overestimates or underestimates.

Pitfall 3: Only looking at the retention rate of tensile strength.

The degradation of impact performance often appears earlier, and the part may 'still have enough strength but shatter upon a touch'.

Pitfall 4: Underestimating the difficulty of light-colored parts.

Long-term color change control for light / white colors is costly, so expectations should be discussed in advance.

Pitfall 5: Ignoring the effect of processing temperature on additives.

If the additives decompose, no matter how good the formula is, it’s useless.

8. Boundary Statement

Operating conditionSuggestion
Black outdoor partsLowest weathering difficulty, mainly carbon black
Light-colored / White Outdoor PartsA complete system is required, with an agreed ΔE range, which increases costs
Long-term outdoor (over 5 years)Complete weather-resistant system Supported by actual exposure data
Indoor but near the windowUV protection also needs to be considered
Outdoor Flame RetardantTwo types of additives may interact with each other and require a special formulation
Outdoor High LoadAging will amplify creep, so it should be evaluated simultaneously
Short-term outdoor (1-2 years)It can be moderately simplified, but a complete system is still recommended.

A practical insight from the industry: In weathering projects, one thing we most frequently remind clients is that accelerated aging is not the same as outdoor exposure, and the two need to be calibrated against each other. In one outdoor installation project, the materials passed a 1000-hour xenon lamp test, with acceptable color difference and strength retention. However, after more than two years of actual installation, the surface showed significant chalking. Upon investigation, it was found that the irradiation intensity and spraying cycles in the test conditions differed greatly from the real environment, which led to an overestimation of the acceleration factor. Later, the test plan was adjusted, and materials were selected again based on exposure data from the same latitude, which finalized the solution. The most dangerous mindset in weathering is to feel assured just because it passed laboratory tests. If possible, it’s better to place a batch of samples in the target area first, as this is more reliable than any report.

A four-year account of a batch of lawn mower housings

The starting point was a lawn mower project, with the casing made of natural weather-resistant PA6, and the market feedback in the first year was very good.

With an incubation period of two years, the batches exported to Southern Europe gradually showed fading. The machines themselves weren’t broken, it was just that the color aged quickly, causing the second-hand residual value to drop directly.

The outbreak occurred in the fourth year when distributors listed the faded items as deductions, with the amounts increasing year by year.

Settlement Plan: For dark-colored parts, change to a carbon black plus hindered amine formula; for light-colored parts, switch to a high-content titanium dioxide system. At the same time, include 3,000 hours of xenon lamp aging in the acceptance criteria. Calculated over four years, the increase in material costs is less than the deductions by a small amount.

We often use this case to illustrate one thing: the cost of weather resistance should be calculated together with the depreciation account; the cost of the material is the smaller part.

When questioning the choice of weather-resistant materials, three points are the most important.

Follow-up Question 1: What are orientation and region? Facing south versus facing north differs by a factor of two, and the plateau versus the coast differs even more. Determine the location first before discussing the formula.

Follow-up Question 2: Who decides the color? The weathering routes for light and dark colors are completely different. The color must be decided before selecting the material; if the order is reversed, rework is required.

Follow-up Question 3: Should we use a xenon lamp or an ultraviolet lamp for acceptance? The correspondence between the two types of lamps must be agreed upon first, otherwise the report will not match the terminal requirements.

Extended Judgment (Domain-General)

These four points are not only applicable to PA66 / PA6 weather-resistant modified materials, but are common extended criteria for all outdoor weather-resistant plastics.

Judgment 1: Weather resistance is not just about UV resistance. UV is only one factor in outdoor aging; heat cycling, humidity, and chemical atmospheres (salt spray by the sea, northern dust, industrial air) are also factors. UV transmittance does not represent overall weather resistance. Many projects think that 'adding UV stabilizers is enough,' but problems arise in the first year.

Judgment Two: Color and weather resistance are linked. Black naturally provides strong UV protection, so black nylon often performs better outdoors than natural or light colors. Formulating light-colored weather-resistant nylon is much more difficult than black—this difficulty is reflected in the price and the number of suppliers. When choosing light-colored weather-resistant nylon, do not estimate the price based on black.

Judgment Three: Weather resistance cannot be judged by the 'formulation' alone; processing must also be considered. The stability of weather-resistant additives at high temperatures is limited. If the processing temperature is too high or the material stays too long at high temperatures, the weather resistance will be consumed prematurely. This is especially important to be cautious of when processing nylon at high temperatures. Mold and equipment temperatures must be strictly controlled, and high-temperature weather-resistant materials cannot be processed under standard PA6/PA66 conditions.

