改性PP发动机舱护板:长期油浸与热老化怎么判

应用领域 发布时间: 2026-09-13 3125 阅读

For the engine compartment shield and air filter housing, modified PP is used. The most common cause of failure is not insufficient rigidity, but aging and cracking after long-term exposure to high-temperature oil. This article explains the six-dimensional operating conditions of engine compartment parts, the criteria for resistance to long-life ethylene glycol coolant and hydrolysis, the distinction between HDT and long-term usage temperature thresholds, as well as the verification sequence and material replacement risks.

A technician from a company that does secondary support sent over a photo: after removing the lower engine compartment guard, the mounting points are crumbling, breaking apart just by hand. Could it be that your material is too poor?

I said, don’t rush to blame the material. First, tell me where this protective plate is attached in the engine compartment, what is next to it, and how many years it has been soaked.

The engine compartment guard and air filter housing are made of modified PP. The first criterion has never been 'is it hard or not,' but 'does it become brittle after a few years?'

Below, break it down layer by layer according to operating conditions, routes, criteria, and verification.

1. Opening Pain Points: The Customer's Original Words and the Most Common Failure Sites

The client's exact words are of two kinds. One is: 'The skid plate has been used for over a year, the fixing points are starting to flake off, and it breaks with a twist. Is the material too poor?' The other is: 'When the air filter housing is removed, the clip positions become brittle, and it cracks after tightening just two screws.'

There are two most common sites of failure:

First, it becomes brittle and cracks after long-term exposure to high temperatures and oil immersion. In the engine compartment, the under panels are attached to the oil pan and the exhaust side, constantly soaked in engine oil vapor, coolant leaks, and brake fluid splashes. In summer, the interior of the engine compartment is persistently hot, with even higher local temperatures for short periods. PP (polypropylene) is generally resistant to polar substances, but time is the killer—thermal and oxidative aging gradually depletes the antioxidants and breaks the molecular chains. It may look fine on the outside, but it will crumble to pieces under vibration or when removed.

Second, the mounting points of the protective plate tear. Stone impacts, vibrations, and clamping forces accumulate over time at the base of the clips, and once the material becomes brittle due to aging, the stress concentration points fail first. This is not simply a 'strength insufficiency'; it is a combination of 'strength collapse after aging' and 'stress concentration'.

An insider detail: the cabin is not a uniform temperature box. The same protective panel has very different thermal loads on the exhaust side versus the intake side; if aging evaluation only relies on standard test samples, the lifespan will be overestimated. Truly representative data must be sampled according to the actual installation orientation—the material on the side near the heat source reaches the aging inflection point earlier.

2. Six-dimensional breakdown of working conditions: at least four dimensions must provide specific numbers

The operating conditions of the engine compartment guard plate and the air filter housing can be broken down into six dimensions. Once the six numbers are all reported, the direction will basically become clear.

DimensionThe actual working condition of this partRequirements for the materials
TemperatureThe cabin maintains a high temperature (designed for an environment of 100-120°C over the long term); local short-term peaks can reach 140°C (public data for air conditioning ducts/fan blade components indicate they can 'withstand a thermal load of 140°C for a short time')It is necessary to distinguish between continuous temperature and short-term peak temperature.
LoadStone impact (rock impact-type test), vibration, fixed-point clamping force; non-structural load-bearingToughness and resistance to stress cracking, not rigidity
MediumEngine oil/fuel, brake fluid, ethylene glycol coolant splashes, de-icing salt, maintenance cleanersHydrolysis-resistant, oil and gasoline-resistant, chemical-resistant
LifespanThe full vehicle lifecycle (commonly designed in the industry for 10 years/15 years or 100,000 kilometers)Performance does not deteriorate after long-term aging
AppearanceThe protective plate is mostly on non-visible surfaces; the air filter housing requires the assembly surface to be flat, with no broken or missing clips.Size and clip integrity
ComplianceControl of banned substances in the whole vehicle and VOCs (looser for cabin parts compared to interior, but still within regulations)Check against the itemized inventory

Among the six dimensions, temperature and medium are two fixed lines. The reason is straightforward: over ninety percent of cabin component failures start with 'thermal-oxidative aging and oil immersion,' not rigidity or appearance. So the first question in component selection is not about price, but 'where in the cabin will your part be installed, what medium will it be exposed to, and how many years must it last?'

