TPE怎么选?先硬度后温度,再谈介质和成本

塑料知识科普 发布时间: 2026-09-12 4117 阅读

The selection table took five pages to fill out, yet mass production still sticks to mold every day. How to choose TPE? If one working condition is missed, the entire batch has to be reworked.

How to choose TPE? Five-step method summarized in one sentence

TPE selection, it's complicated when you look at it closely, but it can be simplified into five steps: hardness → coating → temperature resistance → medium → cost.

The order cannot be confused. The first two steps determine the direction, the next two steps determine life or death, and the final step determines whether to stay or leave:

StepWhy askWhat have you decided?
Step One HardnessHow soft and bouncy should this piece be?Hardness range, system family
Step 2: EncapsulationDo you want to wrap it in other materials?System (SEBS/TPU/Grafted TPE)
Step 3 Temperature ResistanceWhat is the highest/lowest temperature?Temperature resistance grade, system upper limit
Step 4 MediumDoes it come into contact with oil/water/chemicals/food?Formulation direction, dedicated grade
Step Five: CostWhat is the unit cost after yield?Cost-performance trade-off

Technical Golden Saying: Hardness determines the direction, rubber coating determines the system, temperature determines the grade, medium determines the formulation, and cost determines life or death — five steps, not a single one can be skipped.

Why can't the order be messed up? Because the result of the previous step is the input for the next step.

Set the hardness first before sieve the system; Once the system is set, you can talk about temperature resistance and medium resistance; Once temperature resistance and medium are set, cost becomes meaningful—reverse (ask about price first),

It is the most common pitfall in purchasing inquiries: buying cheap materials, and then having to redo all the first four steps.

Step one: first determine the hardness? The feel is benchmarked against a physical reference point.

Hardness is the fundamental language of TPE. Shore A is the main scale, ranging from 0 to 100, with a tactile feel for every 10-degree increment:

Shore APhysical anchorCommon parts
0-10Jelly, gummy candyGel pad, bionic skin
20-30Rubber bands, mouse padToys, watch strap lining
40-50Phone case, tire treadSheath, handle
60-70Toothbrush handle, shoe soleTool handle, seals
70-80Tires, wiper bladesSoles, Casters
80-95Solid tires, rolling pinCasters, wear parts

The same Shore A 70: SEBS is soft and sticky, TPU is elastic and tough, TPV is nearly rubber-like—the hardness dial is just the starting point; the system's characteristics are the essence of the feel. Setting hardness is not about setting a number, it's about deciding 'what kind of feel you want.'

Shore 00 This durometer must also be recognized separately: it measures super soft materials. Gel pads, bionic skin, and shock-absorbing liners are between 00-30A. The Shore 00 scale is finer than the A scale, and the 00 range from 0-100 feels like anything from 'tofu' to 'rubber'.

For a 'jelly feel,' look at Shore 00; for a 'gummy feel,' Shore 00 mid-to-high range or single-digit A.

There is a practical technique for determining hardness: compare with a real sample.

Bring a sample with a satisfying feel (even if it’s not TPE), so the supplier can directly understand the hardness, the system, and the formula — this is more intuitive than looking at ten numbers.

With a press of the hardness tester, half of the truth is revealed; with a squeeze of the sample, the whole feel is understood.

How can hardness be measured accurately?

Three details: Temperature — TPE hardness varies significantly with temperature; it can differ by 5-10 degrees between 25°C and 40°C, so testing should be done at the standard temperature; Thickness — if the sample is too thin, the reading will be harder; the standard requires a certain thickness.

Instrument — Hardness readings from different manufacturers' testers may differ by 5 degrees, so the same device should be used for comparisons within the same system.

**Press the hardness tester, and the truth is half revealed; if the temperature is wrong, the reading deceives.

The choice of durometer also has its nuances: Shore A is used for regular soft materials, Shore 00 for ultra-soft materials, and Shore D for high hardness—using the wrong scale renders the readings meaningless.

