110 船舶管路用什么改性尼龙
船舶管路的四类工况
船舶管路至少分四类:海水冷却管、淡水管、燃油管、压载水管。
海水管的敌人是氯离子腐蚀和海生物附着;淡水管主要是冻胀和水锤;燃油管要耐烃类溶胀和静电;压载水管要耐海水交替干湿。
这四类工况的料不能混用——这也是船舶管路选料的第一条原则。
现场还原
前年年底,一家航天配套院所的洁净间外,工程师给我们讲了一堂课,课的主题是一颗支架的非功能性失效。支架在地面测试一切正常,装星之后在真空热循环试验里出了问题,支架表面析出物污染了光学组件,整星试验重来。
他说了一句航天人常说的话,地面上的小毛病,天上是灾难。析出物这个东西,在大气环境里会被氧化稀释,在真空里直接迁移到最不该去的地方。航天选料的第一课不是力学,是洁净,这个顺序打破了很多从地面行业过来的材料人的直觉。
长碳链尼龙是主力
船舶管路主流走 PA12 和 PA11 这类长碳链尼龙,而不是 PA66。
原因是吸水率——PA66 饱和吸水率 8.5%,PA12 只有 1.5%。
吸水直接导致尺寸膨胀和强度下降,在管路系统里表现为接头松动和爆破压力下降。
PA12 的吸水率低,尺寸稳定性好,这是它占据船舶管路的根本原因。
耐水解和耐氯离子
海水环境对 PA 是双重攻击:水分子引起酰胺键水解,氯离子加速老化。普通 PA66 在 60℃ 海水中 2000 小时后拉伸强度下降 45%。
必须走耐水解体系——加碳二亚胺类抗水解剂 + 铜盐热稳定剂,能把衰减控制在 20% 以内。这一项助剂成本增加约 10%,但寿命能翻倍。
抗冻胀和抗水锤
北方航区的管路会结冰,水结冰体积膨胀 9%,普通硬质管路直接冻裂。改性尼龙的韧性在这里是优势——PA12 在 -40℃ 仍有延展性,能吸收部分膨胀。
但设计上还是要留余量:一是管路走柔性走向(做 U 形弯),二是加保温层,三是停用期放空。水锤的应对是加缓冲罐,不是换料。
燃油管要过静电和渗透两关
燃油管有两个特殊要求。一是静电——燃油流动产生静电,管路体积电阻要低于 10⁹ Ω·cm,走导电 PA12 或加抗静电剂。
二是渗透——燃油分子会透过管壁,渗透率要满足排放法规。PA12 的燃油渗透率远低于 PA6,这是它成为燃油管主材的另一个原因。
多层复合管(PA12/EVOH/PA12)能进一步把渗透率压到单层管的 1/20。
延伸判断:船舶管路的隐性变量
有三件最容易漏掉的隐性变量。一是海生物附着——管内海生物附着会缩小通径,改性尼龙表面能做防污涂层,但寿命有限,要定期清理。
二是接头比管材更容易失效——80% 的泄漏出在接头而非管身,卡套式接头的材质要和管材匹配。
三是干湿交替——压载舱的管路长期干湿交替,比持续浸泡更伤材料,验证时不能只做浸泡测试。
深一层:几个数字的来历
空间环境和地面的根本差异是真空加辐照加极端温度循环,地面工况表在这三个维度上全部要重写。
真空让挥发物自由迁移,辐照打断分子链,冷热循环的幅度从零下一百多到一百多度,材料在这个谱系里的每一步行为都要重新验证,地面数据的参考价值有限,航天数据的体系是独立建的。
出气是第一道筛子,材料的总质量损失和可凝挥发物的限值有明确的门槛,过不了出气关的材料在航天门口就出局。
出气的来源是低分子量组分,残留单体、增塑剂、低聚物,低出气的牌号从原料端就控制这些组分,价格高一截,但这一截是入场的门票,没有砍价的空间。
辐照会打断分子链,性能的衰减按累计剂量算,轨道不同剂量不同,低轨一年的剂量和深空差几个量级。
材料的耐辐照验证按轨道的剂量谱做,聚合物在辐照下的交联和降解是一对方向相反的反应,配方里抗辐照稳定体系的必要性就在这里,没有稳定体系的料,辐照后的性能曲线是陡坡。
冷热交变考验尺寸稳定,支架的精度位在交变后漂移,光学的指向误差就是这么来的。
低热膨胀的体系加结构的对称设计,双管齐下,尺寸稳定的验证在高低温循环后的复测,复测的偏差按光学件的要求严苛得多,航天件的公差比地面行业窄一个量级,注塑的工艺窗口要为公差让路。
电池支架的具体要求是绝缘加导热加结构三合一,电池组的工作热要导出去,支架同时要守住绝缘,导热绝缘的塑料件是这个位置的答案。
支架还要承受发射段的振动,力学谱按发射工况走,几个指标里最容易被低估的是发射段的力学,火箭的振动谱比任何地面运输都猛。
洁净装配的要求延伸到材料的选择,装配环境里不允许材料掉屑,塑料件的边缘处理和毛刺控制是工艺课。毛刺在真空里脱落成游离颗粒,颗粒撞上光学面就是污染事件,件边和孔口的处理标准要写进工艺文件,洁净是这个行业对细节的信仰。
工程实测:4 条强制测试
测试1:海水浸泡 2000 h / 60℃。耐水解 PA12 拉伸保持 82%,普通 PA66 降至 55%——必须耐水解体系。
