光伏接线盒换料要重验哪几项?灌胶相容性与湿热复验

应用领域 发布时间: 2026-09-14 3288 阅读

When changing materials for a photovoltaic junction box, once the housing is replaced, the potting interface often shows signs first. This article explains how to correctly handle the thermal expansion coefficient of the wires, how to distinguish between interface and substrate cracking, which items in the criteria table must be retested, as well as the processes that need to be adjusted and the scheduling of three rounds of trial molding after the change.

The matter of changing materials for photovoltaic junction boxes revealed its true nature last month at a customer who manufactures the boxes.

They transferred the casing from the original material line to our line, without changing a word of the potting glue, and the process parameters were also copied from the original.

There was no response in the first month. In the second month, the component factory reported back: there is a fine gap at the junction between the glue and the casing.

His exact words at the time were: 'The glue wasn’t replaced, the shell was replaced, and there are actually more gaps. Is there a problem with your material?'

I first countered him with three questions: Is the potting compound silicone, polyurethane, or epoxy? Was the housing annealed before potting? After damp-heat aging, was the interface retested again?

He thought for a moment and said he could answer the first two, but he really hadn't done the third one.

The line below represents the full course of those shell casings.

The starting point is that after changing materials, the drawing test passed and the appearance was clean, so the box factory judged the material change as successful; the latent phase is when fine cracks only appear on a few pieces and are considered individual fluctuations; the outbreak is when the components are installed outdoors, exposed to water during the hot and humid season, insulation resistance drops, and complaints come back in concentration; the settlement is a review, finding that the casing itself was not chosen incorrectly, but what changed were the thermal expansion coefficient of the wires, the surface condition before potting, and the humid interface that no one re-tested.

The most expensive cost of changing materials in a junction box is often not in the material price, but in the matching of the two systems.

1. The operating condition of the junction box: in six dimensions, first drop the numbers for the four types

The junction box looks like a small outdoor item, but the working conditions are quite dense.

The temperature needs to be looked at in three layers.

When this layer is operating, the component backsheet temperature commonly ranges from -40 degrees to 85 degrees; for high-power components, the local backsheet temperature can be even higher.

This cycle, calculated based on the day-night temperature difference, occurs more than three hundred times a year. Considering a service life of twenty-five years, the cumulative amount is over seven thousand times.

The layer of damp heat is the real testing ground for the junction box: eighty-five degrees, eighty-five percent humidity, one thousand hours, which is a common test standard in the industry.

This item, the medium, is unique to it: the potting compound itself, the cleaning agent, and the salt spray in coastal scenarios—all three need to be considered.

The electrical part isn't easy either: insulation resistance, resistance to leakage tracking when wet, and the performance after long-term exposure to water are what really count.

This mechanical aspect mainly concerns assembly and bolt pre-tightening, as well as the stress at the connection between the enclosure and the bracket.

Appearance and compliance are placed last, but they are equally strict requirements for unpainted parts: color difference, floating fibers, and certification list.

Among the six items, damp-heat, line expansion, and interface need to be determined first, as they decide how the subsequent path will proceed.

Two or three shell routes, arranged side by side

Changing the material is not about choosing the 'least likely to crack' one, but about clarifying the costs of the three options.

RouteWater Absorption and SizeStress and CrackingCompatibility with glueWhere is it suitable to change from?
PA66-GF General SystemWater absorption is relatively high, and the size is average.Residual stress is relatively high and requires annealing.Sensitive to rubber typesOriginal universal reinforcement material and small box body
PA6 toughened low modulus systemWater absorption is relatively high, size is mediumLow modulus, low stress, more tolerant interfaceMore compatible with siliconeParts that were originally more brittle and prone to cracking
Long carbon chain PA low moisture absorption systemLow water absorption, relatively stable dimensionsMedium stress, better hydrolysis resistanceWide matching surfaceOriginal imported materials are discontinued or out of stock

None of the three is better; it depends on which one fits your type of rubber and structure.

A common misjudgment is comparing only the water absorption rate.

Low water absorption does make the size more stable after moisture and heat, but the issue of interface cracking mainly lies in the difference in linear expansion coefficients and surface condition.

Focusing only on water absorption is like compressing two things into one.