Text version conclusion: In Six-Dimensional, continuous temperature and short-term peak temperature must be calculated separately—relying on the exhaust-side heat shield, short-term 140°C might withstand it, but long-term 120°C continuous baking is a different matter; the air filter housing is affected by intake heat and oil vapor from crankcase breathing, so the temperature is lower, but the medium is more demanding. Mixing these two accounts into a single number is the most common starting point for material selection failures in the engine compartment.

3. Comparison of material routes: Three routes are presented side by side, without drawing a 'which is better' conclusion

The matrix of modified PP is polypropylene. The engine compartment guard and air filter housing mainly fall under three routes; none is better, it only depends on whose operating conditions match.

RouteGet whatCost
Impact Copolymer PP Toughened (copolymer PP blended toughening system, referring to the publicly available paths for radiator water chamber/expansion tank)Hydrolysis-resistant, heat and oxidative aging resistant, good toughness; relatively stable to oil vapor and coolantRigidity is compensated by filling, and the upper limit of heat resistance is restricted by the grade of the substrate.
Copolymer PP mineral (talc) filledReinforce rigidity, reduce shrinkage, control costs; without significantly increasing warpingSlightly reduced toughness, average surface, requires toughening aid
Long Glass Fiber PP (PP-LGF)High rigidity and high heat resistance (glass fiber retained length >3.1 mm critical length; tensile strength 50–80 MPa, flexural strength 80–120 MPa, notched impact at room temperature 15–40 kJ/m², HDT 120–180°C, density 1.0–1.2, shrinkage 0.3–0.8%)Anisotropy, surface floating fibers, unfriendly to stone impact and appearance

The method of division is very simple:

- Large-area protective plates, air filter housings → Combination of Route 1 and Route 2, focusing on toughness, hydrolysis resistance, and dimensional stability

- Bracket positions that need to hang or bear weight → Route three, choose rigidity and heat resistance

- Relying on the short-term high-temperature area on the exhaust side → Strengthen the heat-resistant oxygen system based on Route One, without relying on a filled hard top

There is a public case worth referencing here: the front-end module of the cabin reduced weight by about 30% after using long glass fiber integration (the Ford Super Duty front-end module weight reduction of 1.4 kg can be used as supporting evidence). But that is the idea of structural integration, which does not mean that large-area shields should use long glass fiber—if shields use long glass fiber, warping and fiber floating will become issues before strength does.

Golden saying: You don't need all ingredients in a formula; it's a ranking question. The thing most prone to is oil-immersed aging, so put hydrolysis resistance and heat-oxidation resistance first, and leave rigidity and cost later.

4. ★ Selection Criteria Table: five columns, each item comes with a verification method

The table below is the part of the entire article most worth saving. Focus on the third column "Verification Method · Standard Number" — the part that usually trips people up when selecting cabin components is not "which indicator to look at," but "what to measure with and what measurement counts as passing," especially for medium resistance and aging.

IndicatorThreshold Value (Typical)Verification Method · Standard NumberCommon FailuresCommon solution
Heat Deflection Temperature (HDT)≥100℃ (Refer to GB/T 24149.1-2009 Automotive PP Special Material Threshold)GB/T 1634.2, under a load of 0.45 MPaMistakenly regarded as long-term operating temperature, service deformationOnly used as a short-term criterion; long-term temperature is calculated separately
Short-term heat loadCan withstand 140℃ for a short period (air conditioning duct/fan blade parts with open caliber)Short-term Heat Deformation / Appearance EvaluationLocalized overheating deformationDistinguish between continuous temperature and short-term peak, determined according to installation location
Ethylene Glycol Resistant Long-Lasting Coolant / Hydrolysis ResistantAfter long-term soaking, the mechanical retention rate and appearance comply with item-specific standards (public information: long-term soaking in high-temperature coolant leads to aging and cracking)Plastic liquid medium resistance test, measure tensile retention rate/appearance change rate after immersion, temperature and time cover actual working conditionsCracking from long-term coolant immersionGrafted PP for toughening, strengthening hydrolysis resistance and heat-oxidation system
Oil-resistant immersion (engine oil/brake fluid splashes)The retention rate of elongation/appearance change after soaking is according to the company specifications; the soaking temperature is taken as the actual medium temperature in the machine compartment, and the time is based on the stepwise schedule (e.g., 500 h / 1000 h, according to company specifications).Same method as above, the medium is according to the actual type of splashingMigration of oil and vapor acceleration additives, surface degradationOil-resistant gasoline additive system with dielectric aging evaluation
Long-term thermo-oxidative agingAfter aging, the stretch/impact retention rate and appearance should comply with the company specifications, with a focus on the inflection point.Thermal aging chamber, service life corresponding to cycle and temperature pointsCliff-like embrittlement after antioxidant depletionHeat-resistant oxygen and antioxidant system balancing
Notch Impact (Room Temperature/Low Temperature)Room temperature gap impact according to the item; low temperature according to the installation areaGB/T 1043.1 (Simply Supported Beam)Disassemble/Repair CracksToughening system
Mold Shrinkage / DimensionsShrinkage rate is determined according to the current mold (sensitive for long protective plate parts)GB/T 17037 SeriesAssembly gap/clip does not alignMineral-filled shrinkage adjustment