测试2:吸水率。PA66 饱和吸水 8.5%,PA12 仅 1.5%——尺寸稳定性差 5 倍以上。
测试3:燃油渗透。PA12 单层管渗透率 8 g/m²/day,PA12/EVOH 多层管 0.4 g/m²/day——差 20 倍。
测试4:低温 -40℃ 延展。PA12 在 -40℃ 断裂伸长率 120%,PA66 仅 15%——北方航区必须 PA12。
边界声明
| 工况 | 推荐材料 |
|---|
| 海水冷却管 | 耐水解 PA12 |
| 淡水管 | PA12 或 PA11 |
| 燃油管 | 导电 PA12 或多层复合管 |
| 压载水管 | 耐水解 PA12 + 防污涂层 |
| 北方航区 | PA12(-40℃ 仍有延展) |
工程备忘
船舶管路四类工况不能混用料,主力是 PA12/PA11 长碳链体系——吸水率只有 PA66 的 1/5,尺寸稳定、耐水解、耐燃油渗透。
80% 的泄漏出在接头而非管身,接头材质要单独匹配。
追问三连
问一:改性尼龙在航天上能用在哪?非承力的结构件、绝缘件、电器支架是合理位置,长碳链和低出气体系的尼龙在这些位置有成熟应用。承力主结构和光学件的位置不是塑料的主场,认清边界比突破幻想务实。
问二:地面验证和空间验证怎么衔接?地面按等效谱做加速,空间的真实数据靠搭载试验慢慢积累,两套数据互相校准。新材料的上星路径是从搭载件开始,一步一步来,想一步到位上主结构的,基本都摔在验证的路上。
问三:单件小批的成本怎么控?航天件的批量小,模具摊销是成本大头,通用化设计和柔性制造是解法。把通用件的比例做大,专用件做少,批量的经济性藏在设计里,成本控制的第一战场在设计端,不在生产端。
反向案例与收尾判断
某配套单位为了赶进度,把一个支架件的材料从认证过的低出气牌号换成性能相当但没做出气数据的牌号,打算后补数据。热真空试验的污染把两个光学镜面打了回炉,损失是材料差价的几百倍,进度反而倒退三个月。
航天行业的规矩是数据先行,没有数据的牌号等于不存在,任何进度压力都不能替代验证的完整性,这条铁律的价值用一次事故就能讲清楚,只是没人希望用这种学费去学。
实战案例:常见踩坑与正解
踩坑一:按普通工业件的物性表直接套到航空特种场景,结果装车半年就出现烟毒超标 / 低温脆裂 / 阻燃复检不过。
正解:这类场景是标准先行——适航或轨交的阻燃烟毒标准、低温冲击标准全部要重新核对,普通改性尼龙物性表只覆盖常温力学性能,完全不适用——这是 80% 首批送样失败的根因。
踩坑二:为了减重把玻纤含量一路加上去,结果薄壁处玻纤外露、表面浮纤、尺寸飘。正解:减重靠结构而不是单纯加纤,薄壁件走 GF30 上限,超过就要换高流动牌号或加矿物填充。
踩坑三:只验证常温性能,忽略了高低温交变和盐雾。正解:服役环境验证要按整机寿命做,高低温循环 + 盐雾 + 湿热老化三项一起做,少一项就是批量隐患。
这三个坑都是量产前必须自查的清单。
补记:四条来自航天配套的延伸判断
航天配套的供应商准入靠口碑和案例滚动,一个型号上的成功应用是最好的资质,案例的积累从搭载和实验件起步。建议材料厂主动对接院所的搭载机会,搭载体量小但背书价值大,一颗星上的成功案例能带来后续多个型号的询价,航天市场的营销是案例营销。
商业航天在改写这个行业的节奏,星座的批量化生产把塑料件的量从单件拉到千件级,批产的工艺要求进来。
商业航天件的验证有简化通道,节奏快了两个量级,材料商的商业航天线要单独建,按批产的逻辑配产能和文件,传统的院所线按单件的逻辑走,两条线两套打法。
空间在轨制造是前瞻方向,太空中打印结构件的试验在推进,材料的太空适配性是全新的课题。这个方向离商业化还远,但专利和数据的布局窗口就在当下,前瞻的投入量不大,卡位的价值在五年后兑现,有研发冗余的材料厂值得放一个哨位在这里。
航天材料的降本压力在传导,星座时代的成本敏感度比国家队项目高,降本的空间在工艺和设计,材料等级的红线不动。
低出气、耐辐照这些安全红线是不能碰的,红线内的工艺优化和规模化是降本的合法通道,向客户讲清楚红线和空间的边界,比单纯报低价更能赢得尊重。
增补:另四条来自洁净间的观察
观察之一,航天件的包装和转运是污染控制的延续,件从洁净间到总装厂房的途中,包装的洁净等级要匹配。
包装材料本身也要过出气关,普通塑料膜的挥发物在转运中附着在件上,专用的包装材料是洁净链的一环,包装的洁净投入在航天件上不能省,一环掉链子全链白做。
观察之二,航天件的验收测试有一套自己的语言,客户的验收大纲提前拿到,按大纲准备自检数据,验收的轮次能减一轮。验收大纲里的测试项和材料的常规测试重叠度高,重叠项一次测完两用,自检报告的格式按大纲排,客户的验收效率就是供应商的口碑。