Another misjudgment is treating cracking as the sole responsibility of the casing.

Potting is the molding of two materials together, and the interface stress is determined by three variables: the modulus of the adhesive, curing shrinkage, and the linear thermal expansion of the shell.

If these three things aren't placed on the same table, no matter whose case it is, you'll just have to rely on luck.

3. Material Change Criteria Table: This table determines which items you need to re-inspect

Turn the previous constraints into verifiable indicators.

The thresholds in the table are directional recommendations, not acceptance criteria; the actual values need to be determined by your parts, your type of adhesive, and your actual measurements.

IndicatorDirectional ThresholdVerification Method / StandardCommon failures after material changeCommon solutionCorresponding auxiliary agent system
Coefficient of linear expansion matchingThe smaller the difference with the glue, the better.ISO 11359 or industry thermomechanical methodInterface separation, edge seamChoose the combination with a smaller deviation and review the structure— (Belongs to combined design)
Interface bonding strengthAfter being damp and hot, pulling does not detach itPulling / stripping, retest after containing moisture and heatJunction cracks, water seepagePrimer or plasma control surface conditionCoupling agent (interface bonding)
Environmental Stress Cracking ResistanceVisually free of cracks after soakingSoaking Visual inspection and stretching (GB/T 1040)Matrix cracks, oriented crackingReduce residual stress by choosing a low-stress systemAntioxidant (anti-hydrolysis)
Insulation resistance after damp heatTest in wet condition according to the whole machine specificationsDamp Heat Chamber Insulation Resistance TestInsulation failure after water ingressInterface protection Structural anti-water accumulation— (Belongs to the structural side)
CTI (wet state)Measure in wet condition according to the machine gear.IEC 60112, conditioned stateDropped a gear, authentication stuckLow moisture-absorbing substrate—(Material grade)
Dimensions after moisture conditioningThe key mating position is in the humidity control diagramMoisture conditioning Re-measurement of dimensionsAssembly interference, sealing floatDrawings and acceptance based on moisture conditioning—(Belongs to size management)
Thin-walled flame retardantReport V-0 according to minimum wall thicknessUL94 / IEC 60695-11-10The thin-walled areas do not meet the standardChange the flame retardant system and retest according to the thin-wall specificationHalogen-free flame retardant
Surface condition of the potting areaNo release agent residue or greaseVisual observation Surface energy or water film methodThe adhesion is sometimes good and sometimes badClean or modify the release agent systemLubricant (mold release residue affects bonding)

How to read this table: first look at the first two rows.

Linear expansion matching determines the innate conditions of the interface, and interface adhesion decides whether it can hold.

If these two lines can't pass, all the subsequent insulation and flame-retardant data are meaningless.

The third column is for Purchasing and Quality: Tensile data must indicate whether it has been subjected to hot and humid conditions; tensile data at room temperature cannot be directly treated as long-term conclusions.

The position of the last line is a reminder: when it comes to mold release agents, the cost is almost zero, but the price is often the greatest.

4. Four types of failures after material replacement, and their real causes

Failure 1: Fine cracks appear at the junction between the glue and the shell.

The cracks run along the interface, and after peeling, the surface of the outer casing remains intact, with no tear marks. This type belongs to interface separation.

The root causes are mostly in three areas: thermal expansion difference, surface contamination, and exothermic curing of the adhesive.

When the potting compound cures, it releases heat, heating the casing. After curing, it cools and shrinks, causing the two systems to pull on each other. The greater the difference, the more strain at the interface.

Failure 2: Cracks run through the body of the housing, often along the weld lines or the orientation of the fiberglass.

This type is substrate cracking, and the root cause is two stresses superimposed: residual stress left by injection molding, plus external stress caused by resin curing shrinkage.

A common judgment of sharpness is: treating all potting cracks as a problem with the casing material, which is the most expensive form of inertia in this field.

The material was not chosen incorrectly, and the interface is also clean, yet it can still crack—because the residual stress within the part itself has not been released.

Annealing can release a considerable part, and many factories skip this step directly.

Failure 3: Cracks radiate around the colloidal area, occurring mostly shortly after curing.

This type involves brittle tearing, which is related to the thickness of the adhesive layer and the strength of the constraint.