When reading, you should also pay attention to the reading time: the standard is 1 second for type A or 15 seconds for type D. If you press too long, the reading will drift. Measure at three points and take the average, record the temperature, and this will give a set of usable hardness data.

The five-step method ends here: hardness determines the feel, rubber coating determines the system, temperature-resistant medium determines life and death, cost determines whether to keep or discard, and validation determines success or failure.

Every step has data to rely on, and every stage has samples to check — this is the significance of turning selection from experience into process.

Step two is to decide on the encapsulation? The substrate determines the system.

To coat with rubber, first ask about the substrate:

SubstrateRecommendation systemReason
PPSEBS based (Wang)Good compatibility, strong adhesion
ABS/PCTPU, modified SEBSPolarity matching
PA/MetalGrafted TPE, TPVChemical bond grafting
PEDifficult to contain, requires special handlingLow surface energy

The biggest concern for coated parts is delamination. If the coating delaminates, first check the substrate cleanliness, then check the temperature compatibility—if the material is chosen correctly but the process can't handle it, it's all in vain.

The four key points of coating technology, explained in one go:

4. Verification method: The peel test is a standard procedure—the publicly known cases in the industry, such as the coating on electric tool handles, are considered passing only if the peel strength reaches above 35 N/cm and there is no delamination during thermal cycling from -40°C to 80°C.

Choosing the wrong encapsulation system inevitably leads to delamination and rework—grafted TPE encapsulating PA is bonded at the 'chemical bond' level, while ordinary SEBS encapsulating PA is just 'surface coating' and comes off easily when pulled.

Three steps for encapsulation verification: initial adhesion test (manually peel after demolding) → peel strength test (pull standard specimen) → thermal cycling (-40℃~80℃, check for delamination after cycling). Only if all three steps pass is the encapsulation considered stable.

Industry Public Case: For electric tool handle overmolding, achieving a peel strength of over 35N/cm and no delamination under hot and cold cycles was verified by following these three steps.

Step three: temperature resistance, step four: medium: veto items

Temperature resistance and medium compatibility are 'veto items'; don't expect adjustments to fix them.

Operating conditionMinimum requirementsRemarks
room temperatureSEBS base is fine≤120°C
High temperature for a long time 120℃TPV/TPEECheck the seals CS
150℃ long-termTPEE/TPSIVEngineering grade
Oil-resistantTPU/TPVFirst determine the oil resistance grade
Hydrolysis-resistantTPEE Use with Caution / Special UseLong-term water immersion needs to be measured in practice
Food contactFood-grade SEBSWith GB/FDA certification
Flame retardantUL94 V0 / Halogen-freeExports must be inspected

If the temperature is one level higher, the lifespan is shortened; if the medium is not correct, it becomes useless after three days—there is no 'close enough' for these two items, only 'pass' or 'fail'.

How should temperature resistance be measured to be valid? Both heat aging tests (such as 1000h/70℃) and low-temperature tests (such as -40℃ bending) need to be conducted; don't just look at instantaneous temperature resistance. Not melting at 150℃ instantaneously and not losing performance at 150℃ for 1000 hours are two different concepts.

Common industry practice: TPE material suppliers generally provide aging curves and compression set data (typical value at 70°C × 22h). What you need when purchasing is this data, not a verbal promise.

How to measure the medium? Tell the supplier the actual medium in contact, temperature, and duration, so the formula can match.

Oil includes mineral oil, hydraulic oil, engine oil, all of which are different; water includes ionized water, hot water, disinfectant. The two words 'oil-resistant' are not enough—you need to specify which oil, at what temperature, and for how long; all three parameters are essential.

The medium test checklist can be made into a table: medium name, concentration, temperature, soaking duration, allowable changes (volume/hardness/weight).

After sampling and testing, the data speaks for itself—oral claims of 'oil resistance' don't count, only test reports matter. For the dielectric data of TPE materials, reputable suppliers provide reports from third-party or in-house laboratories.