观察之三,商业航天对塑料件的需求在快速放量,批产化的验证和单件验证的方法论不同,抽检加过程控制替代全检。
过程能力的建设是批产线的核心,注塑的参数闭环和模具的状态监控,把过程数据变成质量证据,商业航天的客户看重过程证据不亚于最终测试。
观察之四,航天材料的备件体系按型号管理,型号批产后的备件需求持续多年,备件的生产要复现当年的工艺和批次。工艺的存档和模具的保存年限要按型号寿命走,这是航天供应商的长期责任,也是长期收入的来源,备件的复现能力是老供应商的护城河。
结语
这句话我们每周都听到——选料这件事,越早问越省事。
这类件的选料与试模,可以一起聊。
What type of modified nylon is used for 110 ship pipelines?
Four Types of Operating Conditions of Ship Piping
Ship pipelines are divided into at least four categories: seawater cooling pipes, fresh water pipes, fuel oil pipes, and ballast water pipes.
The enemies of seawater pipes are chloride ion corrosion and marine organism attachment; freshwater pipes mainly face frost heave and water hammer; fuel oil pipes need to resist hydrocarbon swelling and static electricity; ballast water pipes must withstand alternating wet and dry conditions in seawater.
The materials for these four types of working conditions cannot be mixed — this is also the first principle of material selection for ship pipelines.
On-site restoration
At the end of the year before last, outside the cleanroom of an aerospace support institute, an engineer gave us a lesson. The topic of the lesson was the non-functional failure of a bracket. The bracket worked fine in ground tests, but after being installed on the satellite, it had problems during the vacuum thermal cycling test. The deposits on the surface of the bracket contaminated the optical components, and the entire satellite test had to be redone.
He said a phrase commonly spoken by astronauts: minor issues on the ground become disasters in space. Deposits like this will be oxidized and diluted in the atmospheric environment, but in a vacuum, they directly migrate to the places they shouldn’t be. The first lesson in aerospace material selection isn’t mechanics, it’s cleanliness; breaking this order has defied the intuition of many materials experts coming from ground-based industries.