The thicker the adhesive layer, the greater the force caused by shrinkage; thinning the adhesive layer and slowing down the curing curve is often more effective than changing the material.

Industry experience is that slow curing produces much less stress than fast curing, and factories that extend the curing time usually see a reduction in the cracking rate.

Failure four: In the same batch of housings, individual pieces show surface fogging or uneven local color.

This category is often classified as 'material instability,' but in fact, most of it is related to additives.

If antioxidants are not evenly dispersed, some areas will change color first; after small molecules of flame retardants migrate to the surface, they will form a hazy layer.

This layer of misty substance has another side effect: it separates the primer, making the adhesion sometimes effective and sometimes not.

When you see fogging, first check the mixing and additive system, don't rush to run another batch of material.

5. Processing and verification: include the sequence and a single retest

Regarding annealing, it is recommended to directly write it into the confirmation form for replacing materials in the junction box.

Its function is to reduce the residual stress from injection molding, making room for stress allowance for the subsequent potting.

Drying and material temperature are the second group.

Long carbon chain systems have relatively low water absorption, but after unpacking and leaving them exposed for a few hours, they will still regain moisture; before use, check with a moisture meter or dew point, and don't rely on touch.

Excessive material temperature can cause local degradation of the material, worsen the surface condition, and make the interface base unclean.

Mold temperature affects the surface and the weld line.

If the mold temperature is too low, the weld lines will be weak, the surface will be rougher, and the wetting during potting will actually be worse; this item should be measured per piece, not copied from standard values.

There are three things to adjust on the side of potting: the type of glue and wire expansion, the curing curve, and the temperature during potting.

The temperature in the gluing room in winter is low, the glue's viscosity increases, wetting worsens, and the interface is inherently insufficient — this item is rarely on the troubleshooting list, yet it is often the answer.

It is recommended to arrange the verification sequence like this, do not change it:

1. Sample level: After injection molding, make a qualitative judgment of residual stress, with one group with annealing and one group without annealing

2. Combination level: Pour glue according to the actual type of glue and the thickness of the glue layer, curing curve follows the actual process.

3. Damp heat: 85 degrees, 85% humidity, 1,000 hours, check the interface halfway through

4. Hot and cold cycling: Complete according to the actual range, and observe the interface and the matrix

5. Retest after cycling: pull or peel, and simultaneously retest the insulation resistance

Why can't the order be changed? Because the interface state depends on the history of moisture absorption and temperature; without the layer of humidity and heat, the data from room temperature pulling only indicates that it was good on the day it left the factory.

6. Boundaries: For these types of junction boxes, stop changing materials first

This section may be more valuable than the previous few sections because it helps you cut losses before starting work.

First, epoxy casting with a large flat thin shell.

Epoxy has a high modulus and large shrinkage. Thin-shell components inherently have little stress tolerance, and when the two are combined, there is almost no room at the interface.

For this type of project, it is recommended to first change the adhesive, or make the casing with a stress-relief structure, before discussing material replacement.

Second, parts that cannot be thickened or rounded in structure.

The junction between thick and thin sections and the inner sharp corners are stress concentration points. The part cannot be changed; changing the material only delays the cracking time.

Third, positions where the adhesive layer is very thick and the constraint is strong.

This type is a high-incidence area for curing cracks, and the benefits of modifying the adhesive layer and curing curve are usually higher than those of changing the housing material.

Fourth, parts that require long-term extremely high humidity insulation and cannot have interface protection.

This requirement has gone beyond the range that ordinary modified nylon can cover and should look towards a more specialized system.

Fifth, parts whose failure points have not yet been located.

Interface seams, substrate cracks, and curing tears—each has a completely different solution. Acting without identifying the cause is the same as repeating the previous mistake.

Putting these five points at the front is not to discourage, but to save time.