Judgment Four: Not yellowing for 5 years is a 'visual' indicator, not a 'mechanical performance' indicator. Remaining yellow visually does not mean that the mechanical performance has significantly deteriorated—these two need to go through two separate testing paths. For projects that make an 'outdoor 5-year' commitment, conduct two sets of tests: (1) color change ΔE test; (2) tensile/impact/creep mechanical performance retention test.

These four are useful because 'weather resistance' is like a technical term that all projects discuss, but the specific indicators are often vague. Turning the vague into measurable indicators is one of the main tasks of process engineers.

Finish off by adding one more 'Three Questions and Three Answers'.

Frequently Asked QuestionsAnswer in one sentence
Do you still need a stabilizer after adding carbon black?Necessary, carbon black blocks light but not oxygen, the two lines of defense complement each other
How to verify five years outdoors?Xenon lamps start at three thousand hours, Southern projects double
Can light-colored parts use a carbon black system?No, going the titanium oxide route, the cost needs to be reserved.
Can items that have yellowed be restored?No, you can only replace the part; prevention is the only solution.

Add another reverse case.

A client used indoor-grade material directly on the outdoor access control casing, reasoning that it was 'just a temporary fix.' As a result, the surface chalked after fourteen months, and the property management filed a batch complaint. The difference between indoor and outdoor is just one character, but the formulation differs across the entire stability system—there's no temporary solution for weather resistance, the sun shows no mercy, and the bill will eventually arrive.

The Origin of Numbers: Why Two and Three

Why can't light-colored parts use a carbon black system? Let's start with the mechanism of photo-oxidation. Ultraviolet light breaks polymer chains to produce free radicals, which combine with oxygen to form a chain reaction. Yellowing and chalking are both products of this chain. Carbon black acts like an umbrella, blocking most of the light, so dark-colored parts are naturally weather-resistant;

Light-colored pieces cannot block light; they can only rely on hindered amines to capture free radicals and intervene in the intermediate stages of the chain reaction. The two lines of defense are located differently and cannot replace each other.

How did xenon lamps get 3,000 hours? Based on East China outdoor UV intensity, artificial light sources have an acceleration rate of about ten times, so 3,000 hours corresponds to about five years outdoors. This is the industry's standard conversion starting point: in southern high-irradiance areas, the discount is fifteen times, and plateaus are even more ruthless.

Behind the numbers is the magnification table, and behind the magnification is the region. The acceptance clause only states the number of hours and not the region, which is basically not specified.

Practical Checklist: Six steps for weather-resistant parts project initiation

Project form plus two columns: installation area, orientation, then discuss formula after filling out

Color and formula route binding review, color change must be changed formula evaluation

Xenon lamp hours converted by region and written into acceptance documents

First-year on-site follow-up photos and archives, compare with prototype parts

Raw materials and products stored away from light, warehouse curtains more important than expected

Spare parts lifespan labeling matches the whole machine, don't let spare parts wear out first

None of these six require a lot of money, but each one is working for the reputation five years from now. Weathering is a slow variable, and managing it is to write actions into the process.

Finally, let me share an old rule in the weathering industry: sample panel hanging. Some clients hang a set of sample boards on the workshop roof—formulas, competitors, and previous generation in a row, and take photos quarterly. After three years, which formula has been tested is clearly visible on the wall, more convincing than any acceleration report.

Accelerated aging is responsible for filtering out the poor, hanging panels for verification, and only after completing both processes do they dare to make a five-year commitment. For projects with the means, we always advise: the row of hooks on the roof is the most profitable fixed asset in weathering R&D.

Besides hanging panels, there's another point worth elaborating: the color stability of weather-resistant materials is not synchronized with mechanical stability. Some formulas hold color but mechanics fade first; plastic casings don't change color but crack when broken; Conversely, some materials remain sturdy but the color looks as old as if they've been used for ten years.

Acceptance documents should be written in two separate columns: color difference and mechanical retention rate. Only after passing both columns is it considered five years. We've seen projects where only color difference tests the shell chalky and breaks in the fourth year, with compensation an order of magnitude higher than the material price. Weather resistance is half about the formula, half about detailing the acceptance terms.

Conclusion

Weather-resistant nylon selection, four sentences:

The system must be complete—UVA HALS pigments, three categories combined.

Color determines difficulty—dark colors are easier to make; light colors need to be discussed in advance about expectations and color differences.

Data must be conditional—specific testing conditions and retention rates should be specified, not just 'weather endurance. '

Acceleration must be calibrated—lab and outdoor should verify each other.

The outcome of outdoor pieces isn't about 'factory performance,' but 'how it looks five years later.'

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