Long-chain nylon is the main force
The main pipelines of ships generally use long-chain nylons like PA12 and PA11, rather than PA66.
The reason is water absorption — PA66 has a saturated water absorption rate of 8.5%, while PA12 only has 1.5%.
Water absorption directly leads to dimensional expansion and strength reduction, which in piping systems manifests as loose joints and decreased burst pressure.
PA12 has a low water absorption rate and good dimensional stability, which is the fundamental reason it occupies marine pipelines.
Hydrolysis-resistant and chloride-resistant
The marine environment poses a double threat to PA: water molecules cause hydrolysis of amide bonds, and chloride ions accelerate aging. Ordinary PA66 experiences a 45% decrease in tensile strength after 2000 hours in 60°C seawater.
It is necessary to use a hydrolysis-resistant system—adding carbodiimide-type anti-hydrolysis agents and copper salt heat stabilizers can keep the degradation under 20%. This additive increases costs by about 10%, but the lifespan can be doubled.
Frost heave resistance and water hammer resistance
Pipelines in the northern navigation area can freeze, and water expands by 9% when it freezes, causing ordinary rigid pipelines to crack directly. The toughness of modified nylon is an advantage here—PA12 still has ductility at -40°C and can absorb some of the expansion.
But the design still needs to leave some margin: first, make the pipeline follow a flexible path (forming a U-shaped bend); second, add insulation; third, drain it during the shutdown period. The way to deal with water hammer is to add a buffer tank, not to change the material.
The fuel pipe must pass through both electrostatic and permeability tests
The fuel pipe has two special requirements. First is static electricity—fuel flow generates static electricity, so the volume resistivity of the pipe must be less than 10⁹ Ω·cm, using conductive PA12 or adding antistatic agents.
Second is permeation — fuel molecules can pass through the pipe wall, and the permeability must meet emission regulations. The fuel permeability of PA12 is much lower than that of PA6, which is another reason it becomes the main material for fuel pipes.
Multi-layer composite pipes (PA12/EVOH/PA12) can further reduce the permeability to 1/20 of that of single-layer pipes.
Extended Judgment: Hidden Variables of Ship Pipelines
There are three latent variables that are most easily overlooked. First is marine organism fouling—marine organisms attaching inside the pipes can reduce the flow diameter. Modified nylon surfaces can be coated with anti-fouling layers, but their lifespan is limited and regular cleaning is required.
Secondly, fittings are more prone to failure than pipes—80% of leaks occur at the joints rather than the pipe itself, and the material of clamped fittings must match the pipe material.
Third is the alternation of wet and dry — the pipelines in the ballast tank alternate between wet and dry for a long time, which damages the material more than continuous soaking, so testing cannot be limited to immersion tests.
A deeper look: The origin of a few numbers
The fundamental difference between the space environment and the ground is the combination of vacuum, radiation, and extreme temperature cycles. The ground working condition table needs to be completely rewritten in these three dimensions.
The vacuum allows volatiles to move freely, irradiation breaks molecular chains, and the range of thermal cycling goes from below minus one hundred to above one hundred degrees. Every step of material behavior in this spectrum needs to be re-verified, so the reference value of ground data is limited, and the aerospace data system is independently established.
Degassing is the first screening; there are clear thresholds for the total mass loss of materials and the limits of condensable volatiles. Materials that fail the degassing test are eliminated at the aerospace gate.
The source of outgassing is low molecular weight components, residual monomers, plasticizers, and oligomers. Grades with low outgassing control these components from the raw material stage. They are significantly more expensive, but this extra cost is the entry ticket, leaving no room for bargaining.
Irradiation can break molecular chains, and the performance degradation is calculated according to the cumulative dose. Different orbits have different doses, and the dose in low Earth orbit for one year differs from that in deep space by several orders of magnitude.
The radiation resistance verification of materials is carried out according to the orbital dose spectrum. The crosslinking and degradation of polymers under irradiation are opposite reactions. This is where the necessity of an anti-radiation stabilization system in the formulation comes in. Without a stabilization system, the performance curve of the material after irradiation is steep.
The alternating hot and cold tests the dimensional stability, the accuracy of the bracket drifts after the changes, and this is how the optical pointing error arises.