7. Material Change Risk List (From the original plan to this one, things that need to be changed)

link; segment; partWhat do you want to move?Points that are easy to overlook
MoldIf the substrate changes, the shrinkage rate will change, and the fitting position of the box needs to be re-measured.Only replace the material without repairing the mold, interference occurs first during assembly
DryReplace the dehumidifying dryer and set the window according to the measured moisture content.The exposed surface regains moisture after a few hours.
Humidity controlKey fitting dimensions are drawn and inspected according to the conditioned stateRelease according to dry-state dimensions
Material Temperature / Mold TemperatureReset the welding lines and surface condition per pieceCopy the gear setting from the previous batch
Pressure Holding / DemoldingResidual pressure must be controlled, and release agent residue must be cleanedThe glue-pouring area got demolding agent on it
Surface treatmentPrimer or plasma according to the type of adhesiveFirst pour, then refill; the interface is already set.
Color differencePre-match color panels for non-coated partsThere is a difference in the background color between batches
Verification orderSample → Assembly → Damp heat → Temperature cycling → Re-measure after cyclingIf the previous item fails, just move on.

8. Proofing and mold testing schedule (number of machine runs, what is checked in each run, how long samples are kept)

We change the material for the junction box trial mold, usually in three rounds, without skipping steps between rounds.

First round · Sample comparison: Use your original mold to make three to five samples, check the filling, appearance, weld line position, and at the same time confirm the moisture content after drying.

This round we're not chasing performance; first, let's confirm whether the materials and molds are compatible.

Keep two samples, label the batch number, drying parameters, and mold temperature, and keep them at least until the end of the second round.

Second Round · Process and Interface: Fixed material, varying mold temperature and holding pressure to make two sets of comparison samples; one set annealed, one set not annealed.

Pour the adhesive according to the actual type of adhesive and thickness of the adhesive layer, follow the actual curing curve, and check whether there are any abnormalities in the interface and the substrate.

This round determines the production parameters and also decides whether to keep the annealing or not.

Samples should be sealed by batch. For potting components, keep them together with the casing—failures are a combination behavior; if you keep only the casing or only the potting, you won't be able to reconstruct the scene during review.

Round 3 · Heat and Humidity vs. Circulation: Run for one thousand hours at 85 degrees and 85% humidity, checking the interface once midway and once at the end; then proceed with thermal cycling, and after the cycles, conduct pull tests and insulation retests.

Only after this round passes is it recommended to increase volume.

The sample storage period covers the first batch of mass production, facilitating cause tracking.

9. Self-Production Capacity Position and Frequently Asked Questions

The auxiliary system in the formula is matched according to the working conditions per item — conventional auxiliaries are kept in stock, and special models are matched as needed; you report the working conditions and grade, and the materials and auxiliaries are prepared together at once.

If this article is going to be reported, it can be summarized in four lines:

itemA one-sentence conclusion
Change whatLooking at the casing from a low-stress, low-water-absorption system perspective, first lay out the type of adhesive and the linear expansion data.
Move whatThe temperature and humidity in annealing, drying, surface treatment, and potting rooms should all be operated together.
Test whatInterface after damp heat, pull-out after circulation, wet state insulation, thin-wall flame retardant
When can the volume increase?After three rounds of trial molding, no abnormalities were found at the interface after 1,000 hours of heat and humidity, and re-testing after cycling passed.

Three questions readers often ask

Q: The adhesive wasn't changed, so why did it crack after changing the casing? The interface stress is determined by both the adhesive and the casing ends. Once the casing is changed, the thermal expansion difference and surface condition both change, and the adhesive's tolerance may not be sufficient.

Q: If the room temperature pull test is passed, does that mean the damp heat test is not needed? Room temperature only shows that it can stick on the day of manufacture; the interface after long-term water exposure needs to be judged by damp heat and repeated cyclic testing.

Q: Will annealing affect the dimensions? There will be slight changes, so the drawings should be based on the dimensions after annealing; not annealing and releasing according to the dry dimensions is an even greater risk.

Explain who we are in three lines:

Modify performance——Modified nylon (PA6 / PA66 / PA46 / PA11 / PA12 / PA6T / PA9T and nylon alloys), modified PPO / PPS / thermoplastic elastomers;

Stock available — Major chemical giants' nylon resins, secondary brand materials, and bulk materials in stock;

To determine — what part, what material to use, and which type of auxiliary agent to match.

The first three probing questions—about the type of gel, the arrangement of annealing, and the retesting after humidity and heat—become clear when revisited here: once these three are answered, whether the junction box can be replaced and which items need to be re-verified after replacement are basically determined.

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