Step Five Cost: Only by Calculating the Total Account Does It Count

The cost is not the unit price, but the cost per piece after yield rate:

Unit cost = (Material price + Processing fee + Scrap allocation) ÷ Number of good products

Cheap materials are costly because of rework: saving three cents per unit but dropping the yield by ten percentage points results in a net loss. Conversely, a more expensive system that increases yield from 90% to 98% actually saves money overall.

Calculate a real account (example data):

PlanMaterial Price (CNY/kg)YieldNumber of scrap per ten thousand unitsUnit Total Cost
A cheap materialEighteen88%One Thousand Two HundredTall
B slightly higher tierTwenty Two97%Three HundredRather low

The material price differs by four yuan, the yield rate differs by nine points, and the overall cost differs by thirty percent — this is why experienced buyers calculate unit cost per piece, not unit price.

The processing window is also a hidden cost factor: one requires processing at 200°C, while another can be molded at 170°C, leading to a significant difference in energy consumption; one material tends to stick to the mold, while another releases smoothly, resulting in a difference of several seconds in cycle time.

When selecting the model, make sure to include the injection molding parameter window; only then is the cost account considered complete.

Go through the selection of three real items, and the five-step method comes alive:

Tool handle: Need to cover PP substrate, sweat and oil resistant, not crack at -20°C — Step 1: Hardness selected 60A, Step 2: Coating selected SEBS base (polar compatible), Step 3: Temperature resistance -20°C~60°C passed, Step 4: Medium is sweat and light oil,

Step five calculate the general ledger based on yield.

Industrial Seals: Must resist hydraulic oil and long-term pressure—Step 1: hardness 70A, Step 2: no overmolding, Step 3: long-term temperature resistance 100°C, Step 4: mineral oil resistance, system directly locks in TPV.

SEBS was rejected on both oil resistance and permanent compression deformation.

Charging pile cable sheath: must be bend-resistant, flame-retardant, and weather-resistant—Step one hardness around 85A, step two no rubber coating, step three temperature resistant -40℃~70℃, step four outdoor weather resistance plus flame retardancy, locking dedicated SEBS base grade,

Ordinary SEBS cannot pass the bending fatigue life test.

Three pieces move through, the same five-step method, three completely different paths.

The process of small batch verification, the final step beyond the five-step method:

Step One Sample Request: Ask the supplier to recommend 1-2 grades according to the five-step table, and also provide the physical property sheet and injection molding parameter suggestions.

Step One Sample Request: Ask the supplier to recommend 1-2 grades according to the five-step table, and also provide the physical property table and injection molding parameter recommendations.

Step 2 Mold Trial: Use the production mold to produce a small batch, recording the actual values of melt temperature, mold temperature, molding cycle, and shrinkage rate.

Step 3: Test performance: hardness, tensile, tear, compression set, temperature resistance, medium resistance, check each item according to the working condition list.

Step 4 Aging Verification: Thermal aging for 1000 hours, low-temperature shock, UV aging, answer the question of 'whether it will still be okay after a year' in advance.

Step 5: Three consecutive approvals: Only after three consecutive batches are consistent is bulk supply allowed.

These five steps may seem complicated, but each step actually has ready-made methods and standards—the real difficulty is sticking with them until the end. Skip a step, and there's an increased risk of rework in mass production; if you go through the entire process, things generally go smoothly afterward.

How to compare quotes from five companies? First, narrow down to three companies with the correct material direction, then compare the unit cost after yield, and finally use samples from the same batch to compare data.

Cologne Customer Case: Wear Resistance Fails, Custom Grades Provide a Fundamental Solution

A Wuhan factory applying modified materials to make wear-resistant parts experienced fast surface wear, leading to continuous customer complaints. After an investigation by Kolon, it was found that the wear resistance index of the general-grade material only reached the borderline value, and the sand particle environment in the working conditions was much harsher than the standard test.