The system with low thermal expansion combined with a structurally symmetrical design takes a two-pronged approach. The dimensional stability is verified through re-measurement after high and low temperature cycles. The deviation in re-measurement is much stricter according to the requirements of optical components. Aerospace component tolerances are an order of magnitude tighter than those of ground industries, and the injection molding process window must accommodate the tolerances.
The specific requirements for the battery bracket are insulation, heat conduction, and structural integration all in one. The heat generated by the battery pack needs to be conducted away, while the bracket must maintain insulation. Plastic parts that are both thermally conductive and insulated are the solution for this position.
The support also has to withstand the vibrations during the launch phase, with the mechanical spectrum following the launch conditions. Among several indicators, the mechanical aspect during the launch phase is the most easily underestimated. The rocket's vibration spectrum is more intense than any ground transportation.
The requirements for clean assembly extend to the selection of materials. In the assembly environment, material debris is not allowed. The edge treatment and burr control of plastic parts are matters for the process department. Burrs that fall off in a vacuum become free particles, and when particles collide with optical surfaces, it counts as a contamination event. The standards for handling part edges and hole openings must be written into the process documents. Cleanliness is a belief in attention to detail in this industry.
Engineering field measurement: 4 mandatory tests
Test 1: Soaked in seawater for 2000 h / 60°C. Hydrolysis-resistant PA12 retains 82% of its tensile strength, while regular PA66 drops to 55%—a hydrolysis-resistant system is required.
Test 2: Water absorption. PA66 has a saturated water absorption of 8.5%, while PA12 is only 1.5%—more than 5 times worse in dimensional stability.
Test 3: Fuel Permeation. PA12 single-layer tube permeability is 8 g/m²/day, PA12/EVOH multi-layer tube is 0.4 g/m²/day — a difference of 20 times.
Test 4: Low temperature -40℃ elongation. PA12 has a fracture elongation of 120% at -40℃, while PA66 is only 15%——PA12 is required for the northern aviation zone.
Boundary Declaration
| Operating condition | Recommended materials |
|---|
| Seawater cooling pipe | Hydrolysis-resistant PA12 |
| Freshwater pipe | PA12 or PA11 |
| Fuel pipe | Conductive PA12 or multilayer composite pipe |
| ballast water pipe | Hydrolysis-resistant PA12 anti-fouling coating |
| Northern Flight Zone | PA12 (still extends at -40°C) |
Engineering memo
Ship pipelines Materials cannot be mixed under four working conditions; the main component is PA12/PA11 long carbon chain systems—with a water absorption rate only one-fifth that of PA66, stable size, hydrolysis resistance, and fuel penetration resistance.
80% of leakage is at joints rather than pipe bodies; joint materials must be matched individually.
Follow-up Questions Linked
Question 1: Where can modified nylon be used in aerospace? Non-load-bearing structural components, insulating parts, and electrical supports are reasonable positions; nylon with long carbon chains and low-outlet systems has mature applications in these areas. The position of the load-bearing main structure and optical components is not the main domain of plastics; recognizing boundaries is more realistic than breaking through fantasies.
Question 2: How do ground verification and spatial verification connect? Ground uses an equivalent spectrum for acceleration, while real spatial data is slowly accumulated through onboard tests, with two sets of data calibrated against each other. The path to launching new materials to satellite starts with the mounted components, step by step. Those who want to get the main structure in one step mostly fall into the validation process.
Question 3: How to control the cost of small-batch single parts? Aerospace parts have small batch sizes, mold amortization is the main cost, and generalized design and flexible manufacturing are the solutions. Increase the proportion of general-purpose parts and reduce specialized parts; the economic benefits of mass production are hidden in design. The first battlefield for cost control is on the design side, not the production side.
Reverse Case and Final Judgment
A supporting unit changed the material of a support component from a certified low vent grade to one with comparable performance but no gas data, planning to supplement the data later. Contamination from thermal vacuum tests refired two optical mirrors, causing losses hundreds of times the material price difference, while progress was actually rearranged.
The rule in the aerospace industry is data first; grades without data are as good as nonexistent. No progress pressure can replace the completeness of verification. The value of this iron rule can be explained by a single accident, but no one wants to learn it at that cost.
Practical Case: Common pitfalls and correct solutions
Pitfall 1: Applying the physical property tables of ordinary industrial parts directly to special aviation scenarios, but after half a year of installation, they failed the smoke toxicity limit / low-temperature brittle cracking / flame retardancy re-inspection.