Text version conclusion: Among the seven items, HDT ≥100℃ and 140℃ short-term heat loads are both 'short-term criteria' and cannot be used as long-term operating temperatures—this is the most commonly confused point in the industry; for ethylene glycol resistance and oil immersion, the threshold should be based on the 'retention rate after immersion,' and real media must be used, as testing with heat aging alone would overestimate lifespan; shrinkage is not just about the material itself, it must be considered together with the customer's mold. Treat this table as a physical check-up report; if any item is missing, do not deem it qualified. This saves much more money than testing a sample and then going back to find the reason.

5. Common Failures and Root Causes: Four Phenomena, Four Root Causes

Failure 1: Tear at the fixed point / broken buckle. The root cause is mostly the loss of toughness after long-term thermal-oxidative aging, combined with stress concentration from stone impact and vibration. First, check the crack initiation point — if it radiates from the root of the buckle, it indicates stress concentration and creep; if the crack starts from any point on the surface, then suspect material toughness first. If the order is reversed, you'll waste several rounds of replacements.

Failure two: after long-term oil immersion, the surface becomes chalky and sticky. The root cause is that additives are extracted and migrated by oil vapor. Testing with only thermal aging does not reveal the problem; it must be evaluated with the medium to expose it.

Failure Three: Assembly clearance / clips not fitting. This type is most commonly attributed to 'material shrinkage.' However, shrinkage itself is a design input—if the shrinkage rate changes when the material is switched but the mold is not re-verified, clearance problems are bound to occur. This is the most typical associated cost of changing materials, not a material defect.

Failure Four (Dare to question a common practice): Using the bumper's −30°C low-temperature impact standard to evaluate the engine splash shield. The main causes of engine splash shield failure are thermal-oxidative aging and oil immersion, not low-temperature brittleness (unless it's parked for a long time in extremely cold northern regions). Using low-temperature impact as the primary criterion can lead to choosing the wrong system, costing more money, and still not solving the real problem. Similarly, 'HDT ≥ 100°C means it can be used long-term at 100°C' is also wrong — HDT is the onset of short-term deformation under load and cannot predict performance three years later.

Failure phenomenonCommon MisjudgmentActual possible reasonsWhat should we check first?
Fixed-point tearingThe ingredient is too brittleThermo-oxidative aging Stress concentrationCrack initiation point and propagation direction
Surface powdering and becoming stickyPoor material qualityAdditives are extracted by oil vaporAging test with dielectric
The assembly clearance does not matchMaterial shrinks a lotShrinkage rate after material change/rechecking per moldShrinkage rate and the current mold value
Breaks upon assembly and disassemblyInsufficient resilienceToughness collapse after aging Buckle stressAging retention rate Snap-fit structure

Table note: When troubleshooting failures, first identify the cause category, then decide whether to change the structure or the formula— the cost difference between the two directions is an order of magnitude.

6. Verification sequence: what is a priori, what is a posteriori

Almost no one in the industry writes this part, but it is the key to whether material changes can save money. If the order is wrong, the costs will concentrate and explode at the final step.

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① Medium compatibility and thermal aging samples Resistance to ethylene glycol/oil soaking Tensile retention and appearance after thermal aging

↓ Fail (retention rate drops below specification / cracking) directly returned, do not move the mold

② Notch Impact and Rigidity Notch impact at room/low temperature, bending modulus, HDT

↓ But return

③ Short-shot mold test Complete filling, weld lines, floating fibers, weak spots of stone marks

↓ Only proceed after passing the batch

(4) Vehicle Fitting and Vibration Durability: Snap assembly force, vibration bench, stone strike

⑤ Batch trial production Client-side verification

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Text version of the conclusion: The verification sequence is medium aging → impact rigidity → short shot → assembly matching → mass production. The medium aging step must be completed before mold trials, because it is most likely to result in outright failure in the later stages of service; once this is passed, then working on the mold side will not waste mold trial costs.