Cologne collaborated to customize special grades resistant to oil and temperature, elevating the wear resistance level to the actual requirements of the working conditions. After small-batch validation, the rework rate was reduced by half. Selection is not about choosing what is 'enough,' but selecting what 'matches the working conditions' — general grades can't solve it, only special grades are the answer.

Common pitfalls: missing items in model selection, finding supplements during mass production

pitConsequenceSolution
Place the order by only reporting the hardnessThe feel in hand is not rightFill in the Five-Step Form first
Omitted mediumOil bubble crackingMedia field is required
Do not view the processing windowSticking to the mold / ShrinkageNeed injection molding parameters
Mixing samples and batchesBatch DriftThree batches of retained samples
Only look at the unit priceYield slaps in the faceCalculate unit cost

The final form of the five-step selection table is a purchase order: hardness grade, base material, temperature range, list of media, target yield, maximum unit cost — **all six columns filled out.

No matter who you send the quote to, it won't go off track.

This is also why we recommend that every purchaser keep a 'Five-Step Selection Decision Card': it's not about memorizing the process, but about keeping the power of judgment in your own hands.

Three more detailed pitfalls: Pigment system — TPE coloring requires special masterbatch, ordinary pigments tend to precipitate; Drying — some grades will have silver streaks if not dried; Storage — after opening, moisture absorption can cause performance drift.

The pit is not in the depth, but in the details.

Three frequently asked questions answered together:

Question: For the same grade, if two suppliers' quotes differ by 20%, how should you choose?

Answer: First, check the physical property data (comparability only exists if the test conditions are consistent), then review the batch stability records, and finally carry out small batch trial molding. If the price difference comes from downgrading the formula, it usually becomes apparent during trial molding.

Question: The sample performs very well, but it drifts during mass production. Why?

Answer: Eighty percent of the time it is a batch control issue. Require the supplier to provide sample data from three batches, match the sample batches with the delivery batches, and the drift can be caught.

Q: The selection form has been filled out, but the supplier says this working condition doesn't need to be so strict. Whose advice should I follow?

Answer: Listen to the data. Ask the supplier to provide the basis for their recommendations (test data, cases). If they can't provide it, follow the conservative plan.

When it comes to selecting models, it's better to be strict than lenient—being strict might just cost a bit more, being lenient leads to rework and accidents.

The final step in the selection process is documentation: organize the five-step table, grade selection, test results, and batch records into one page and put it into the project file.

There are three benefits — replacing personnel is manageable (a new engineer can continue selection according to the files), changing suppliers has a basis (with data in hand, not being led by quotations), and review has a handle (if a problem occurs,

First look at the files, then discuss responsibility.

Many companies' selection knowledge is scattered in individuals' minds. When someone leaves, the experience is lost — documenting the selection process is a way to turn personal experience into company assets, and the cost is just a table.

There is another easily overlooked linkage with hardness: when hardness changes, other physical properties change along with it.

In the same system, as hardness increases, the tensile strength usually rises, the elongation at break decreases, the permanent compression deformation improves, and the feel becomes harder.

So 'setting the hardness first' is not isolated—it also predicts the trend of other properties of this batch of material.

Use the hardness dial for indexing, use the physical properties table for verification, and only when the two lines match can the selection be considered complete.

Summary

Compare the criteria in this article with your TPE; most problems can be screened out on paper first, which is more important than the price list.

Complete in five steps: the system, specifications, process, and cost all fall into place. Leave the rest to verification: small batch test production, three batches retained for samples, and mass release.

Before pouring the material into the machine, what needed to be done was actually already finished.

How much to enhance, whether to add flame retardant, which level of temperature resistance to achieve, whether the size is stable—once these judgments are made, the particles just execute the conclusions.

Ningbo Cologne New Materials Co., Ltd. produces modified thermoplastic elastomers, modified nylons (PA6 / PA66 / PA46 / PA11 / PA12 / PA6T / PA9T and nylon alloys), modified PPO / PPS, as well as stock of nylon resins, secondary materials, and bulk materials from major chemical giants.

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