Correct answer: This scenario requires standards first—the flame retardant smoke and toxicity standards and low-temperature impact standards for airworthiness or rail transit must all be rechecked. The standard modified nylon physical property table only covers ambient temperature mechanical properties and is completely unsuitable—this is the root cause of 80% of the initial batch of sample submission failures.
Pitfall 2: To reduce weight, glass fiber content was added all the way, resulting in exposed glass fibers at thin walls, floating fibers on the surface, and loose dimensions. Correct answer: Weight reduction depends on structure, not just fibering. For thin-walled parts, follow the GF30 limit; if exceeded, switch to higher flow grades or add mineral filling.
Pitfall 3: Only verify room temperature performance, ignoring alternating high and low temperatures and salt spray. Correct answer: Service environment verification should be done based on the total machine lifespan, including high and low temperature cycling + salt spray + damp heat aging. Missing one means batch production hazards.
These three pitfalls are all checklists that must be checked before mass production.
Supplement: Four extended judgments from aerospace supporting suppliers
Aerospace supply supplier entry depends on reputation and case rolling. Successful application on a model is the best qualification, and case accumulation starts with installation and test parts. It is recommended that material factories proactively connect with institutes for installation opportunities. Although the scale is small, the endorsement value is high. A successful case rated on one star can lead to multiple subsequent model inquiries. Marketing in the aerospace market is case marketing.
Commercial Aerospace is rewriting the pace of this industry. Constellation's mass production has pushed plastic parts from single pieces to thousands of units, and mass production process requirements have been introduced.
Commercial aerospace parts verification has a simplified channel, with a pace two orders of magnitude faster. Material suppliers' commercial aerospace lines must be built separately, with capacity and documentation allocated according to mass production logic. Traditional institute lines follow the logic of single pieces, with two lines and two sets of approaches.
In-orbit manufacturing is a forward-looking direction, and testing of space-printed structural parts is progressing. The adaptability of materials to space is a brand-new challenge. This direction is still far from commercialization, but the window for patent and data layout is right now. The investment in forward-looking is not large, and the value of positioning will be realized in five years. Material factories with R&D redundancy are worth setting up a sentry here.
Cost reduction pressure for aerospace materials is being transmitted. The cost sensitivity of the constellation era is higher than that of national team projects. The space for cost reduction lies in process and design, and the red line of material grade remains unchanged.
Low breathing and radiation resistance—these safety red lines must not be crossed. Process optimization and scaling within these lines are legitimate paths to cost reduction. Clearly explaining the boundaries between red lines and space to customers is more respectful than simply quoting low prices.
Addition: Four other observations from the cleanroom
Observation One: Packaging and transportation of aerospace parts are continuations of pollution control. On the journey from the cleanroom to the final assembly plant, the cleanliness level of the packaging must match.
Packaging materials themselves must also pass the air release barrier. Volatile substances from ordinary plastic film adhere to the parts during transport. Specialized packaging materials are part of the clean chain, and the cleanliness investment in the space parts cannot be saved. If one link fails, the entire chain is wasted.
Observation Two: Aerospace parts acceptance testing has its own language. Customers receive the acceptance outline in advance, and self-inspection data is prepared according to the outline, reducing the number of acceptance rounds. The test items in the acceptance syllabus overlap heavily with conventional material tests, with overlapping items being tested once and used for both purposes. The format of self-inspection reports is arranged according to the outline, and the customer's acceptance efficiency reflects the supplier's reputation.
Observation 3: Commercial aerospace demand for plastic parts is rapidly ramping up. Methodologies for mass production verification and single-piece verification differ; sampling inspection and process control replace full inspection.
Building process capability is the core of batch production lines. Closed-loop injection molding parameters and mold status monitoring turn process data into quality evidence. Commercial aerospace customers value process evidence no less than final testing.
Observation 4: The aerospace materials spare parts system is managed by model. After mass production of models, demand for spare parts continues for many years, and production must replicate the current year's process and batch. Archiving processes and mold preservation should be based on model lifespan. This is the long-term responsibility of aerospace suppliers and a source of long-term income. The reproducibility of spare parts is the moat for established suppliers.
Conclusion
We hear this phrase every week—the earlier you ask about material selection, the easier it is.
For these types of parts, material selection and mold trials can be discussed together