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A professional detail: after soaking, the sample should be adjusted to the standard condition before measurement. If the residual medium on the surface is not wiped off, the values may be artificially high or low; samples aged with medium taken from the actual installation orientation are closer to the true performance of the part than standard test rods.

7. Reverse Honesty: In these three situations, this part should not use modified PP

Earlier we talked about 'how to do it'; here we talk about 'when not to do it.' This section has the highest value for selection and judgment.

The situation that occurredWhy is modified PP not suitable?Which way should I go?
Requires continuous operation above 150℃ for a long timeModified PP's heat resistance is improved through fillers/toughening, the HDT upper limit is around that line, and in the long term it is more constrained by the lifespan of the antioxidant system.Switch to a higher heat-resistant engineering plastic system
Requires A-level appearance surface (exposed highlights do not need painting)Cabin panels are mostly non-visible surfaces; if A-level appearance with high filling is also required, the surface should be delicate and the rigidity balanced.Appearance parts and structural parts are designed separately
Requires extremely high rigidity and does not allow any creepThe creep of PP is structural, and modification can only alleviate it.The load-bearing bracket uses engineering plastics or metal, or long glass fiber reinforced materials.

The rule is very clear: whenever there is a 'requirement for two opposite directions at the same time,' it indicates that this part should not be forced with PP. When faced with such a demand, our approach is to first clarify it, and then discuss whether there is room for compromise—if the order is forced through, it will eventually have to be returned through rework and claims.

8. What to touch when changing materials: a checklist to look at before you act

Before deciding to try modifying the PP, it is recommended to go through this table first. The client's real concern is often not performance, but 'do I need to change my current molds and processes?'

Items to moveWhat needs to be confirmedWhat will happen if I don't do it?
Mold shrinkage rateThe shrinkage rate of new material differs from the original plan, and long protective plates are particularly sensitive.Size is out of tolerance, clips do not align
Gate and VentingDifferences in the flow of mineral/glass fiber materials, insufficient venting can easily trap airUnderfill, weld lines, burning
Material Temperature and Mold TemperatureThe processing window of heat-resistant systems is differentFloating fibers, decomposition, surface defects
DryIt depends on the specific system; fillers are usually not needed.Silver threads, bubbles
Pressure Holding and DemoldingShrinkage differences cause deformation and whitening on the surfaceDeformation, extrusion strain
Color differenceAppearance of the air filter housing assembly surfaceBatch color difference dispute
Verification orderSample medium aging → Impact rigidity → Short shot → LoadingAll the risks are concentrated to explode at the final step

Text Version Conclusion: Material changes involve three aspects: molds, processes, and color differences, among which the verification sequence should be discussed first. Skipping small samples and testing the mold directly is equivalent to spending the cost in advance; skipping trial shots and going straight to mass production can result in the loss of the entire batch if it fails once.

9. One-page report comparison table (can be directly pasted into PPT)

SceneRecommended RouteKey indicatorsVerification StandardConditions that need to be confirmed first
Large-area engine compartment shieldImpact copolymer Toughening Mineral fillingEthylene glycol resistance / hydrolysis resistance, thermal oxidation aging retention rate, shrinkage rateMedium soaking, heat aging, GB/T 1043.1, GB/T 17037Installation location heat load, type of contact medium
Air filter housing (not exterior)Copolymerized PP ToughenedEngine oil immersion retention rate, buckle impact, dimensionsAging with medium, notch impactMedium temperature and time
Skid Plate Bracket / Mounting PositionLong glass fiber PP (glass fiber retained >3.1 mm)Tensile 50–80 / Bending 80–120 / HDT 120–180Long glass fiber criterion, GB/T 1043.1Whether to accept anisotropy
Short-time high-temperature zone protective plateCopolymer PP Heat-Resistant Oxygen SystemShort-term 140℃ thermal load, HDT ≥ 100℃Short-term heat exposure, GB/T 1634.2Continuous Temperature and Short-Term Peak Demarcation

Text version conclusion: The purpose of this table is to allow technicians to report conclusions directly without having to reorganize their wording. There is only one criterion for judgment—whether the client can use this table to finalize the material direction in one meeting.

10. The part of this item that is most prone to problems is often not the material.

The discussion of the cabin protective panel and air filter housing in publicly available technical materials focuses on three main issues: aging and cracking after long-term exposure to high-temperature coolant, surface degradation caused by the migration of oil vapor accelerants, and stress cracking at points of clamping and snap-fit joints. These three issues point to a single conclusion — the material verification of cabin components must involve exposure to the relevant medium and long-term testing. Short-term sample verification alone will be exposed during the later stages of service.

The publicly available criteria are also very clear: Ethylene glycol-resistant long-life coolant, hydrolysis-resistant, heat aging-resistant (copolymer PP toughened blend system, Class B public information); short-term thermal load is classified into continuous and peak values according to the criterion of 'can withstand 140℃ for a short time'; if using long glass fibers, the retained fiber length must exceed the 3.1 mm critical length, otherwise the fibers will be pulled out and the strength will not be realized.

The industry standard practice is to set three things together: impact-copolymer grade selection, increased toughening system dosage, and mineral filling to control shrinkage; positions that bear structural functions use a long glass fiber or filled glass fiber hybrid system; the additive system is selected according to the 'heat resistance, oil and gasoline resistance' combination, and aging tests are conducted with the medium.

Ningbo Kolon New Materials Co., Ltd. commonly supplies modified polypropylene (PP) particles with impact-resistant copolymer toughening direction in this part. They classify and recommend based on the thermal load and contact medium according to the installation position, covering filling, glass fiber reinforcement, toughening, and other modification directions. They are mainly used to address the two issues mentioned above: 'long-term oil immersion aging and assembly dimensions.' Small samples can be provided for each part for comparative verification with medium aging.

Frequently Asked Questions

Question: Can the guard plate and air filter housing be made from the same material?

Answer: It depends on the contact medium and temperature distribution. The baffle near the exhaust side has a high thermal load and heavy oil vapor; the air filter housing is subjected to intake heat and oil vapor from crankcase breathing. If the operating conditions at both locations are similar, the materials can be combined; if they differ significantly, they need to be recommended separately by grade—the premise of combining is that the medium and temperature ranges truly overlap, not just for convenience.

Question: How do you determine whether or not to use long fiberglass?

Answer: Check whether it really bears load. Large-area protective panels covered with fiberglass will first have issues like warping and floating fibers; only load-bearing positions with brackets are worthwhile. The criterion is that critical 3.1 mm fiberglass length—if it can't be maintained, adding more fiberglass will just result in the short fibers being pulled out.

Operating conditionKey criterionCologne regular supply
Large-area engine compartment shieldEthylene glycol resistance / hydrolysis resistance, thermal oxidation aging retention rate, shrinkage rateImpact Copolymer PP Toughened Mineral Filled Orientation
Air filter housing (not exterior)Engine oil immersion retention, snap-fit impact, dimensionsCopolymer PP, toughening direction
Guard plate bracket / mounting positionLong glass fiber retention >3.1 mm, HDT 120–180℃Long glass fiber PP direction
Short-term high-temperature area guard plateShort-term 140℃ thermal load, HDT ≥100℃Copolymer PP, heat-resistant oxidation system direction

A reminder: when there is a problem with a part, the most common mistake is changing the material first. Oil immersion cracking, snap-fit chipping, dimension mismatch—each issue has more than one cause. Identify the cause first, then change the material; if the order is reversed, even after several changes, the problem often remains.

About Us

About us, in four sentences:

1. Modified polypropylene: homopolymer / random copolymer / impact copolymer;

2. Modification directions: filled, glass fiber reinforced, toughened, flame-retardant, low odor low VOC, weather-resistant, scratch-resistant without painting;

3. Trading of PP resin from major petrochemical plants;

4. Secondary brand materials and large bag stock available.

Ningbo Kolong New Materials Co., Ltd. produces modified polypropylene (PP) granules covering homopolymer / random copolymer / impact copolymer substrates, as well as modification directions including filled, glass fiber reinforced, toughened, flame-retardant, low odor low VOC, weather-resistant, and scratch-resistant without painting. The company also trades PP resins from major petrochemical plants, secondary brand materials, and bulk stock.

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